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"[a 46ec8aac122bd4f6e3" PSKSKS^tz"zz_s8zn ' Z8Td$ h  F'8  Sf[ՋwS f1,gՋwSՋe100R0nR100R0 2,gՋwSRwS`!TwSa!0wS`!:N b \T{HhmQNT{aS NwSa!:N^ b \T{HhQNT{wS N0 3,gwSS(u0Rvv[SP[(ϑ gH 1 C 12 N 14O 16 Si 28S 32Na 23Mg 24Cl 35.5Ba 137K 39Cu 64P 31Ag 108Fe 56 ,{`!wS b qQ46R N0 bk\S gN*NcknxT{Hh k2R qQ46R 1021N~/fwm mN~ wm m~NmN^\:Sv_SS0R^l͑Ɖ NR gsQlcknxv/f A0wm4l+TA \ё^\>eeQwm4l-NSN6RSё^\A B0)R(unoPlS5u/f\Sf[lS:N5u C0Nwm4l-NcSnvǏ zmS'lS؏SS^ D0wm^Yё^\~8hw+T gFe0Mn0Co0BI{ё^\ 20NANh?OR_W8^pe NRlcknxv/f A012 g NaHSO4(WqeyP[;`pe:N0.3NA B028 g N60US(SV -N+T gvN N.*Npe:N3NA C0(W25!e S:_:N1.01105 Pae 11.2 L'll@b+TvSP[pe:NNA D08^)n N \5.6 g beQϑvSmkxx-Nly5uP[pe:N0.3NA 30 NR[eHh0Rvvv/f A0dSFe|-Nm gvI2RpOI2GSNS B0dSNaClVSO-Nm gvMgCl2ReQKOHnmTǏn nmS~vf C0dSxx-Nm gvxx"lReQǏϑv"l'lSnm S~vf D0dS"l'lSA-Nm gv"l'lS>eeQ4l-NdbbFmrT ReQϑ/lSAnm Rϑ4lǏnmm 40 NRňn@b:yv[ N0Rvvv/f  SHAPE \* MERGEFORMAT  50S\ϑMgO0A12O30SiO20Fe2O3vmT|+g ReQǏϑvx EQRS^TǏn _0RlmXTnmY0 NRScknxv/f A0 NVy'lSir[^v4lSir-N Al(OH)3x'`g:_ B0TlmX-NnReQ]xx lmbaban C0nmY-Nv3yP[;N/fMg2 0Al3 0Fe3 0H D0nmY-NReQǏϑ(l4l @b_lm:NFe(OH)3TMg(OH)2 60x(W4l-Nn㉦^_\ FOfnNKInm V:NSuS^I2(aq)+I-(aq)I3-0]w(W N T)n^ NS^vs^a8^peYSV NRl Ncknxv/f A0 NS^ckS^:N>epS^ B0[[M6Rx4l :NX'Yxvn㉦^SReQ\ϑvKI C0(uS^StSdSkx|-N\ϑvxUS( D0 NSO|-NReQ s^a NyR 70(Wc[sX-N NRT~yP[SN'YϑqQX[v/f A0ernm-N[Ag(NH3)2]+0 K+0 H+ 0NO3 B0nRZ^ՋmNervnm-NCO32 0K+0ClO 0AlO2 C0(Wc(H+)/c(OH ) = 11013vnm-NNH4+0Ca2+0C1 0K+ D0ReQݔ|TNu'Yϑ"llvnm-NNH4 0Na 0NO3 0SO42- 80 NRyP[e z_fNQcknxv/f A0T50 mL 1 molL 1fwnm-NneQpen0.1 molL 1Ba(OH)2nm Al3 +2SO42 +2Ba2++3OH === Al(OH)3!+2BaSO4! B0TKINzkxxvmTnm-NeQ'll4H++O2+6I === 3I2+2H2O C0a mol FeBr2nm-NeQa mol Cl22Fe2++2Br +2Cl2 = Br2+2Fe3++4C1 D0(Wonwpp4l-NReQϑxx"lAnmCa2++ OH + HCO3 == CaCO3!+H2O 90Nyx~s|{Y8TD"ll (uُyPge6RYvN!k5u`lStYV2u@b:y 5u`lv5u(:N6 mol/L KOHnm NRl-Ncknx  A0>e5ueK+yTg B0>e5ue5u`lgv5ugS^:NH2 2e- = 2H+ C0>e5ue5u`lckgv5ugS^:N NiO(OH)+H2O+e- = Ni(OH)2+OH- D05u`lEQ5ue\x5ugN5unvckgvޏ 100,{ NhTgCQ }R [vSP[gY5uP[B\ N0RqT@b5uP[pe\N!kYB\TgQB\5uP[peKN] FOI{NgQB\5uP[pevcktepe P0 NRlcknxv/f A08^)n N 3z[X[(WvRv'lSirNpxnmS^ B0RvgؚN'lSir[^v4lSir/f:_x C0(WV`e RvUS(^\N TN{|WvvfSOD0(W8^)n N Rvl`"lSir(Wzzl-N3z[X[(W 110 NV/fgf[!h[[NSf[ՋBRFU^pNVvkxxՋBRh~{ NvRQ[ ncdk NRlcknxv/f A0kxxvir(vϑSm^:N9.2 mol" L-1 B0M6R200 mL 4.6 mol" L-1vzkxxSkxx25 mL C0kxxNI{SOyv4lmTT@b_nmSm^:N9.2 mol" L-1 D0kxxNI{SOy4lmTT(ϑRpe'YN49% 120CQ }8vUS(S8N9b_bvSTir cY NV@b:yvsQ|SulS(vQ-Nm`"n,NGW:Ncktepe) NRlcknxv/f A0X:NFe0YS:NCl0Br0I B0X:NFe0YS:NCl C0XN[:Nё^\CQ } D0X0YSGW:N^ё^\CQ } 130zpQ]zAm zYV O)Y6qlNuR'lS v^(WyrkvqphV-NO'llT)Y6qlqp CH4(g)+2O2(g)=CO2(g)+2H2O(g) PSS^[SuvS^ :NCH4(g)+H2O(g) CO(g)+3H2(g) "H1=+216 kJ/mol CH4(g)+ CO2(g)2CO(g) + 2H2(g) "H2=+260 kJ/mol  NQvQNs^avX[(W NRlcknxv/f A0X'YPSS^[vS:_ 2upvlSsQ\ B0PSS^[~c(W550^750! vvN/fcؚCH4 lSvs C0nqp[v;Nvv/fNuCO2T4ll\OSelN2upS^ D0催PSS^[-Ns^ae [hV-Nc(CH4)=a molL 1, c(CO)=b molL 1,c(H2)=c molL 1 ReQPSS^[vCH4vir(vϑ:Na+(b+c)/4 140(WSV@b:yňn-NۏL(lvPS'lS[_ NtQvSm(l4l-N NeeQzzl \~pv”NcNt-Nv^cяmb0S^Ǐ z-N S‰[0Rt-N g~hrlSONu ”NY~Oc~p0 NR gsQlv/f  A0S^Tnm-N+T gNO3- B0S^Tnm-Nc(H+)X'Y C0[Ǐ z-N gSTS^Su D0[Ǐ z-NNH3H2Ov5uy8^pe NSSuSS 150 NRS-Ncknxv/f A0pHv TvCH3COONanm0C6H5ONanm0Na2CO3nm0NaOHnm c(CH3COONa)c(C6H5ONa )c(Na2CO3)c(NaOH ) B0(W8^)n N 10 mL 0.02 molL 1 HClnmN10 mL 0.02 molL 1 Ba(OH)2nmEQRmT mTTnmvSOy:N20 mL RnmvpH = 10 C0\pH = 3vNCQ1_xHATpH = 11vNaOHnmEQRmTTN[ g c(OH-)c(H+)c(Na+)c(A-) D0\0.2 molL 1vvxN0.1 molL 1vNaAlO2nmI{SOymT vQnm-NyP[Sm^1u\0R'Yvz^:Nc(OH-)c(Al3+)c(H+)c(Na+)c(Cl-) 1608^)ne Ksp[Mg(OH)2] = 1.110 11 Ksp(AgCl) = 1.810 10 Ksp(Ag2CrO4) = 1.910 12 Ksp(CH3COOAg) = 2.310 3 NRS Ncknxv/f A0Sm^GW:N0.2 molL 1vAgNO3nmTCH3COONanmI{SOymTN[NuCH3COOAglm B0\0.001 molL 1vAgNO3nmneQ0.001 molL 1vKClT0.001 molL 1vK2CrO4nm-N HQNuAg2CrO4lm C0c(Mg2+):N0.11 molL 1vnm-NNuMg(OH)2lm nmvp(c6R(W9N N D0(WvQNagN NSv`Q N TqTAgCl4lnm-NReQNaClnm Ksp(AgCl) NS 170YVh:yS^2SO2(g)+O2(g)2SO3(g) "H<0vckS^sevSS`Q Ջ9hncdkf~$Re NRlScknxv/f A0t1eQ\NSO2vSm^ XRNSO3vSm^ B0t1eMNON)n^ s^aTckS^eTyR C0t1eQ\NS:_ s^aTS^eTyR D0t1eXRNSO2TO2vSm^ s^aTckS^eTyR 1801u'lSܔT'lSvmTira g ReQ2 molL 1vkxxnm50 mL p`}Y[hQn \a gvmTir(WǏϑvCOlAm-NRpEQRS^ QtSTiRYOVSOv(ϑ:N A01.6a g B0a-1.6) g C0a-3.2) g D0el{ 190M|NSԈyf[[8leP0e,gyf[[ NOQgTVyf[[lNl\V(WSsTxvz~rgIQˆ}vGFP ebZPQzQ!.s RNN2008t^\Sf[VY.~xvzSsGFP-NvurWV~gYV@b:y NR gsQlcknxv/f A0 g:gir N^\NeSTir B01 mol g:girRP[-NS g1 molxxS. C0 g:girNn4lSSuRbS^ D0 g:gir NNzkxxS^ 200]w(Wt! gBa(OH)2znm-N c(H ) = 10-a molL 10c(OH ) = 10-b molL 1 Na+b=160T勶nm-NnReQpH = cvvx t! NKm_mTmvpHY NV@b:y ^SBa(OH)2nmSOy/mLvxSOy/mLmTmpH122.00010222.0018.009322.0022.008GPmTeSOySS_eu N Rc:N A03 B04 C05 D06 210gzkxxTz]xxvmTnm200 mL s^GWRb$NN TvQ-NNN-NnReQܔ| gYn19.2 g]w]xxS؏S:NNOlSO 0TSNN-NnReQ| NulSOvϑ|(ϑXRvSSYV@b:y0 NRRgb~gv/f  A0mTm-NNO3-vir(vϑ:N0.2 mol B0OAkNu/fNO ABkS^:N2Fe3++Fe = 3Fe2+ BCkNu"ll C0nm-Ng~n(:NFeSO4 D0c(H2SO4):N5 molL 1 220)Y6qwm4l-N;N+T gNa+0K+0Ca2+0Mg2+0Cl 0SO42 0Br 0CO32 0HCO3 I{yP[0kpRS5uqdqc>ev+TSO2vplS)R(uwm4l1kx vQ]zAm zY NV@b:y NRlv/f A0)Y6qwm4lpH H" 8vSV/f1uNwm4l-NvCO32 0HCO3 4l B0 'lS /f)R(u'll\H2SO30HSO3 0SO32 I{'lSubSO42 C0 S^0zʑ eR)Y6qwm4lvvv/f-NT0zʑ~'lSTwm4l-Nubvx D0 c>e Qegvwm4l-NSO42 vir(vϑSm^NۏeQ8T6eTXv)Y6qwm4lv T 230s g(uyP[NbcTwX\O5ugv5ui5uqTvNa2SO4nmuNNaOHTH2SO4 NRl-Ncknxv/f A0lSOA/fH2 nmE/fzkxx B0lSOB/fH2 nmD/fNaOHnm C0Na2SO4 nm1uGSReQ FSeQzkxx D0[geEQ4l N(ueEQNa2SO4 ,{a!wS^ b qQ54R 24011R ]w'lS'`KMnO4>HNO3Bi CQ }+3N3z[ Na3BiO3nm:Ner0SN[ϑvMn(NO3)2nmO!kۏL NR[ saU_Y N0 `$nRϑvNa3BiO3nm nmS:N+}~r0 a$~~nRϑH2O2 +}~r*S v^ gllNu0 b$QReQϑvPbO2VSO VSOn nmSS:N+}~r0 c$gTeQϑvSO2lSO VT{ NR  = 1 \* GB2 t$ BiCQ }(WhTgh-NvMOn   = 2 \* GB2 u$KMnO40H2O20PbO2'lS'`1u:_0R1_vz^:N   = 3 \* GB2 v$[c$-Nvsa:N  w$[a$S^vyP[e z_/f  x$[b$S^vyP[e z_/f_ 0 2509R ]N6RYؚ0x/f0v͑STirT8^(uv'lSBR0N N/f]N N(uo0w6RYؚ0xvNy]zAm z0  SHAPE \* MERGEFORMAT  1 KMnO4znm/fNy8^(uvmkBR0vQmkStN NRir(v Tv/f_____kXNS 0 a084mkmNaClOnm b0S'l4l c0Z d075%R| 2 ؚ0xOX[(WhrՋBRt NRՋBROX[ NhrՋBRtv/f_______kXNS 0 a0Sm]xx b0]xx c0/l4l d0px 3 NAm z-NSN_sO(uvir( g 0 QSf[_ 0 4 NQir(_sN6RYǏ z-Nv_c1Y R1 mol MnO2S6R_ mol KMnO40 5 uN-N~QvCO2lSO0傞[[6RY~QvCO2 @bՋBRg}Y b kXNS 0 a0wppw b0zHCl c0zH2SO4 d0~x 6 d\O`!v Ty/f d\Oa!9hncKMnO4TK2CO3$Nir((W kX'`( Nv]_ Ǒ(u kXd\Oek 0pǏn_0RKMnO4|vfSO0 26012R ]wXTYT/f1u$Ny8^CQ }~bvSTir A0B:NlSO G:N}vrlm F/fNy$N'`"l'lSir (W5u_Ye nm-N g}vr lmNu FO@w5u㉄vۏL }vrlmnn gTS:NonnmC g$Nyn( X0W0C0Ev0qrS^GW:NĞr0Tir(KNvsQ|YV@b:yRNir]~weu dlSOvS^Y vQYOS^GW(Wnm-NۏL 0  VT{ NR (1)X0Y0WvSf[_R+R:N 0 0 (2)QQS^`$vyP[e z_ (3)ANBS^ub1 mol De>eQpϑ:N92.3 kJ RdkS^vpSf[e z_:N (4)TonnmC-NReQ10 molL 1vkxx S_R50 mLeMb_YQslm GP5uǏ z-NnmSOySS_eu N SXTYmTmvSOy:N100 mL Ynmvir(vϑSm^:Na molL 1 RXnmvir(vϑSm^:N molL 1+TaNpe_h:y 270]wHCNv~g:N EMBED ACD.ChemSketch.20  R CN RCOOH R Cl+CN R CN+Cl R:NpW 0ss|0u#nI{^ir4lSuTS6R_| [/f͑vS]Se [(WN[agN NSSuN NSS12R  (1)QQS^{|Wa$ 00000 c$ 0000 0 (2)QQS^b$vSf[e z_  QQf|-N+T gWvN*NSf[S^e z_ 0 (3)E:NsrSTir RvQ~g{_ 0 (4)E:NؚZir RvQ~g{_ 0 28010R (W537!01.01105 Pae _[ySSv[핹[hV-NEQeQ1 mol XT3 mol Y dke[y:NV L0OcR`)nR`S SuS^X(g)+3Y(g) EMBED PBrush 2Z(g) 0Rs^ae s^amTlSO-NZvSOyRpe:N0.50 (1) 0Rs^ae XvlSs~:N 0 (2) Oc N)n^TS:_R`[ NS T[hV-NSEQeQ4 mol Z RS^0Rs^ae s^alSO-NY vSOyRpe:N [hVv[y:N L0 (3) S N[yV[ NSv[핹[hV Nc6R)n^ NS O2 mol XT6 mol YS^ 0Rs^aes^alSO-NZvSOyRpeN:N0.5 R[핹[hVv[y:N 0 (4) )n^N:N537! [hVSOyOcVL NS(R`[) _vQ-NEQeQa mol Xvb mol Y OS^0Rs^a ُes^alSO-NZvSOyRpeN:N0.5 SO|S:_:N1.01105 Pa a: b = 1: 3 Ra = 0 Sf[T{Hh N0 bk\S gN*NcknxT{Hh k2R qQ46R 123456789101112CBDACDCCCADD1314151617181920212223ADABABBDDDB 2401~4kzz2R ,{5zz3R qQ11R  = 1 \* GB2 t$MOn ,{mQhTg ,{d!A   = 2 \* GB2 u$1u:_0R1_vz^:N PbO2>KMnO4> H2O2   = 3 \* GB2 v$sa:N +}~r*S ub}vrlm  w$ 2MnO4-+5H2O2+6H+=2Mn2++5O2!+8H2O  x$_ 5PbO2+2Mn2++4H+=5Pb2++2MnO4-+2H2O 0 250kzz1R qQ9R 1 ___ ab kXNS 02 _ d kXNS 0 3 MnO2  KOH 4 23 mol5  kXNS cd 0 6 Ty/f Ǐn  n㉦^ kX'`( Sm)~vf kXd\Oek 260kzz2R qQ12R (1)X0Y0WvSf[_R+R:N NaCl0AlCl3 0NaOH (2) Al3+ + 3AlO2-+ 6H2O == 4Al(OH)3! (3) H2(g) + C12(g)=2HCl(g) %H= -1846 kJ/mol (4) a+10 molL 1 270kzz2R qQ12R t$a$ RbS^ , c$ SNS^ u$ EMBED ACD.ChemSketch.20  + 2Cu(OH)2 Cu2O!+ 2H2O v$  EMBED ACD.ChemSketch.20  w$  EMBED ACD.ChemSketch.20  280kzz2R qQ10R (1) 66.7% 0 (2) 0.375 0 (3) 0 (4)a = 1.5mol 0 Q4l SiO2-Nm gNH4Cl D0Rppog RySiO2TNH4Cl Smvx Na2Snm KMnO4 C0kKMnO40Cl20Sv'lS'` A0[ϑKm[Sf[S^s MnO2 H2O2 ~X4l 4l Na B0NaT4lS^vpHe^  EMBED Word.Picture.8 \* MERGEFORMAT  +Tkxpl 'lS S^0zʑ )Y6qwm4l QSTpl 'll )Y6qwm4l 8T6eTX c>e + A C B E D yP[Nbc F G |x MnO2 q KMnO4 K2CO3 MnO2 KOH H2O K2MnO4 CO2 d\O`! KMnO4 K2CO3 d\Oa! km KMnO4|vfSO r^q KMnO4vfSO wppۂS KOH zzl H+ H2O _+ + 4V 3 NL 4V 3 NL  BDRTXZ^`| ~ Ľzrlf`YSM 5aJ\ 5aJ\ 5o(aJ\ 5aJ\ CJaJ5 CJaJ5CJo(aJ5 CJaJ5CJQJaJ5 CJaJ5o(aJo(aJaJaJaJ OJQJaJaJ OJQJaJaJ OJQJaJaJ OJQJaJaJaJaJ 5aJ\ OJQJ^J B*`JphCJOJQJo(aJCJ,PJo(aJ5CJ$OJQJo(5 0 2 4 b d " $ < > V X Z \ l p ¾{pgd]ZVH*aJaJ OJQJaJaJB*`JphaJB*`JphaJH*B*`JphaJ6B*`JphaJB*`JphaJH*B*`JphaJaJH*aJ6aJaJH*aJaJaJaJH*aJ6aJaJaJaJB*`JphaJB*`JphaJaJaJaJaJmHsHnHtHaJUaJaJ 0 2 4 6 T ^ ` x z   f h źwne\SHB*`Jpho(aJB*`JphaJB*`JphaJB*`JphaJB*`JphaJB*`JphaJB*`JphaJH*B*`JphaJB*`JphaJB*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJaJB*`JphaJaJH*aJ6aJaJaJH*aJ6aJaJh x z   pr·yvrokhda]ZVSPMIH*aJaJaJaJH*aJaJH*aJaJH*aJaJH*aJaJH*aJaJB*`JphaJB*`JphaJB*`JphaJUjUB*`JphaJ$B*`JphaJmHsHnHtHUUB*`JphaJB*`JphaJB*`JphaJUB*`JphaJaJ4*aJaJB*`Jpho(aJB*`Jpho(aJ JLZ\^`d·ysnhc]WROaJKHaJ H*KHaJ H*KHaJKHaJ H*KHaJKHaJ H*KHaJKHaJUB*`JphaJH*aJaJH*aJaJB*`JphaJH*B*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJaJaJaJaJ$&`b "$&(ú}ri^UJAB*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJaJB*`JphaJB*`JphaJB*`JphaJKHKHaJKHaJKHaJKHaJKHaJKHaJKHaJKHaJ      !"#$%&'()*+,-./0123456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxyz|}~(*2468\^bfhprz|~ø|qf[RF=B*`JphaJB*`JphaJ6]B*`JphaJB*`JphaJH*B*`JphaJH*B*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJH*B*`JphaJB*`JphaJB*`JphaJH*B*`JphaJH*B*`JphaJB*`JphaJH*·{pg\SH?6B*`JphaJB*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`Jpho(aJB*`JphaJB*`JphaJH*B*`JphaJB*`JphaJ6]B*`JphaJB*`JphaJH* "&(FPRTtxypg\SH?B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJB*`JphaJaJB*`JphaJB*`JphaJB*`JphaJH*B*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJH*  ź~sj_VKB9B*`JphaJB*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`Jpho(aJB*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJB*`JphaJB*`JphaJH* 8:>@FHJPRVX^`bdfhype\SJ=B*`JphaJmHsHB*`JphaJB*`JphaJB*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`Jpho(aJB*`JphaJB*`Jpho(aJH*B*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJmHsHB*`JphaJhj|~ȿxlcXOD;B*`JphaJB*`JphaJH*B*`JphaJB*`Jpho(aJB*`JphaJB*`Jpho(aJH*B*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJ6B*`JphaJmHsHB*`JphaJH*B*`JphaJB*`JphaJ6 "$&(,.68>zneZQF=B*`JphaJB*`JphaJH*B*`JphaJB*`Jpho(aJB*`JphaJB*`Jpho(aJH*B*`JphaJH*B*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*B*`JphaJB*`JphaJmHsHB*`JphaJB*`JphaJB*`JphaJH*B*`JphaJB*`JphaJH*>@BDH  $&(JLNRTVXZ^`bdÿ{xtqmif]B*`JphaJaJH*aJH*aJaJo(aJaJ 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