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C-NQsVSO0~~TC-NeQ$NylSO v0R NQ gVSONu0 ,{ NekRyC-N@b_vmTir _0RNaHCO3VSO0 ,{VekTnm-NReQϑvgVSO|+g gNH4ClvfSOgQ0 1 NV@b:yňnvޏcz^/fac________c___bc_____kXcSS 0  2 A-N8^ (uvVSOS^ir:N_______________D-N^ (uvmSO:N________________0 3 ,{Nek-N_______ňnHQSuS^0 4 C-N(utb_r^q{ N(uv[{ vQ\O(u/f__________________________________________ň ge4lCaCl2vUb_{v\O(u/f______________________________________________________0 5 ,{ NekRyQNaHCO3VSOvd\O/f___________________0 6 ,{Vek-N@bRVSO|+gSf[_:N 0@b_vvfSO-N8^+T g\ϑvNaClTNaHCO3(~`S5~8) N*N{USv[ NO(uvQNNUOՋBR f@b_vfSO'YR/fNH4C10{QQd\OTsa_________________________________________________________________________0 1713R 05u`lOyr^5u`l (Wu;m-Nv(uϑ_'Y0vQ-Nnf 05u`lvg VYSV@b:y0VT{ NR 1 5u`l>e5ueSuv;NS^:N Zn+2NH4Cl+2MnO2=Zn(NH3)2Cl2+2MnOOH ckgSuv;NS^/f ____________________________________________________0 2 NVh:yN^enf 05u`ldS XT5ugTvQ[ir-NV6e6RYKMnO4I{ir(vNy]z NQ^e5u`l-N[EX[(Wv\ϑvQNё^\ 0  `$ўrVSOmTir4lxme:NcؚxmQs 8^Ǒ(uvce:N___________________T{$Nag _0RnmReQzvxv\O(u:N___________________________________________0 a$n#n4lm|ppTVSO;NbNS gNy d\Oa-N_0RqWWv;NbR/fK2MnO4 Ǐ z-NSuS^vSf[e z_:N___________________________________________________________0 b$V-NNirvSf[_R+R:NA _______0B_______0 3 Qnxyϑ_0RvKMnO4 N+TNIxS^vBg( 3.160 g >eeQ\pog-N R4lnTly0R200mL[ϑt-N[[ (W%b_t-N(u]ϑlyS0.6700 ge4lIx ReQϑkxxnmn Rp75~80!0(u]M6R}YvKMnO4nmۏLn[ mnmSOy:N22.50mL0 ]wMr(Na2C2O4)=134 Mr(KMnO4)=158 `$$Ren[~pvsa/f_______________________________________________________0 a$ KMnO4v~^:N__________0 1811R F)Y[NƖV:NenWvHQL (W-NWS0W:Sb gg'Yv2uňnv^]^bt^N50N(TN2uňn01uTbl~b:NH20COT\ϑvCO2 vc6RYN2u mSY NS^0 2uTbS^ i CO(g) + 2H2(g)  CH3OH(g) %H1 = -90.1 kJ" mol-1 N2uTbS^ii 2CH3OH(g)  CH3OCH3(g) + H2O(g) %H2 = -23.9 kJ" mol-1 iii 2CH3OH(g)  C2H4(g)+2H2O(g) %H3 = -29.1 kJ" mol-1 VT{ NR 1 Al2O3/fTblvc6RYN2uS^PSBRv;NbRKNN0]N NNݔWw6RYؚ~^Al2O3v;N]zAm z/fNSf[e z_h:y 0 02Al(OH)3  Al2O3 +3H2O0 2 N[)n^e S^i vs^a8^pepefrS^ = 3 \* GB3 b$s NS g$N*NSNW0 F0F0D0[V0WN!hՋTv 2017J\ؚ N,{N!kTՋST{HhN S f[ b ,gqQ14\ k\3R S1234567T{HhCBACA BAS891011121314T{HhCDADDBC15. 8R 1 S0Fe 1R ST{NybYT{GWeR 2 Fe3+ + 3H2O  INCLUDEPICTURE "../../../../XKW/AppData/Local/Temp/ksohtml/wps9128.tmp.jpg" \* MERGEFORMAT  Fe(OH)3+ 3H+ bFe3+ + 3H2O = Fe(OH)3 SO + 3H+ 2R 3 Fe3S4+3H2SO43H2S!+3FeSO4+S! 2R :\!bcb!1R ScbN!k 4 H2SO3+I2+H2O SO42-+4H++2I- SegR5uyvNkxxS:N[hQ5uyvkxx Nx؏S:N:_xHI03R e z_01_xS:_xTub"lxxT1R 16. 11R 1 fed 1R \T{0YT{bz^GWeR c 1R 2 wppwb'YtwbWWrCaCO31R TtGW~R T{Q|reR 0qTxx"lnmbqTNaHCO3nm 1R 3 B 1R 4 2bkP8T 1R TtGW~R 8T6eYYOvNH3 1R TtGW~R 5 Ǐn 1R 6 NaCl1R S\ϑVSO>eeQՋ{-N Rp VSO'YRm1Y (WՋ{SQXS gYvVSOQ~ 2R d\OsaTNR vQ[TtT{HhSgq~R 17.13R 1 MnO2 +NH4+ + e- = MnOOH + NH3 2R N/fg{kS_1R  = O(u ! cb1R 2 `$Rp0\VSOmTir|x0db2R T{QvQ-NNag_1R Zn(NH3)2Cl2 + 2HCl = ZnCl2 + 2NH4Cl v^b6RSm)eSu4l2R S^e z__NS(ueW[f lSTb6R4lT1R a$ 3MnO2 + KClO3 + 6KOH  INCLUDEPICTURE "../../../../XKW/AppData/Local/Temp/ksohtml/wps9158.tmp.jpg" \* MERGEFORMAT  3K2MnO4 +KCl+3H2O2R q_NS(uRp0ؚ)n l gcb1R b$ MnO21R NH4Cl1R 3 `$S_neQgTNnnm nmS:NEm~rNJSRQ N*r1R a$88.89%2R 88.80~88.99%GW~2R 89%eR 88.9%*gla gHepeW[cb1R 18. 11R 1 Al2O3+2NaOH +3H2O=2NaAl(OH)4 1R Qb NaAlO2 NS_1R xn N~R 2NaAl(OH)4+CO2 = Al(OH)3!+NaHCO3 1R Qb Na2CO3 eR 2 61.5%(2R 62%S_1R) 3 `$ii(1R vQNeR) S^ii ;mSNO (Wv TagN NS^s'Y (1R) a$ NS(1R) 4 2CO(g) + 4H2(g)  INCLUDEPICTURE "../../../../XKW/AppData/Local/Temp/ksohtml/wps9169.tmp.jpg" \* MERGEFORMAT CH3OCH3(g) + H2O(g) %H = -204.1kJ/mol (2R MRb[TbMb gR) S^lSORP[peQ\ S:_GSؚOs^aSy COTH2lSsX'Y CH3OCH3NsXRS:_GSؚOCOTH2Sm^XR S^sX'Y02R s^ayRTsX'Y҉^T1R 19.[Sf[- O3ir(~gN'`(]15R 1 4hTgVIIIe1R [Ar]3d104s11R ܔ1YSv/fhQEQnv3d105uP[ 1YSv4s15uP[2R hQEQnv3d1004s1T1R 2 RP[vfSO1R 3 "l. ckVbSO sp3 INCLUDEPICTURE "../../../../XKW/AppData/Local/Temp/ksohtml/wps916A.tmp.jpg" \* MERGEFORMAT  kzz1R qQ4R 4 4632R 5 ё^\.1R Cu3AuH83R AuCu3H8_3R0H N/fgTFOkOcknx_2R 20.[Sf[- O5 g:gSf[W@x]15R 1  INCLUDEPICTURE "../../../../XKW/AppData/Local/Temp/ksohtml/wps916B.tmp.jpg" \* MERGEFORMAT 2R Qb INCLUDEPICTURE 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