ࡱ> oqlmnq` R{bjbjqPqP::n$e6 6 6 6 6 6 6 Z mmm8>mDn$2o:opppsu:vTQSSSSSS$@h8wQ6 {s^s{{w6 6 ppȤ{6 p6 pQ{Q6 6 po wKAm0͟ޤ05Nh&dD$6 ŝv.wrw\wvvvwwvvv{{{{,K!KJ hV 6 6 6 6 6 6  ,{N qpp n 0vh[*0 10Nqppvi_ v^ۏL{USv{0 20wSSf[S^-NϑlSvSV Q8^vϑlSb__0 30NSf[(W㉳QnqS:g-Nv͑\O(u0wS~n0cؚϑ)R(uHesv[EaIN0 40NDn0n0sO/fS_N>yOv͑pp0 ͑ppqppvi_SvsQ{0 0pht0 wƋpNS^pv{|W 10qpp (1)i_(W101kPae 1molir(qpub3z[v'lSire@b>eQvpϑ SZPir(vqpp0qppvUSMON,(ukJ/molh:y0 (2)laqpp/fS^pvNyb__0O(uqppvi_et NRp0 `$ ĉ[/f(W101 kPaS:_ NKmQpϑ0fN-NcOvqpppenc/f(W101kPa NKm[Qegv0V:NS:_ N T S^p g@b N T0 a$ ĉ[Sqirvir(vϑ:N1mol(ُ7hMb gSk'`)0Vdk h:ySqirvqppvpSf[e z_-N SqirvSf[ϑpe:N1 vQNir(vSf[ϑpe8^QsRpe0OY C8H18vqpp:N5518kJ/mol (upSf[e z_h:yR:N C8H18(l)+ INCLUDEPICTURE "http://www.hxfdz.com/upload_files/article/57/2_kivss__013AQ034-4.gif" \* MERGEFORMATINET O2(g)= 8CO2(g)+9H2O(l)0%H= 5518kJ/mol b$ ĉ[ubir:N3z[v'lSirOYC! CO20H !H2O(l)0S !SO2I{0 C(s)+ INCLUDEPICTURE "http://www.hxfdz.com/upload_files/article/57/2_fu4uw__013AQ1c-5.gif" \* MERGEFORMATINET O2(g)=CO(g)00%H= 110.5kJ/mol C(s)+O2(g)=CO2(g) 00%H= 393.5kJ/mol Cvqpp:N393.5kJ/mol N/f110.5kJ/mol0 c$ Sqppe (uck

eQ393.5kJvpϑ0 20-NTp (1)i_(Wznm-N xߍxSu-NTS^ ub1mol H2O ُevS^pS-NTp0 (2)-NTpvh:yH (aq)+OH (aq)=H2O(l)0%H= 57.3kJ/mol0 (3)la `$ ُ̑vznmN,Blxnm-Nvc(H )d"1mol/L xnm-Nvc(OH )d"1mol/L0ُ/fVSmxnmTSmxnmvNzʑeO>eQpϑ0 a$:_xN:_xv-NTS^vQ[(/fH TOH S^(sSNx0xvy{|esQ) ǏY!k[Km[ 1molH T1molOH S^ub1molH2Oe >eQpϑ57.3kJ0vQpSf[e z_:N H (aq)+OH (aq)=H2O(l)%H= 57.3kJ/mol Vdk NR-NTS^v%Hv T :N 57.3kJ/mol0 b$ -NTp/fNub1molH2O:NWQ V:Nh:y-NTpvpSf[e z_-N 4lvSf[ϑpe:N1 vQx0xbvvSf[ϑpeSN:NRpe_{Nub1mol4l:NhQ-NTS^[a:Nznm:_xN:_x-NTeub1mol H2OGW>ep57.3kJ 1_xb1_x5uy8T6epϑ @bN[NSR-NTS^ev-NTp\N57.3kJ/mol0 wƋpNn 10+TIN n1\/fcOϑv6qDn [SbSwqe03IQ0ΘR0Am4l0noPlSgI I{I{0bVvMRO(uv;Nn/fSwqe0 20bVnvsr (1);N/fSwqetυϑ gP N NQu g~\gz0 (2)n)R(usNO jm9%N͑0 (3)nPϑ0N[ bVvNGWnb gϑNO0 (4)яt^egnv;`m9ϑNNGWm9ϑ`QHT NMR FO/f N6qQsNnqS:g0 3en {|W*Y30uir0Θ0"l00Wp0wm mTuir(I{0 yrpDn0N[ SNQu l galgb_\alg0 0ĉ_elc[0 N0kqppN-NTp 00qpp-NTpv TpϑSS>epS^%H%H<0 USMOkJ/mol Nv TpS^agN101kPa(Wznm-NS^irvϑ1mol(O2vϑ NP)S/f1mol _NS/f0.5molubirvϑ NPϑH2O/f1molS^pv+TIN1molS^ir[hQqpe>eQvpϑ N TS^irqpp_N N T0ub1molH2Oe>eQvpϑ N TN0mTirqpS^pv{US{-----ASW[NSl 010ASW[NSl/fۏLN~RmTirs^GWϑN~Rϑ{vNy{Oel0QS cM(s^GW) = M1n1/(n1+n2) + M2n2/(n1+n2){v GWS(uASW[NSl{_-N M(s^GW)h:ymTirvgs^GWϑ M10M2Rh:y$N~R[^vϑ0Yh:ys^GWRP[ϑ M10M2Rh:y$N~RTꁄvRP[ϑ n10n2h:y$N~R(WmT ir-N@b`SvN n1:n2(W'YYpe`Q Nh:y$N~Rir(vϑKNk ge_NSN/f$N~Rv(ϑk Y(WۏL gsQnm(ϑ~vRkSm^v{0ASW[NSl8^(u NBl{mTlSOs^GWRP[ϑS~b0mTps^GWRP[_S~b0 TMO }SP[~vR+Tϑ0nmvM6R0mTirvS^I{_NSN^(u(WmTirqpvS^p{-N0 20^(u>NO 00O: ]w NR$N*NpSf[e z:2H2 (g) + O2 (g) = 2H2 O(l) 0%H-571.6 kJ/mol C3 H8 (g) +5O2 (g) = 3CO2 (g) + 4H2 O(l) 0%H-2220 kJ/mol, [Kmw"llTNpvmTlSOqQ5id\[hQqpe>ep3847CS&q, RmTlSO-N"llTNpvSOyk/f A. 1:3 0 B. 3:1 0 C.1:4 0 D. 1:1 [Rg] 00000000000  INCLUDEPICTURE "http://www.hxfdz.com/upload_files/article/57/2_ay1rh__013AV4F-15.jpg" \* MERGEFORMATINET  009hnc;`pϑ[R`, ndk_v/f 285.8X + 2220 Y = 769.4 (X+Y) SwX :Y ^:Nir(vϑk,EeASW[NSl_Qv/fir(vϑk, sSSOyk 0xQOg0 {|WNi_v^(u 001 NRpSf[e z_-N %Hcknxh:yir(vqppv/f(0 ) ACO(g) +1/2O2 (g) =CO2 (g) %H-283.0 kJ/mol BC(s) +1/2O2 (g) =CO(g) %H-110.5 kJ/mol CH2 (g) +1/2O2 (g)=H2 O(g) %H-241.8 kJ/mol D2C8 H18 (l) +25O2 (g)=16CO2 (g)+18H2 O(l) %H-11036 kJ/mol ㉐g A ,ge(Wgqppv[IN T{HhB N/fir([hQqpub3z[v'lSir T{HhCubirH2 O(g) N/f3z[v'lSir vQ3z[v'lSir:NH2 O(l) T{HhD N/f1molv[hQqp N&{Tqppvi_0 T{Hh A {|WN gsQqppv{ 00 (WN[agN N COTCH4 qpvpSf[e z_R+R:N 002CO(g) + O2 (g) = 2CO2 (g) %H =-566 kJ/mol 00CH4 (g) + 2 O2 (g) = C O2 (g) + 2H2 O(l) %H =-890 kJ/mol 01u1molCOT3molCH4 ~bvmTl(W NagN N[hQqpe ʑ>evpϑ:N(0 ) A2912kJ0000 B2953kJ 00 C3236kJ0 0D3867kJ ㉐g 1molCO[hQqp>eQvpϑ/f566kJ/2 3molCH4 [hQqp>eQvpϑ/f890kJ3 ,gʑ>ev;`ϑ^S_/f(566/2+8903 )kJ T{Hh B {|W Nnv)R(u  bVN'lSxvc>eϑMOE\NLu,{N :NQ\N'lSxُy)n[lSOvc>e NRce N[v/f A. 'YRSU\"ln00B. EQR)R(u*Y3 C. NO(u+Txn0D. cؚn)R(us0 ㉐g  vMRhQtn؏;NO`+Txir(vqp0Q\N'lSxvc>e^(W_Sen cؚn)R(usI{eb NR+Y0 T{Hh C0  (1997hQV)nSRR:NN~nTN~n06qLu-NNsbb__cOvny:NN~nO`vQ[nvϑc6RSvny:NN~n0"ll/fNyؚHe l galgvN~n [SN1u6qLu-N'YϑX[(Wv4leg6RS2H2 O(l)=2H2 (g)+O2 (g)H=517.6 kJmol-1 00(1) NRScknxv/f0(0 ) A.5u/fN~n0 B.4lR/fN~n C.)Y6ql/fN~n D4ldql/fN~n (2)sQN(u4l6RSN~n"ll N NxvzeT Ncknxv/f0(0 ) A.gb4lv"l/fSNqpvir( VdkSxvz(W4l NR㉄v`Q N O"lb:NN~n B.l\*Y3IQZƖ Nuؚ)n O4lR㉧Nu"ll C.[~bؚHePSBR O4lR㉧Nu"ll, Teʑ>eϑ D.[~byrkSf[ir( (uN_S^Nn NR4l6RS"ll ㉐g 00(1)1u~Oo`Sw4lR0)Y6ql/fN~n 5u/fO`dqqpvpb4l0Θ08hI{lS 6R_vn 4ldql/fCOTH2 vmTl [/f1u&qpT4l}l(Wؚ)n NS^ubEe5uT4ldqlGW:NN~n (2)4l,gv^ Nqp 4lRTubvH2 MbSNqpv^>eQpϑ 4lvR/f8TpS^ (WSu8TpS^e S^ir8T6eϑMblS:Nubir T{Hh (1)A0C00(2)A0C W@x~ 1 NRlcknxv/f0 A(W101kPae 1molir([hQqpe@b>eQvpϑ SZPir(vqpp BxTxSu-NTS^ub1mol4l ُevS^pS-NTp Cqppb-NTp/fS^pvy{|KNN D(Wznm-N 1molCH3 COOHT1mol NaOH[hQ-NTe>eQvpϑ:N57.3kJ 2]w2CO(g)+O2(g)=2CO2 (g); %H= 566.0kJ/mol.1udk$ReCOvqpp/f A. -283.0kJ/mol000B. -566.0kJ/mol C. 283.0kJ/mol00D. 566.0kJ/mol 3:_xN:_xvznmSu-NTS^vpHe^ H+ (aq)+OH- (aq)=H2 O(l) %H=-57.3kJ/mol T1L0.5mol/LvNaOHnm-NReQzx0SmH2 SO4 0z]xx Rp`}Y[hQS^evpHe^%H0%H2 0%H3 vsQ|cknxv/f A. %H1 >%H2 >%H3 00 B. %H1 <%H3 <%H2 C. %H2 >%H1 >%H3 00 D. %H1 >%H3 >%H2 42upT"llqpvpSf[e z_R+RY N CH4 (g)+2O2 (g)=CO2 (g)+2H2 O(l)0%H1 0 2H2 (g)+O2 (g)==2H2 O(g)0%H2 2H2 (g)+O2 (g)=2H2 O(l)0%H3 0 8^)n NSSOy:N41v2upT"llmTlSO11.2L(hQ) [hQqpTb` Y8^)n >eQpϑ:N 0A00.4%H1 0.05%H3 00000 B00 "&  D F b d f j    * , < > ú}}}}jhU ho[UaJhU ho[H*aJhU ho[OJQJ^JaJo(hU ho[5\aJhU ho[aJo(hU ho[aJ*ho6ho[5CJKHOJQJ^JaJo('ho6ho[5CJKHOJQJ^JaJ$ho[5CJKHOJQJ^JaJo(-"*2 $$1$Ifa$gdo[ $$1$Ifa$gdo[$dd1$[$\$a$gdo[gdo[$Q1$WD`Qa$gdU z{02\^jlxz"$HJVXPR*,np*,:<HJTVܶܬܬܶܬܬܬܬܬܬܬܬhU ho[H*aJhU ho[5\aJhU ho[OJQJ^JaJo(hU ho[H*aJhU ho[aJjhU ho[UaJjhU ho[UaJD24PRxz"$PRxzܿܿܿѴܿܿܿܿܿܿܿܿܖ܁܁)jhU ho[KHOJQJU^JaJ#hU ho[KHOJQJ^JaJo(hU ho[CJaJo(hU ho[CJaJ#hU ho[H*KHOJQJ^JaJhU ho[KHaJ hU ho[KHOJQJ^JaJhU ho[aJo(hU ho[aJ.24<FP[MMM $$1$Ifa$gdo[kd$$IfT\ n  0634abTPRTZxn``` $$1$Ifa$gdo[kd$$IfT4F` 06    34ab Txzn```` $$1$Ifa$gdo[kdx$$IfT4F06    34ab TYKKKK $$1$Ifa$gdo[kdH$$IfT4\` n  0634abT"YKKKK $$1$Ifa$gdo[kd($$IfT4\n  0634abT"$&4rYKKKK $$1$Ifa$gdo[kd$$IfT4\n  0634abTBRYTTDDD$dd1$[$\$a$gdo[gdo[kd$$IfT4\n  0634abT(*TVnpIJĐ{e{e{O{e{O:(hU ho[KHOJQJ^JaJmHsH+hU ho[KHOJQJ^JaJmHo(sH+hU ho[H*KHOJQJ^JaJmHsH(hU ho[KHOJQJ^JaJmHsH&hU ho[5KHOJQJ\^JaJh#KHOJQJ^JaJ#hU ho[KHOJQJ^JaJo( hU ho[KHOJQJ^JaJ)jhU ho[KHOJQJU^JaJ)j hU ho[KHOJQJU^JaJLV~J p !!!6""""Z# $1$a$gd#$;dd1$WD[$\$`;a$gdU gdo[$hdd1$[$\$`ha$gdo[$dd1$[$\$a$gdo[ $1$a$gdo[ (*<>NP|~ J N t x !ԾԾr\r\r+hU ho[H*KHOJQJ^JaJmHsH(hU ho[KHOJQJ^JaJmHsH#hU ho[H*KHOJQJ^JaJ hU ho[KHOJQJ^JaJ&hU ho[5KHOJQJ\^JaJ+hU ho[KHOJQJ^JaJmHo(sH(hU ho[KHOJQJ^JaJmHsH+hU ho[H*KHOJQJ^JaJmHsH$ !!!!(!*!>!@!R!T!!!!4"6"<"z"|"""""""#########.$4$:$<$@$%%(%*%6%8%}}oh#KHOJQJ^JaJh#KHOJQJ^JaJo(&hU ho[5KHOJQJ\^JaJ#hU ho[KHOJQJ^JaJo(#hU ho[H*KHOJQJ^JaJ+hU ho[H*KHOJQJ^JaJmHsH(hU ho[KHOJQJ^JaJmHsH hU ho[KHOJQJ^JaJ+Z##.$<$d%%%%%%"&r&&&''v((((($dd1$WD+[$\$`a$gdU $dd1$[$\$a$gdo[$hdd1$[$\$`ha$gdo[ $1$a$gdo[$dd1$[$\$a$gd#8%^%b%&&'''''((v(|(((((((F)H))))))))))~*****˷˒|h˷ZhttKHOJQJ^JaJ'hU ho[CJKHOJQJ^JaJo(*hU ho[5CJKHOJQJ^JaJo($hjT5CJKHOJQJ^JaJo(#hU ho[H*KHOJQJ^JaJ&hU ho[5KHOJQJ\^JaJ#hU ho[KHOJQJ^JaJo(#hU ho[H*KHOJQJ^JaJ hU ho[KHOJQJ^JaJ#( )H)n))<**+&,r,,,l--"XtXFYYY6Z dpWD`gdDdpgdo[$dd1$WDd[$\$`a$gd!$hdd1$[$\$`ha$gdo[ $1$a$gdo[$dd1$[$\$a$gdo[*****+ +++z+|+++++++++++++++,, ,,,,(,2,4,<,>,F,H,Z,\,d,f,n,p,r,t,,,ȶȶȤȤȤȤȤȤȤȤȤȤȤȤȤȤȤȤȤ{(hU ho[KHOJQJ^JaJmHsH&hU ho[H*KHOJQJ^JaJo(#hU ho[H*KHOJQJ^JaJ#hU ho[H*KHOJQJ^JaJ hU ho[KHOJQJ^JaJ&hU ho[5KHOJQJ\^JaJ#hU ho[KHOJQJ^JaJo(/,,,,,,,,,,,,,,,,,,,---- -"-0-4-6-B-D-R-T-^-`-d-f-h-j-l-------.íÈvv#hU ho[H*KHOJQJ^JaJ#hU ho[KHOJQJ^JaJo(%hDKHOJQJ^JaJmHo(sH+hU ho[KHOJQJ^JaJmHo(sH hU ho[KHOJQJ^JaJ(hU ho[KHOJQJ^JaJmHsH+hU ho[H*KHOJQJ^JaJmHsH-.4%H1 0.05%H2 0 C00.4%H1 0.1%H3 00000 D00.4%H1 0.2%H3 5v T(ϑv"ll0N'lSx0YN02up[hQqpe >eQpϑg\v/f(]wُNir(vhQqppR+R:N-285.8 kJ/mol0-283.0 kJ/mol0-1366.8kJ/mol0-890.3kJ/mol) 0A. H2 (g)0 B. CO(g) 0C. C2 H5 OH(l)0 D. CH4 (g)0 6. NRSSǏ z ^\N>epS^v/f `$ m`4lSb4ll a$ xx-NTS^ b$ SmH2SO4zʑ c$ VSONaOHnN4l d$ H2(WCl2-Nqp e$ 1_x5uy A0a$b$c$d$ B0a$b$c$ C0a$d$ D0`$b$d$ 7*gegenvyrp/fDn0N[ (WO(ue[sXealgbalg_\ NSNQu0 NR^\N*gegenhQv/f `$)Y6ql a$dq b$8h c$wl d$*Y3 e$uir( f$Θ g$"l ؚ A`$a$b$c$ Bd$e$f$g$ Cb$d$e$f$g$ Db$c$d$e$f$g$ 8 NR y-NfYN\O:NqevOpv/f `$qpeSu'lSS^ a$EQRqpvNir NalgsX b$YN/fNyQun c$qpe>eQ'Yϑvp A`$a$b$ B`$a$c$ C`$b$c$ Da$b$c$ cؚ~ 9]w25!0101kPaagN N4Al (s) + 3O2 (g) == 2Al2O3 (s) %H = -2834.9 kJmol-1 4Al (s) +2O3 (g) == 2Al2O3 (s) %H = -3119.91 kJmol-11udk_Qv~cknxv/f AI{(ϑvO2kO3ϑNO 1uO2SO3 :N8TpS^ BI{(ϑvO2kO3ϑNO 1uO2SO3 :N>epS^ CO3kO23z[ 1uO2SO3 :N8TpS^ DO2kO33z[ 1uO2SO3 :N>epS^ 10. OncN[ QQ NRS^vpSf[e z_0 1 (W25!0101kPa N 1g2uqpubCO2Tm`4le>ep22.68kJ0Rh:y2uqppvpSf[e z_:N___________________________________________0 2 ϑvN2TO2[hQS^ kub23g NO28T6e16.95kJpϑ_______________0 3 ]wb_1mol H H. 1molN H. 1molNa"N.R+Rvϑ/f436kJ0391kJ0946kJ RN2NH2S^ubNH3vpSf[e z_:N________________________________ 11(W298 K01.01105 Pa N \22 g CO2eQ750 mL 1 mol/L NaOHnm-NEQRS^ Km_S^>eQx kJvpϑ0]w(WagN N \1 mol CO2eQ1 L 2 mol/L NaOHnm-NEQRS^>eQy kJvpϑ0RCO2NNaOHnmS^ubNaHCO3vpSf[e z_cknxv/f ACO2(g) NaOH(aq)===NaHCO3(aq) H (2y x)kJ/mol BCO2(g) NaOH(aq)===NaHCO3(aq) H (2x y)kJ/mol CCO2(g) NaOH(aq)===NaHCO3(aq) H (4x y)kJ/mol D2CO2(g) NaOH(l)===NaHCO3(l) H (8x 2y)kJ/mol 12.b NRir(R+RReQv4lv%b_tQ zsS^X'}&^Ub_{v^XP[0 ]wUb_{QHQň g\ϑ4lNmbvs^:NON‰[ HQgb~r ReQ NRTNir(T SuYV@b:ySS `$NaOH|+ga$18 molL-1vH2SO4nm b$NH4NO3vfSOc$Na2O2VSOd$uwpp A`$a$c$d$ B`$a$b$ Ca$b$d$ Db$c$d$ 13. Nh-Nvpenc/f4xOW1 molir(-NvSf[.@bmvϑ  9hnc NpencVT{ NR 1 NRir(,gwQ gvϑgNOv/f________0 A.H200B.Cl20 C.Br20 D.I2 2 NR"lSir-Ng3z[v/f________ 0 A.HCl0 0B.HBr00 C.HI 3 X2+H2====2HXXNhCl0Br0I vS^/f8TpS^؏/f>epS^ ________ 0 4 v TagN N X2XNhCl0Br0I R+RN"llS^ S_mI{ir(vϑv"lle >eQb8T6evpϑgYv/f________ 0 14bdq\O:NqeSǏ NR$Ny_ _`!0C(s) O2(g)===CO2(g)0H1<0 _a!0HQ6R4ldql C(s) H2O(g)===CO(g) H2(g)0H2>0 Qqp4ldql2CO(g) O2(g)===2CO2(g)0H3<0 2H2(g) O2(g)===2H2O(g)0H4<0 VT{ NR (1)$Re$Ny_>ep_`!>eQvpϑ_______a!>eQvpϑ(kX 'YN 0 I{N b \N )0 (2)H1 H2 H3 H4vpef[sQ|_/f__________________________________0 (3)1uN6RS4ldqlvS^̑ S^irwQ gv;`ϑ______ubirwQ gv;`ϑ HN(WSf[S^e S^ir1\_______ϑMblS:Nubir VdkvQS^agN:N_______0 (4)]wFe2O3(s) 3CO(g)===2Fe(s) 3CO2(g) H1 25 kJ/mol `$ 3Fe2O3(s) CO(g)===2Fe3O4(s) CO2(g) H2 47 kJ/mol a$ Fe3O4(s) CO(g)===3FeO(s) CO2(g) H3 19 kJ/mol b$ QQCO؏SFeOvpSf[e z_______________________________________0 (5){dqǏ_a!\O:NqevaIN0 15.25!0101kPa N `$2Na(s) 1/2O2(g)=Na2O(s) %H1= 414KJ/mol a$2Na(s) O2(g)=Na2O2(s) %H2= 511KJ/mol NRlcknxv/f A.`$Ta$Nirv43yP[*Npek NvI{ B.`$Ta$ubI{ir(vϑvNir ly5uP[pe N T C.8^)n NNaNϑO2S^ubNa2O )n^GSؚubNa2OvsnR_ D.25!0101kPa N Na2O2s +2 Nas = 2Na2Os %H= 317kJ/mol 16(u50mL0.50mol/LvxN50mL0.55mol/LNaOHnm(WYV@b:yvňn-NۏL-NTS^0ǏKm[S^Ǐ z-N@b>eQvpϑS{-NTp0VT{ NR 1 N[ňn N w V-N\:\vNyst(uT/f 0 2 V:y-N(uTkXRTvňnS 0 3 pogkXnx~agv\O(u/f 0 4 'Ypog NY Nvlx~g Bl_v-NTppe

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