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" SQ pm`|Nu40LDx6h RY8ZyZ`[RYRYRYzy4RYRYRY|_|_|_|_ )J JfdR R R R R R  ,{ N Sf[S^pv{(N)cs~ e1Ye f[ v vwƋ N btve[_Ǐ z N elǏЏ(uve[_Bl gsQvS^p ۏNektS^pvi_`a `^ NeQb8T6evpϑ FO/fgNir(vS^p 1uNyySV NvcKm_ SǏSf[{ve_c_0(WuN-N [qevqp0S^agNvc6RNS^pv)R(u _NS^p{ :NeOS^p{ bNegf[`Nve[_0 [gfN] ,{ N Sf[S^p{ N0ve[_ []1840t^ veGHHess OVSf[[ N'Yϑv[N[-N;`~QNagĉ_Sf[S^ N{/fNek[b؏/fRQek[b vQS^p/fv Tv0_N1\/f Sf[S^vS^pSNS^vY`TS^ir T~`Tubir gsQ NwQSOS^ۏLv_esQ0YgN*NS^SNRQekۏL RTRekS^vS^pKNTNS^Nek[bevS^p/fv Tv ُ1\/fve[_0 [bq_]  EMBED PBrush  EMBED PBrush  []9hncV:yNq\q\vؚ^N Nq\_esQSϑ[a[_egOve[_0 ;;mR=f[uf[vsQQ[T [gfN]10 ve[_Sf[S^vS^pSNS^vY`TS^ir T~`Tubir gsQ NwQSOS^ۏLv_esQ0 []ve[_(WuNTyf[xvz-N g_͑vaIN0 gNS^vS^p}6qelvcKm_ FO)R(uve[_ Nc{Bl_0 [gfN]20ve[_(WuNTyf[xvz-N g_͑vaIN [yf[cvz][NS^Cs +  EMBED PBrush O2g =COg V:NCqpe NS[hQubCO ;` gNRCO2ub Vdkُ*NS^vHelvcKm_ Tf[N]9hncve[_N*NeHhS^vH0 [^uqQ TRg]bNSNKm_CNO2S^ubCO2NSCONO2S^ubCO2vS^pCs O2g =CO2g H= 3935 kJmol COg +  EMBED PBrush O2g =CO2g H= 2830 kJmol ;bq_=  ;=9hncve[_.SN_[fBl{QCs +  EMBED PBrush O2g =COg vH0 5"H1=H2+H34"H2=H1 H3= 3935kJ/mol  2830kJ/mol  1105 kJmolsSCs +  EMBED PBrush O2g =COg vH= 1105 kJmol ;bq_=  EMBED PBrush  ;pQՋ=O10Ǐ{Blv"llvqppSNǏ$Ny_eg[b Y NVh ]wH2g + EMBED PBrush O2g =H2Og %H1 241.8kJ/mol H2O(g)H2O(l)%H2 44.0kJ/mol 9hncve[_ R %H%H1 %H2 241.8kJ/mol ( 44.0kJ/mol) 285.8kJ/mol ;pQՋ=O20[-N NvcKmQ1uwXT"llub2upS^vH FOSKmQCH4qpS^vH1 9hncve[_BlH4 CH4(g)+2O2(g)CO2(g)+2H2O(l)H1=-890.3kJmol-1 (1) C(wX)+O2(g)CO2(g)H2=-3935kJmol-1 (2) H2g + EMBED PBrush O2g =H2Ol H3=-285.8kJmol-1 (3) C(wX)+2H2(g)CH4(g)H4 (4) ;bq_=  ;=)R(uve[_e SNǏ]wS^~Ǐ{USvNpeЏ{_0R@bBlS^ Ndkeg{_@bBlS^vpHe^0_NSNN*N_ OS^ir~ǏNN-NekgTV Y0RNirV:NS^_(1) (2) (3)T(4)KN gN NsQ| (2)+(3)2-(1)=(4)@bN H4=H2+2H3-H1=-393.5 kJmol-1+2(-285.8) kJmol-1-(-890.3) kJmol-1=-74.8kJmol-1 [\~]Sc{Bl_gNelvcKm_vS^p Y C NO2 ub CO v%H0 ;pQՋ=O30ir(vubpS[IN:N1u3z[US(ub1 molir(@b>eQvpϑ YN'lSxlSOvubp1\/fvS^p]w NRQyir(vubpa|(C6H12O6)1259kJ/mol H2O (1)285.8kJ/mol CO2393.5kJ/molՋ{1kga|(WNSOQ[hQ'lSubN'lSxlSOTm`4l gYScOvϑ HQBlQ1 mol 'lSe>eQvpϑsS %H9hnc]wagN_w   ;X~`N= ]w NRpSf[e z_ `$%H 25kJ/mol a$%H 47kJ/mol b$%H+19kJ/mol QQFeO(s)NCOS^ubFe(s)TvpSf[e z_____________________________ Yef[V~  Ye Hh ,{ N Sf[S^pv{(N) ---xQWN cs~ e1Ye f[ v vwƋ N b10tS^p 20NS^pv{Ǐ z N el~TЏ(uS^pTve[_vwƋ㉳QϑSSv[E`a `^ NeQvpϑ {S^p QQvQpSf[S^e z_0 O10\0.3molvl`ؚqeYN|xpB2H6 (W'll-Nqp ubV` N'lSN|xTm`4l >eQ649.5kJpϑ S^vpSf[e z_:N_____________0S]wH2Og =H2Ol %H2 44.0kJ/mol R11.2LhQrQ YN|xp[hQqpubl`4le>eQvpϑ/f_____________kJ0 ㉐g0.3molYN|xp[hQqpubm`4l>eQ649.5kJpϑ R1molYN|xp[hQqp>eQvpϑ:N INCLUDEPICTURE "http://www.chinaedu.com/101resource004/wenjianku/200410/101ktb/lanmu/F10H0277/Image4791.gif" \* MERGEFORMATINET VdkYN|xpqpvpSf[S^e z_:N INCLUDEPICTURE "http://www.chinaedu.com/101resource004/wenjianku/200410/101ktb/lanmu/F10H0277/Image4792.gif" \* MERGEFORMATINET  INCLUDEPICTURE "http://www.chinaedu.com/101resource004/wenjianku/200410/101ktb/lanmu/F10H0277/Image4793.gif" \* MERGEFORMATINET 01uN1mol4l}lS8Tp44kJ R3molm`4lhQ}lS^8Tp INCLUDEPICTURE "http://www.chinaedu.com/101resource004/wenjianku/200410/101ktb/lanmu/F10H0277/Image4794.gif" \* MERGEFORMATINET  @bN1molYN|xp[hQqpNul`4le>ep INCLUDEPICTURE "http://www.chinaedu.com/10$.68<>FJLPRVXl~ " $ ( 4 6 8 < N r 6 8 : B F T V n r t x z n v ̴̼ڨ旅t h^jh jB*CJaJo(ph#hh j5B*CJaJo(ph hh j5B*CJaJphh)Rh j5CJo(hh jo(hh j5B*\o(phhh j5B*o(phht\Nh j5CJo( h jo(h j5CJo(h^Ph j5CJo(-&0246@<kd$$Ifl4CFtc `{ t06    44 laytm$d,$Ifa$gdmld,$Ifgdml̔2jp@DFJLPRU<<<<$d,$Ifa$gdmlkd$$Ifl4BFtc { t06    44 laytmd,$IfgdmlRVX\bflzd,$IfWD`gd jl$d,$Ifa$gdmlz|~aHHHH$d,$Ifa$gdmlkd$$Ifl4F] 'Z t06    44 lapytmE,,$d,$Ifa$gdmlkd$$Ifl4F] 'Z t06    44 lapytmd,$IfWD`gd jl ,kdZ$$Ifl4F] 'Z t06    44 lapytmd,$IfWD`gd jl$d,$Ifa$gdml ( 2 4 < L J}kd$$Ifl0P  t0644 laytmd,$IfXD2YD2gdml$d,$Ifa$gdmlL N R V Z ^ b f j n r hhhhhhhhh$d,$Ifa$gdml}kde$$Ifl0P  t0644 laytm r  6 8 : K}kd$$Ifl0  t0644 laytmd,$Ifgdml$d,$If[$\$a$gdml: D F V p {jkd;$$Ifl J! 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t0644 laytm "&(046:<@BVnprv*,2XZ\^~~h9''h j0J!5PJaJh9''h j5H*PJaJh9''h j5PJaJh9''h j5PJ\aJh9''h j5CJ\h9''h j5CJQJ\h)Rh j5CJo(ht\Nh j5CJo( h jo(h j5CJo(h^Ph j5CJo(1 *.kU<U$d,$Ifa$gdmld,$Ifgdmlkd$$Ifl4CF% ` t06    44 laytm.046:<@BFLkRRRRRRRR$d,$Ifa$gdmlkd4$$Ifl4BF%  t06    44 laytm LPVf|~2kd$$Ifl4F]V  t06    44 lapytmd,$Ifgdml$d,$Ifa$gdml~d,$IfWD`gd jl$d,$Ifa$gdmlaHHHH$d,$Ifa$gdmlkda$$Ifl4F]V  t06    44 lapytmlnvK2$d,$Ifa$gdmlkd$$Ifl4F]V  t06    44 lapytmd,$IfgdmlvcJ$d,$Ifa$gdml}kd$$Ifl0:  t0644 laytmd,$IfXD2YD2gdmlh$d,$Ifa$gdml}kd $$Ifl0:  t0644 laytm{{$d,$Ifa$gdmljkdw$$Ifl J! t0644 laytm,x~~dMM7d,$Ifgdmld,$H$Ifgdmld,$H$IfWD`gdml}kd̽$$Ifl0 C t0644 laytmx~  !!!!""$"&"("l"n"r#t#v#x###$|||||||}}ɽɬɽɛɽɊɽyɽwfɽ jh9''h jH*PJUaJU jph9''h jH*PJUaJ jVh9''h jH*PJUaJ j h9''h jH*PJUaJ j7h9''h jH*PJUaJh9''h jH*PJaJ jh9''h jH*PJUaJh9''h jPJaJh9''h j5PJ\aJh9''h j5PJaJ$1resource004/wenjianku/200410/101ktb/lanmu/F10H0277/Image4795.gif" \* MERGEFORMATINET  R11.2LhQrQ YN|xp[hQqpNul`4l>eQpϑ/f INCLUDEPICTURE "http://www.chinaedu.com/101resource004/wenjianku/200410/101ktb/lanmu/F10H0277/Image4796.gif" \* MERGEFORMATINET 0 ;X~`N=]wEQRqpa gYNplSOeub1molN'lSxlSOTm`4l v^>eQpϑb kJ RYNpqpvpSf[e z_cknxv/f A. 2C2H2(g) 5O2(g)4CO2(g) 2H2O(l) H 2b kJ / mol B. C2H2(g) 5/2O2(g)2CO2(g) H2O(l) H2b kJ / mol C. 2C2H2(g) 5O2(g)4CO2(g) 2H2O(l) H 4b kJ / mol D. 2C2H2(g) 5O2(g)4CO2(g) 2H2O(l) Hb kJ / mol WN)R(uve[_BlS^p O20yf[[vefcQ N{Sf[Ǐ z/fNek[bbRQek[b ُ*N;`Ǐ zvpHe^/fv Tv0 )R(uve[_SKmgNyr+RS^vpHe^0 1  EMBED Equation.2 s }vx + EMBED Equation.2   EMBED Equation.2  2  EMBED Equation.2   EMBED Equation.2  R}vxlS:N~xvpSf[e z______________0v TvrQ N ϑNOv/f_________}vxv3z['`k~x___________kX ؚ b NO 0 ㉐gOaBl EMBED Equation.2  EMBED Equation.2 SY NS^Ǐ z EMBED Equation.2 ncve[_ g EMBED Equation.2 =-2983.2+4738.5 kJ/mol=-29.2kJ/mol sS EMBED Equation.2  EMBED Equation.2 0}vxlS:N~x/f>epS^ 3z['`k~xNOϑNO3z[ 0 ;X~`N=1uё~w(TiO2(6RSUS(Ti mS0Rvek:N TiO2TiCl4Ti ]w`$ C(s( O2(g(CO2(g( (H(393(5 kJmol(1 a$ 2CO(g( O2(g(2CO2(g( (H(566 kJmol(1 b$ TiO2(s( 2Cl2(g(TiCl4(s( O2(g( (H+141 kJmol(1 RTiO2(s( 2Cl2(g( 2C(s(TiCl4(s( 2CO(g(v(H 0 W N9hncN[ϑvir(SRS^>eQvpϑb9hnc]wvpSf[e z_ ۏL gsQS^pv{bk'Y\0 O30]w NR$N*NpSf[e z_ H2 (g) + 1/2 O2(g) == H2O (l) (H(285.8 kJmol(1 C3H8(g)+5O2(g) == 3 CO2(g) +4H2O (l) (H(2220.0 kJmol(1 [Km_"llTNpvmTlSOqQ5 mol [hQqpe>ep3847kJ RmTlSO-N"llTNpvSOyk/f_______ $N>eQvpϑKNk~:N_____ A013 B031 C014 D0513 lNASW[NSl lN0O{cdl T{HhBD ;X~`N=]w 2k_0Rv Tvpϑ R+RqpVSOxT"llv(ϑk~:N A. 2:3.25 B. 12:3.25 C. 1:1 D. 393.5:241.8 ㉐g1uaSR_e z    T{Hh B WVS^p'Y\k O40(W T)n TS N NRT~pSf[e z_-N v/f A.     B.     C.    D.    ㉐gS^ppeep @bNubm`4lkubl`4l>eQvpYsSB yS^irvr` N T 1uNNV`kx0Rl`kx8Tp @bNl`kxqp>eQvpϑkV`kxqp>eQvpϑY sSC yubirvy{| N T 1uNCONO2S^ubCO2>eQpϑ EeD yS^irvir(vϑ N T MRNS^vir(vϑ/fTNS^vir(vϑv2 P Ee sS0T{Hh A0C0 ;X~`N="ll0N'lSx0p02upvpSf[e z_R+R:N H2(g) 1/2O2(g)H2O(l) %H 285.8kJ/mol CO(g) 1/2O2(g)CO2(g) %H 283.0kJ/mol C8H18(l) 25/2O2(g)8CO2(g) 9H2O(l)%H 5518kJ/mol CH4(g) 2O2(g)CO2(g) 2H2O(l) %H 89.3kJ/mol v T(ϑv"ll0N'lSx0p02up[hQqpe >eQpϑg\v/f A H2(g) B CO(g) C C8H18(l) D CH4(g) WN)R(u.{S^p elH="E(S^ir) "Eubir sSS^pI{NS^irv.;`Tߍubirv.;`TKN]08^NNbb_1 molgSf[.@b8T6evϑ wbSf[.v.0.8^(uEh:y USMO/fkJ/mol0 0O5CH3 CH3!CH2CH2 H2 gsQSf[.v.Y N0 00Sf[. 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