ࡱ> ikbcdefgh)` Rbjbj{{[6TTTTddVTW&Y&Y&Y&Y[[[HJJJJJJ$hNnE[A[@[[[n&Y&Y[2&Y&YH[HV@H&YHW /T ģ tɦ0УxIIHIH,[[[[[[[nnv[[[[[[[D)/$$/ Sf[S^Nϑ`N N0USy b(,g'YqQ6\ k\4R qQ24R) 1 NRl-Ncknxv/f(00) A(WSf[S^Ǐ z-N Suir(SSv Te NN[SuϑSS B4xOWubirhQSf[.@bvϑ'YN4xOWS^irhQSf[.@bvϑe S^:N8TpS^ Cubirv;`q'YNS^irv;`qe S^8Tp H0 DHv'Y\NpSf[e z_vSf[ϑpeesQ 0㉐g00Sf[S^Suir(SSv TeN[4O@wϑvSS AS^pI{NS^irv.;`TQSubirv.;`T sSH0 S^:N>epS^ Bubirv;`q'YNS^irv;`q S^8T6epϑ RH0 CcknxS^p NNNS^ir0ubirvr` gsQ ؏NpSf[e z_vSf[ϑpebckk D0 0T{Hh00C 2 NRS-Ncknxv/f(00) A T)n TS N H2(g) Cl2(g)===2HCl(g)(WIQgqagN NTpqagN NvH N T B8^)n N S^2A(s) B(g)===2C(g) D(g) NSۏL RS^vqSN['YN CRpvSf[S^ ubirv;`ϑN[ؚNS^irv;`ϑ DSf[S^-N_4O@wϑvSS vQhsb__S gp 0㉐g00HSNS^vY+g` gsQ NS^vǏ zesQ A yRpvvvS/fOۏS^Su NS^8Tp>epesQ YCqp/f>epS^ FOS^RpMbSu C ySf[S^-NvϑSS gYyhsb__ YIQ0p05uI{ D y0 0T{Hh00B 3..gf[u(uYV@b:yňnۏLSf[S^X 2Y===2ZϑSS`Qvxvz0S__Ջ{-NnRՋBRYe w0RՋ{-N2uY NM YNY NGS0 NRsQNS^vScknxv/f(00) `$S^:N>epS^ a$ubirv;`ϑkS^irv;`ϑؚ b$S^Ǐ zSN wb/f .X[ NX0YQ萄vϑlS:Npϑ ʑ>eQeg A`$a$b$0000000 B`$b$ C`$a$ Db$ 0㉐g002uY NM YNY NGS tQS:_X'Y )n^GSؚ fS^:N>epS^0 0T{Hh00B 4(2014Nؚ N(h)]w`$1 mol H2RP[-NSf[.eˆe8T6e436 kJvϑa$1 mol Cl2RP[-NSf[.eˆe8T6e243 kJvϑb$1uHSP[TClSP[b_b1 mol HClRP[eʑ>e431 kJvϑ NRScknxv/f(00) A"llT/llS^ub/lS"llSOvpSf[e z_/fH2(g) Cl2(g)===2HCl(g) B"llT/llS^ub2 mol/lS"llSO S^vH183 kJ/mol C"llT/llS^ub2 mol/lS"llSO S^vH 183 kJ/mol D"llT/llS^ub1 mol/lS"llSO S^vH 183 kJ/mol 0㉐g00ub2 mol HClRm1 mol H2T1 mol Cl201 mol H2T1 mol Cl2e.8T6evϑ:N436 kJ 243 kJ679 kJ,2 mol HClb.>eQvϑ:N2431 kJ862 kJ Eeub2 mol HClvH679 kJ/mol 862 kJ/mol 183 kJ/mol Rub1 mol HClvH eq \f(183 kJ/mol,2) 91.5 kJ/mol0 0T{Hh00C 5. NRlcknxv/f(00) A(2012[_ؚ)NaHCO3 H2eq \o(%))&,\s\up12(P"l),\s\do12(ʑ"l))HCOONa H2OS^-N P"l0ʑ"lǏ zGWeϑSS B(2011_lςؚ)YVh:yg8TpS^R+R(W g0ePSBRv`Q NS^Ǐ z-NvϑSS C(2011Ym_lؚ)Sf[S^ geir(ub v^u_(ϑ[R`[_Tϑ[R`[_ D(2012y^ؚ)2SO2(g) O2(g)===2SO3(g)T4SO2(g) 2O2(g)===4SO3(g)vHvI{ 0㉐g00P"l0ʑ"lGW^\NSf[SS Sf[SSvǏ z;`/f4O@wϑSS A NcknxS^irvϑؚNubirvϑ S^:N>epS^ B NcknxS^pNSf[ϑpebckk Sf[ϑpeR P H_N^R P D Ncknx0 0T{Hh00C 6S^A(g) B(g) !C(g)0HR$NekۏL`$A(g) B(g) !X(g)0H10a$X(g) !C(g)0H2 S^Ǐ z-NϑSSYV@b:y E1h:yA(g) B(g) !X(g)v;mS NRlcknxv/f (00)  INCLUDEPICTURE "E:\\vQN\\360Nv\\Sf[\\2014t^ePWh\\T\ONWORD\\6-18.TIF" \* MERGEFORMAT  AH1H H2>0 BX/fS^A(g) B(g) !C(g)vPSBR CE2/fS^a$v;mS DHE1 E2 0㉐g009hncve[_ HH1 H2 sSH1H H2 Q9hncVaSwH1>0 AycknxNV-N wQ X^:NS^v-NNir N/fPSBR ByE2^:NS^a$vS^v;mS Cy*g~QS^`$vS^v;mSTS^a$v;mS el{H Dy0 0T{Hh00A N0Sy b(,g'YqQ2\ k\6R qQ12R) 7uNmvf>f:yhVvǏ z-NO(uvSf[nmBRNF3/fNy)n[lSO vQX[PϑvR/fCO2v12 000^20 000 P (W'Yl-Nv[}TS740t^KNEN N N/fQySf[.v. Na"NF FN F1 molRP[-NvSf[.e ˆe8T6evϑ/kJ941.7154.8283.0 NRl-Ncknxv/f(00) AǏ zN2(g) !2N(g)8T6eϑ BǏ zN(g) 3F(g) !NF3(g)>eQϑ CS^N2(g) 3F2(g) !2NF3(g)vH>0 DNF38T6eϑTYgl gSf[.veˆNub NSSuSf[S^ 0㉐g00Sf[.veˆ8T6eϑ Sf[.vb_b>eQϑ $N*NǏ zv;`SOpHe^/fS^p0e.vǏ z 8T6eϑ Acknxb.vǏ z >eQϑ Bcknx yC-NS^vHS^irv.KNT ubirv.KNT941.7 kJmol 1 3154.8 kJmol 1 6283.0 kJmol 1 291.9 kJmol 1 CNF38T6eϑTl gSf[.veˆNb_b R/firtSS0Sf[S^Ǐ z-N_ gSf[.veˆNb_b D0 0T{Hh00AB 8(2014Ym_lb]N-Nؚ Ng-N)USekxTckNkxlS:NN'lSkxvϑSSVY NV@b:y NRlcknxv/f(00)  INCLUDEPICTURE "E:\\vQN\\360Nv\\Sf[\\2014t^ePWh\\T\ONWORD\\6-19.TIF" \* MERGEFORMAT  AS(s USe)===S(s ckN)0H 0.33 kJmol 1 BckNkxkUSekx3z[ Cv Tir(vϑvckNkxkUSekx@b+T gvϑؚ D`$h:yeˆ1 mol O2-NvqQN.@b8T6evϑkb_b1 mol SO2-NvqQN.@b>eQvϑ\297.16 kJ 0㉐g009hncV:y SwUSekxlS:NckNkxe>eQpϑ ckNkxvϑNO 3z[ EeA0Bycknxv Tir(vϑvckNkx^kUSekx@b+T gvϑNO Cy`$h:yeˆ1 mol S(s USe)T1 mol O2(g)-NvqQN.@b8T6evϑkb_b1 mol SO2(g)-NvqQN.@b>eQvϑ\297.16 kJ Dy0 0T{Hh00AB N0^ b(,g'YqQ4\ qQ64R) 9(14R)(2014 f!jb)N2NH2S^ubNH3vǏ z-NϑSSf~YV@b:y0(WN*NV[[yv[핹[hV-NEQeQ1 mol N2T 3 mol H2OS^N2 3H2%&2NH30Rs^a Km_S^>eQpϑ:NQ10  INCLUDEPICTURE "E:\\vQN\\360Nv\\Sf[\\2014t^ePWh\\T\ONWORD\\6-20.TIF" \* MERGEFORMAT  kXQ NRzz}v (1)Q1________92 kJ(kX > 0 < b  )0 (2)bf~/f________evϑSSf~0 (3) NagN Ns^aeH2vlSs:N________0 (4)(W)n^SOyN[vagN N eQ 2 mol N2 T6 mol H2 S^T>eQvpϑ:NQ2 kJ R2Q1NQ2vsQ|:N________0 0㉐g00NS^vV:y-NSw vQpSf[e z_:NN2(g) 3H2(g)%&2NH3(g)0H 92 kJmol 1 NQ192 kJs^ae>eQQ1 kJ pϑ Rmv n(H2)eq \f(3Q1,92) mol R(H2)eq \f(3Q1,923)eq \f(Q1,92)S_v TagNeEQeQ2 mol N2T 6 mol H2s^aT >eQvpϑQ22Q10 0T{Hh00(1)<0(2)ReQPSBR0(3)Q1/92 (4)Q2>2Q1 10(18R)(2014h]^ N!hT)yf[[)R(u*Y3R4lubv"ll(WPSBR\O(u NNN'lSxS^ub2u v^_SQvcN2u:Nqevqe5u`l0]wH2(g)0CO(g)TCH3OH(l)vqppHR+R:N 285.8 kJmol 10 283.0 kJmol 1T 726.5 kJmol 10VT{ NR (1)(u*Y3R10 mol4lmvϑ/f________kJ0 (2)2u N[hQqpubN'lSxTm`4lvpSf[e z_:N________________________________________0 (3)(W[y:N2 Lv[핹[hV-N 1uCO2TH2Tb2u (WvQNagN NSv`Q N g)n^[S^vq_T [~gY NV@b:y(lT10T2GW'YN300 !)  INCLUDEPICTURE "E:\\vQN\\360Nv\\Sf[\\2014t^ePWh\\T\ONWORD\\C14+.TIF" \* MERGEFORMAT  NRlcknxv/f________(kX^S)0 `$)n^:NT1e NS^_Y0Rs^a ub2uvs^GWs:Nv(CH3OH)eq \f(nA,tA) molL 1min 1 a$S^(WT1evs^a8^pekT2ev\ b$S^:N>epS^ c$YNApvS^SO|NT1S0RT2 0Rs^aeeq \f(n(H2),n(CH3OH))X'Y (4)(WT1)n^e \1 mol CO2T3 mol H2EQeQN[R`[[hV-N EQRS^0Rs^aT CO2lSs:N R[hVQvS:_NwYS:_KNk:N________0 0㉐g00(1)9hnc"llvqppQQpSf[e z_H2(g) 1/2O2(g)===H2O(l)0H1 285.8 kJmol 1`$ RR10 mol4lmϑ:N2 858 kJ0 (2)9hncqppQQQpSf[e z_ CH3OH(l) 3/2O2(g)===CO2(g) 2H2O(l) H2 726.5 kJmol 1a$ CO(g) 1/2O2(g)===CO2(g)0H3 283.0 kJmol 1b$ e z_a$ b$S_CH3OH(l) O2(g)===CO(g) 2H2O(l) RHH2 H3 726.5 kJmol 1 ( 283.0 kJmol 1) 443.5 kJmol 10 (3)e z_`$b$ a$S_ CO2(g) 3H2(g)===CH3OH(l) H2O(l) RH3H1 H23( 285.8 kJmol 1) ( 726.5 kJmol 1) 130.9 kJmol 10 v(CH3OH)eq \f(\f(nA mol,2 L),tA min)eq \f(nA,2tA) molL 1min 1 `$0)n^ؚS^s_ HQ0Rs^a RT2>T10S^/f>epS^ GS)ns^aTyR s^a8^peQ\ eq \f(n(H2),n(CH3OH))X'Y a$ b$0c$cknx0 (4)300 !e2uT4l:Nl` 9hncSf[S^e z_ 00000000CO2 3H2%&CH3OH H2O wYir(vϑ(mol)0010 030000000000 lSir(vϑ(mol)  3   s^air(vϑ(mol) 1  3 3   S:_KNkI{Nir(vϑKNk Rps^/pY(4 2)/4(2 )/20 0T{Hh00(1)2 858 (2)CH3OH(l) O2(g)===CO(g) 2H2O(l) H 443.5 kJmol 1 (3)b$c$0(4)(2 )/2 11(16R)Ǐ!n`t:NSf[S^v^ N/fǏ{USvxd1\[bv /fNS^ir0RubirvǏ z-N~ǏN*NؚϑvǏ!n`0YV1/f1 mol NO2N1 mol COp`}YS^ubCO2TNOǏ z-NvϑSS:yaV0  INCLUDEPICTURE "E:\\vQN\\360Nv\\Sf[\\2014t^ePWh\\T\ONWORD\\6-21.TIF" \* MERGEFORMAT  00 00V1000000000V2 (1)ՋQQNO2TCOS^vpSf[e z_ _______________0 S^v;mS/f________kJmol 10 (2)(W[핹[hV-NۏLv NS^/fSS^ RvQS^vpSf[e z_:N_______________________________________ S^v;mS:N________kJmol 10 (3)V2/fgf[u!jNV1;uQvNO(g) CO2(g)===NO2(g) CO(g)vϑSS:yaV0RV-NE3________kJmol 1 E4________kJmol 10 0㉐g00(1)V-NE1/f;mS sSS^v;mS:N134 kJmol 10ubirTS^irKNvϑ]sS:NS^p0 (2)SS^vS^vS^p^NckS^vpeep )S^ vQ-NH________________((u+T ga0bvsQ|_h:y)0 (2)V:y-Nh:yS^H2(g) eq \f(1,2)O2(g)===H2O(g)0H 241.8 kJmol 1 Rb_________kJmol 1 x________0 (3)SS Nf(u 0W^l 6R/ll ُNel/f(uCuCl2\OPSBR (W450 !)R(uzzl-Nv'llߍ/lS"lS^6R/ll0 S^vSf[e z_:N_______________________0 _eu)n^TS:_[S^pvq_T 9hnc N-Nv gsQpenc {S_S^-N g1 mol5uP[lye S^vϑSS:N________________0 0㉐g00(1)S^irvϑؚNubir Vdk/f>epS^0S^p:NS^irNubirvϑKN] sSH(a b)kJmol 10 (2)bh:yH0OSP[~T:Nl`4levϑSS vQpeeQvϑ:N31.4 kJ0 0T{Hh00(1)>ep0(a b)kJmol 10(2)9260496.4 (3)O2 4HCleq \o(=====,\s\up12(450 !),\s\do12(PSBR))2Cl2 2H2O0>eQϑ31.4 kJ N0USy b(,g'YqQ6\ k\4R qQ24R) 12012t^NLusXe-NV;N~rm9 `OLRNT NRZPl N&{T;Nv/f(00) A_S)R(u*Y30uir(I{nmn Bc^W>WvR{|V6e xSTyPgevQub/g "6 8 D F l t v : < ŴxdxdxMŴ;;#h16h16CJH*OJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph#h16h166CJOJQJ^JaJ h16h16CJOJQJ^JaJ$h16h16CJOJPJQJ^JaJ&hT`Qh165CJ,OJQJ^JaJ,o(&hT`QhT`Q5CJ,OJQJ^JaJ,o(Ll > l ,   ,Pf 0dhG$WD`0gd:! 0dhG$WD`0gd16$ sdhG$WD`sa$gdT`Q $ & P T       4 8 ܳybTE6h16h16CJQJ^JaJh:!CJOJQJ^JaJo(jh16UmHnHu-h16h16B*CJOJPJQJ^JaJph'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph#h16h166CJOJQJ^JaJ h16h16CJOJQJ^JaJ$h16h16@CJOJQJ^JaJ 06DFJNTX\^bdfnp$&68fh ﺧ}kkkk#h16h16CJH*OJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJphh16CJOJQJ^JaJo(h16h16CJQJ^JaJ h16h16CJOJQJ^JaJ*f&t \\z$ 0dhG$WD`0a$gd16 dhG$WDZ `gd16 0dhG$WD`0gd16 Z\LN`brt "0HﳠyyyyjVC$h16h16CJOJPJQJ^JaJ'h16h166CJOJPJQJ^JaJh16h16CJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph#h16h166CJOJQJ^JaJ$h16h16@CJOJQJ^JaJ h16h16CJOJQJ^JaJ$&*,.tv|~تxffQQfff)jh16h16CJOJQJU^JaJ#h16h16CJH*OJQJ^JaJjh16UmHnHu h16h16CJOJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph-jh16h16CJOJPJQJU^JaJ$h16h16CJOJPJQJ^JaJ'h16h166CJOJPJQJ^JaJܸܡ{g{P? h16h16@CJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph#h16h166CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJ h16h16CJOJQJ^JaJ$h16h16@CJOJQJ^JaJ   "*,.:<>\^`vxzTZbdfjlprtΫΫΫxΫΫΫhT`QCJOJQJ^JaJo()jh16h16CJOJQJU^JaJh16CJOJQJ^JaJo(#h16h16CJH*OJQJ^JaJ h16h16@CJQJ^JaJ#h16h166CJOJQJ^JaJ h16h16CJOJQJ^JaJh16h16CJQJ^JaJ/8$ dh$G$Ifa$gd16 0dhG$WD`0gd16   "468ﴡzzfzfzfzzfzfzf'h16h16CJH*OJPJQJ^JaJ'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph#h16h16CJH*OJQJ^JaJ#h16h166CJOJQJ^JaJ h16h16CJOJQJ^JaJ"fh"$bdܷ{{laRa{h16CJOJQJ^JaJo(h16h16CJaJh16h16CJQJ^JaJ#h16h16CJH*OJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph h16h16CJOJQJ^JaJ'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ h16h16CJPJQJ^JaJ$>JVbK66666$ dh$G$Ifa$gd16kdD$$IfTl\b_  jo0;4 lap(yt16TbdbK88888 0dhG$WD`0gd16kdE$$IfTl\b_  jo0;4 lap(yt16T  &(bjl HLϽϽϽϽϫϽϔnZnF'h16h16CJH*OJPJQJ^JaJ'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph#h16h166CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJ h16h16CJOJQJ^JaJh16h16CJQJ^JaJ h16h16@CJQJ^JaJLPRjnrt&2TFHJL`{fWfBf)jFh16h16CJOJQJU^JaJhT`QCJOJQJ^JaJo()jh16h16CJOJQJU^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph h16h16CJOJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ'h16h16CJH*OJPJQJ^JaJh16h16CJQJ^JaJ$h16h16CJOJPJQJ^JaJb.NZ !d"t"""$##F%~%%&''$ 0dhG$WD`0a$gd16 0dhG$WD`0gd16`dxz,.Zbd* , ^ ` ܸܩܗܗ܀mZIZ5Z5'h16h16CJH*OJPJQJ^JaJ h16h16CJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph#h16h16CJH*OJQJ^JaJh16h16CJQJ^JaJ#h16h16CJH*OJQJ^JaJ#h16h166CJOJQJ^JaJ h16h16CJOJQJ^JaJ$h16h16@CJOJQJ^JaJ` !!!!!`!b!t!v!~!!!!!!!!!!!!\"^"ܲܲܠܠܠܠܠܠܠܠ}hYhhT`QCJOJQJ^JaJo()jh16h16CJOJQJU^JaJ#h16h166CJOJQJ^JaJ h16h16CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph h16h16CJOJQJ^JaJ$h16h16CJOJPJQJ^JaJ^"`"b"z"|"~"""""##X#Z#l#n##############IJđđĠĠĠIJIJIJzgT$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJphh16h16CJQJ^JaJ#h16h16CJH*OJQJ^JaJ#h16h166CJOJQJ^JaJ h16h16CJOJQJ^JaJ)jh16h16CJOJQJU^JaJ)jh16h16CJOJQJU^JaJ#####$$ $$$,$0$4$6$8$P$R$T$l$n$r$t$x$z$$$$$$$$$$$$$$$$$$$$$$$$ر؝ررر؆ر؆؆رw؆؆ر؆h16h16CJQJ^JaJ-jh16h16CJOJPJQJU^JaJ'h16h16CJH*OJPJQJ^JaJ'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ.$%%"%$%6%8%:%>%@%B%F%N%P%r%t%v%%%%%%%%%.&0&H&J&^&`&&&xfxfxfffxT#h16h16CJH*OJQJ^JaJ#h16h16CJH*OJQJ^JaJ#h16h166CJOJQJ^JaJ h16h16CJOJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph'h16h166CJOJPJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ &&&&&''''((*(,(.(0(2(@(B(H(J(((((")$)*),).)X)Z)`)b)j)l)x)z)|)~)q_#h16h166CJOJQJ^JaJ)jUh16h16CJOJQJU^JaJhT`QCJOJQJ^JaJo()jh16h16CJOJQJU^JaJh16h16CJQJ^JaJ#h16h166CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJ#h16h16CJH*OJQJ^JaJ h16h16CJOJQJ^JaJ%'H(("))))B**++,@,,h--N.///8000$1@1$ 0dhG$WD`0a$gd16 0dhG$WD`0gd16~)))))))))))))))))))))))))****** *"*$*&*(***,*0*2*6*8*:*<*J*L*N*h*j*z*|**ʵʣʣʔʔʔʵۃʃʵ h16h16CJOJQJ^JaJh16h16CJQJ^JaJ#h16h16CJH*OJQJ^JaJ)jh16h16CJOJQJU^JaJ h16h16CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJ#h16h166CJOJQJ^JaJ3***** +"+2+4+:+>+B+D+P+R+T+p+t+v++++++ŲvbN= h16h16CJPJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ'h16h166CJOJPJQJ^JaJ(h16h16@CJOJPJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph h16h16CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJ++++ , ,,,,8,<,>,@,T,V,\,`,f,h,n,r,ذ؜t\tCt\t0h16h16@CJOJPJQJ^JaJmHsH/h16h16CJH*OJPJQJ^JaJmHsH,h16h16CJOJPJQJ^JaJmHsH 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h16h16CJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ$//////////R0V0\0b0j0t0z00000000000000Ъq^$h16h16CJOJPJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ'h16h166CJOJPJQJ^JaJ!h:!CJOJPJQJ^JaJo($h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ,h16h16CJOJPJQJ^JaJmHsH/h16h16CJH*OJPJQJ^JaJmHsH0001"1$1,1.1J1L1Z1\1b1f1x1z1111ıt^t^tGt^t1+h16h166CJOJQJ^JaJmHsH,h16h16@CJOJQJ^JaJmHsH+h16h16CJH*OJQJ^JaJmHsH(h16h16CJOJQJ^JaJmHsH-h16h16B*CJOJPJQJ^JaJph h16h16CJOJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ'h16h166CJOJPJQJ^JaJ@11112R33344456J666:7d7z78 | dhG$WD`| gd:!$ 0dhG$WD`0a$gd16  dhG$WD` gd:! 0dhG$WD`0gd16111111`2b22222J3L3N3P3V3`3333444555ĵģģĎj[ģIIģ#h16h16CJH*OJQJ^JaJh16CJOJQJ^JaJo()jGh16h16CJOJQJU^JaJhT`QCJOJQJ^JaJo()jh16h16CJOJQJU^JaJ#h16h16CJH*OJQJ^JaJh16h16CJQJ^JaJ h16h16CJOJQJ^JaJ+h16h16CJH*OJQJ^JaJmHsH(h16h16CJOJQJ^JaJmHsH5 555>5@5B5`5d5f5h5j5555555555ܸܦܸܦ܏|iUAi'h16h16CJH*OJPJQJ^JaJ'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph#h16h16CJH*OJQJ^JaJ#h16h166CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJ h16h16CJOJQJ^JaJ$h16h16@CJOJQJ^JaJ55P6R6T6h6j6l666666666666666İİ؟vcvQ?#h16h16CJH*OJQJ^JaJ#h16h166CJOJQJ^JaJ$h16h16@CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph h16h16CJOJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ67777$7&7:7<7>7V7Z7\7d7882868F8H8J8X8\8n8p8뭗끭o\Qo?o#h16h16CJH*OJQJ^JaJh16h16CJaJ$h16h16@CJOJQJ^JaJ#h16h166CJOJQJ^JaJ+h16h16CJH*OJQJ^JaJmHsH+h16h166CJOJQJ^JaJmHsH h16h16CJOJQJ^JaJ,h16h16@CJOJQJ^JaJmHsH+h16h16CJH*OJQJ^JaJmHsH(h16h16CJOJQJ^JaJmHsH88$808<8F8$ dh$G$Ifa$gd16F8H8^8f83$ dh$G$Ifa$gd16kdo$$IfTlrSq 804 lap2yt16Tf8n8r8z8$ dh$G$Ifa$gd16p8z8|888888888899999999999999 :":$:&:P:R:Z:\:p:r:t:v:|:﫜xxxxff#h16h16CJH*OJQJ^JaJh16h16CJQJ^JaJ)jh16h16CJOJQJU^JaJhT`QCJOJQJ^JaJo()jh16h16CJOJQJU^JaJ#h16h16CJH*OJQJ^JaJ#h16h166CJOJQJ^JaJh16h16CJaJ h16h16CJOJQJ^JaJ&z8|8883$ dh$G$Ifa$gd16kd$$IfTlrSq 804 lap2yt16T8888$ dh$G$Ifa$gd1688883$ dh$G$Ifa$gd16kd$$IfTlrSq 804 lap2yt16T8888$ dh$G$Ifa$gd168883  0dhG$WD`0gd16kd$$IfTlrSq 804 lap2yt16T898::l;;><<X=>h>>>6????6l 0dhG$WD`0gdT`Q 0dhG$WD`0gd16$ 0dhG$WD`0a$gd16|::::::::::::::; ;;;.;0;D;F;><F<H<<<<ܸܦܸܦܸܗܗܗ܀mZFZ'h16h166CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ-h16h16B*CJOJPJQJ^JaJphh16h16CJQJ^JaJ#h16h16CJH*OJQJ^JaJ#h16h166CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJ h16h16CJOJQJ^JaJ$h16h16@CJOJQJ^JaJ<<<<<<<<<<==(=*=,=F=H=|=~===========>>$>4>6>8>:>H>ص؞؞صصص؍vdd#h16h166CJOJQJ^JaJ-h16h16B*CJOJPJQJ^JaJph h16h16CJOJQJ^JaJ-jh16h16CJOJPJQJU^JaJh16h16CJQJ^JaJ'h16h16CJH*OJPJQJ^JaJ$h16h16CJOJPJQJ^JaJ'h16h166CJOJPJQJ^JaJ$H>L>p>r>|>~>>>>>>>>>>>>> ??ltvܵܢܓܵ܁n][]Dn-h,8xhT`QB*CJOJPJQJ^JaJphU h,8xhT`QCJOJQJ^JaJ$h,8xhT`QCJOJPJQJ^JaJ#h16h16CJOJQJ^JaJo(h16h16CJQJ^JaJ$h16h16@CJOJQJ^JaJ)jh16h16CJOJQJU^JaJ#h16h16CJH*OJQJ^JaJ h16h16CJOJQJ^JaJ#h16h16CJH*OJQJ^JaJCQ\SwqevO(u NMNOPM2.5[sXvalg DEQR_S)R(u~)Y6q~~ \PbkO(uTySf[TbPge 0㉐g00\PbkO(uTySf[TbPge N[E0 0T{Hh00D 2 NRpSf[e z_-NvHcknxh:yir(vqppv/f(00) ACO(g) eq \f(1,2)O2(g)===CO2(g)0H 283.0 kJ/mol BC(s) eq \f(1,2)O2(g)===CO(g)0H 110.5 kJ/mol CH2(g) eq \f(1,2)O2(g)===H2O(g)0H 241.8 kJ/mol D2C8H18(l) 25O2(g)===16CO2(g) 18H2O(l) H 11 036 kJ/mol 0㉐g00By Cl g[hQqpCy H2O(g)^:NH2O(l)Dy C8H18(l)vϑpe^:N10 0T{Hh00A 39hncxN"llS^vpSf[e z_ `$I2(s) H2(g)%&2HI(g)0H1 26.48 kJ/mol a$I2(g) H2(g)%&2HI(g)0H2 9.48 kJ/mol0 NR$Recknxv/f(00) AS^a$vNirkS^`$vNir3z[ B1 mol I2(s)k1 mol I2(g);`ϑNO35.96 kJ C254 g I2(g)-NeQ2 g H2(g)EQRS^>ep9.48 kJ DS^a$S^irv;`ϑkS^`$S^irv;`ϑؚ17 kJ 0㉐g00S^a$NS^`$vNirv T vQ3z['`v T A1u$N*NS^vHNI2vr`Sw BcknxVReQvH2:N1 mol S^:NSS^ Ee>eQvpϑ\N9.48 kJ CS^a$-NS^irv;`ϑkS^`$-NS^irv;`ϑؚ35.96 kJ D0 0T{Hh00B 4(2014T\n^ؚ N!jb)]wNH3H2O(aq)NH2SO4(aq)S^ub1 mol(NH4)2SO4vH 24.2 kJmol 1:_x0:_xvznmS^v-NTpH 57.3 kJmol 10RNH3H2O(W4lnm-N5uyvHI{N(00) A 45.2 kJmol 10000 B 45.2 kJmol 1 C 69.4 kJmol 1 D 69.4 kJmol 1 0㉐g00NH3H2O(aq)NH2SO4(aq)ub1 mol(NH4)2SO4 Teub2 mol H2O NH3H2O(W4lnm-N5uyvHx R1uve[_S_2x 2( 57.3 kJmol 1) 24.2 kJmol 1 x 45.2 kJmol 10 0T{Hh00A 5(2014VnWS NASN!hؚ NT)]w `$H2O(g)===H2O(l)0H1 Q1 kJmol 1 a$C2H5OH(g)===C2H5OH(l)H2 Q2 kJmol 1 b$C2H5OH(g) 3O2(g)===2CO2(g) 3H2O(g) H3 Q3 kJmol 1 O23 gm`e4lR|[hQqp gTb` Y0R[)n R>eQvpϑ:N(USMOkJ)(00) AQ1 Q2 Q3 B1.5Q1 0.5Q2 0.5Q3 C0.5Q1 1.5Q2 0.5Q3 D0.5(Q1 Q2 Q3) 0㉐g009hncve[_ 1 molm`e4lR|[hQqpvHH13 H2 H3( 3Q1 Q2 Q3)kJmol 1023 g(0.5 mol)m`e4lR|[hQqp gTb` Y0R[)n >eQvpϑ:N(1.5Q1 0.5Q2 0.5Q3) kJ Bcknx0 0T{Hh00B 6(2014q\NMoJWg+g)]w3.6 gx(W6.4 g'll-Nqp S^ir=\ Km_>eQpϑa kJ0SwS12.0 gx[hQqp >eQpϑ:Nb kJ RpSf[e z_C(s) eq \f(1,2)O2(g)===CO(g)0H RHI{N (00) A (a b)kJmol 1 B (a b)kJmol 1 C (5a 0.5b)kJmol 1 D (10a b)kJmol 1 0㉐g009hnca_$N*NSf[e z_ `$3C(s) 2O2(g)===2CO(g) CO2(g) H 10a kJmol 1 a$C(s) O2(g)===CO2(g)0H b kJmol 1 Req \f(1,2)(`$ a$)_C(s) eq \f(1,2)O2(g)===CO(g) H (5a 0.5b)kJmol 10 0T{Hh00C N0Sy b(,g'YqQ2\ k\6R qQ12R) 7(2014WS f^ؚ Nx)]wYNpNl[hQqpvpSf[e z_Y N `$C2H2(g) 5/2O2(g) !2CO2(g) H2O(l) H 1 300 kJ/mol a$C6H6(g) 15/2O2(g) !6CO2(g) 3H2O(l) H 3 295 kJ/mol NRlcknxv/f(00) A1 mol C2H2(g)[hQqpubl`4le>ep\N1 300 kJ B1 mol C6H6(l)[hQqpubm`4le>ep'YN3 295 kJ Cv TagN N I{(ϑvC2H2(g)NC6H6(g)[hQqp C6H6(g)>epfY DC2H2(g) NZubC6H6(g)vǏ z^\N>epS^ 0㉐g00m`4lubl`4l8Tp RA-N>ep^\N1 300 kJ cknxm`vϑkl`vϑNO RB-N>eQpϑ^\N3 295 kJ BǏ{SwI{(ϑv$N[hQqpeYNp>epY C9hncve[_ 1u3`$ a$_3C2H2(g)===C6H6(g)0H 605 kJmol 1 Dcknx0 0T{Hh00AD 81.01105 Pa N 1.0 kgNp(Wzzl-N[hQqpubCO2Tm`4l>eQ5104 kJvpϑ0 NR$Recknxv/f(00) ANp/fNyeWn BNpvqpp:N5104 kJmol 1 C1.0 kgNp(W1.01105 Pa NqpubN'lSxTl`4l>eQvpϑ\N5104 kJ DNpqpvpSf[e z_:NC4H10(g) eq \f(13,2)O2(g)===4CO2(g) 5H2O(l)0H 2 900 kJ/mol 0㉐g00Np/f O~vSwqe A1.0 kgNpvir(vϑ:Neq \f(1 000,58) mol EeNpvqpp:N5104 kJeq \f(1 000,58) mol2 900 kJ/mol B0Dcknxm`4l}lSe8T6epϑ @bN1.0 kgNp(W1.01105 Pa NqpubN'lSxTl`4l>eQvpϑ\N5104 kJ Ccknx0 0T{Hh00CD N0^ b(,g'YqQ4\ qQ64R) 9(16R)(2014^]^ؚ N!jb)S NRVhT gsQBlVT{  INCLUDEPICTURE "E:\\vQN\\360Nv\\Sf[\\2014t^ePWh\\T\ONWORD\\6-36.TIF" \* MERGEFORMAT  (1)YV/f1 mol NO2(g)T1 mol CO(g)S^ubCO2TNOǏ z-NϑSS:yaV (WS^SO|-NReQPSBR S^sX'Y E1vSS/f________ HvSS/f________(kX X'Y 0 Q\ b NS )0QQNO2TCOS^vpSf[e z_ __________0 (2)2u(P[Nbcqe5u`l-N\2ullS:N"llv$NyS^St/f `$CH3OH(g) H2O(g)===CO2(g) 3H2(g) H 49.0 kJmol 1 a$CH3OH(g) 1/2O2(g)===CO2(g) 2H2(g) H 192.9 kJmol 1 Swb$H2O(g)===H2O(l)0H 44 kJmol 1 R2uqpubm`4lvpSf[e z_:N__________________0 0㉐g00(1)‰[Vb_ E1^:NS^v;mS ReQPSBRS^v;mSMNO FO/fH NS1 mol NO2(g)T1 mol CO(g)S^ubCO2TNOvS^ppeNc0 (1) NRZPl gRNn _nAm v/f________(kX^S)0 a'YRSU\QQgll \^_vyylS:NnmؚHevn b'YR_Ǒdq0wlT)Y6qlNnNNevXvnBl c_S*Y304l0Θ00WpI{en Q\O(udq0wlI{Swqe dQ\Dnm XRDnv͑ YO(u0Dnv_sQu (2)ёRwTwXGW:Nxv T }_b_SO [Nqp'll NeubN'lSx EQRqpubN'lSx S^-N>eQvpϑYV@b:y0  INCLUDEPICTURE "E:\\vQN\\360Nv\\Sf[\\2014t^ePWh\\T\ONWORD\\Y17.TIF" \* MERGEFORMAT  `$(W8^rQ N ёRwTwX-N________(kX ёRw b wX )f3z[ wXvqpp:N________0 a$12 gwX(WN[ϑzzl-Nqp ublSO36 g Ǐ z>eQvpϑ________0 (3)]wN20O2RP[-NSf[.v.R+R/f946 kJmol 10497 kJmol 10 N2(g) O2(g)===2NO(g) H180.0 kJmol 10 NORP[-NSf[.v.:N________kJmol 10 (4)~T N gsQOo` QQCOTNOS^vpSf[e z___________________________________0 0㉐g00(2)`$wXvϑfNO f3z[0wXvqppc1 molwX[hQqpubCO2e>eQvpϑ0a$12 gwXT24 g'llS^ sS1 mol CT0.75 mol O2S^ Rub0.5 mol COT0.5 mol CO2 >eQpϑ0.5 mol110.5 kJmol 1 0.5 mol393.5 kJmol 1252.0 kJ0(3)HE(N2.) E(O2.) 2E(NO.) 2E(NO.)946 kJmol 1 497 kJmol 1 180.0 kJmol 1 E(NO.)631.5 kJmol 10(4)]w2CO(g) O2(g)===2CO2(g)0H 566.0 kJmol 1 N2(g) O2(g)===2NO(g)0H180.0 kJmol 1 vhS^2NO(g) 2CO (g)===N2(g) 2CO2(g)S1uMRQT_ RH 746.0 kJmol 10 0T{Hh00(1)acd0(2)`$wX0393.5 kJmol 1 a$252.0 kJ0(3)631.5 (4)2NO(g) 2CO(g)===N2(g) 2CO2(g) H 746.0 kJmol 1 11(16R)(2012Ym_lؚ9e)(1)2upp͑te/fHQۏv6R"lel S+T2up'lST}l͑te0TS^|~ TeeQ2up0'llT4ll Suv;NSf[S^ g Sf[e z_qS H(kJmol 1)2u p 'l SCH4(g) 2O2(g)===CO2(g) 2H2O(g)H1CH4(g) O2(g)===CO2(g) 2H2(g) 322.0 }l ͑ teCH4(g) H2O(g)===CO(g) 3H2(g)206.2CH4(g) 2H2O(g)===CO2(g) 4H2(g)165.0(1)`$S^CO(g) H2O(g)===CO2(g) H2(g)vH________kJmol 10 a$2upvqpp:NH2 RH2________H1(kX > 0 < b  )0 (2)ir((tBuNO)2(Wck^pnBR-NSuY NS^(tBuNO)2%&2(tBuNO)0H0[Km_S^vH 50.5 kJmol 1 ;mSEa90.4 kJmol 10 NRϑsQ|VTtv/f________0  INCLUDEPICTURE "E:\\vQN\\360Nv\\Sf[\\2014t^ePWh\\T\ONWORD\\6-38.TIF" \* MERGEFORMAT  0㉐g00(1)`$1u}l͑tev$N*NS^Sw )R(u,{N*NS^QS,{N*NS^R_QS^vS^p:NH(165.0 206.2)kJmol 1 41.2 kJmol 10a$h:y2upqppvpSf[e z_:NCH4(g) 2O2(g)===CO2(g) 2H2O(l)0H20ubm`4lkubl`4lʑ>eQvpϑY EeH2<H10 (2)1u[Km_S^vS^pH 50.5 kJmol 1 SwS^/f8TpS^ RS^irv;`ϑNONubirv;`ϑ ScdϑsQ|VBTC0SOnc;mSEa90.4 kJmol 1 Ea H<50.5 kJmol 1 ϑsQ|VA-N Ea H>50.5 kJmol 1 EaNHvkO N[0 ϑsQ|VD/fTtv Ee D0 0T{Hh00(1)`$ 41.20a$<0(2)D 12(16R)(1)\CH4NH2O(g)eQZ&q*Y3S^hV SSuS^ `$CH4(g) H2O(g)%&CO(g) 3H2(g) S^vH 206 kJmol 1 ]wa$CH4(g) 2O2(g)===CO2(g) 2H2O(g)0H 802 kJmol 1 QQ1uCO2TH2O(g)ubCOvpSf[e z__________________________________0 (2)}lf>\l-N;N+T gCO0NO20SO20CO2 vMRǑ(uv/f(W}lfclňn-N[ňN*NQShVSN gHe0W\>\l-Nv g[lSOlS0YCO(g) NO2(g)===NO(g) CO2(g)0H a kJmol 1(a>0) 2CO(g) 2NO(g)===N2(g) 2CO2(g) H b kJmol 1(b>0) R(uhQrQ Nv3.36 L CO؏SNO2N2(CO[hQS^)vte*NǏ z-N>eQvpϑ:N________kJ((u+T gaTbvNpe_h:y)0 0㉐g00(1)Rg$N_P[ b`$_ a$_S_CO2(g) 3H2O(g)===2O2(g) CO(g) 3H2(g)0H 206 kJmol 1 ( 802 kJmol 1) 1 008 kJmol 10 (2)CO(g) NO2(g)===NO(g) CO2(g)0H a kJmol 1XNN2_2CO(g) 2NO2(g)===2NO(g) 2CO2(g)0H 2a kJmol 1N2CO(g) 2NO(g)===N2(g) 2CO2(g)0H b kJmol 1vRsS_4CO(g) 2NO2(g)===N2(g) 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