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EeDcknx Ee BDpċ,ggN?O=O_W8^pev^(u ;N/f(ϑbc{ir(vϑ{_|pe la}vx~gvRg$Re v^-NI{0 134R Tvfc2N C9hncǏ'lSN4lS^vubir$Re DǏ'lSTǏ'lSwQ g:_v_5uP[RT{AǏ'lS-NyP[>f+2N Ǐ'l9hyP[>fc2N @bNvQSf[_:NBaO2 EeA BǏ'lS-NǏ'l9hyP[>fc2N vQ5uP[_/f vfSO-N43yP[*Npek:N11 EeB CǏ'lS-NOCQ }STN:Nc1N S^TSTNSS:N0N0c2N N4lS^ve z_:N2BaO2+2H2O=2BaOH 2+O2 R1molǏ'lSNϑ4lS^ub0.5mol'll EeCcknx D"l'lSTǏ'lS-NǏ'l9hyP[ g:_'lS'` @bNǏ'lSTǏ'lSS\O:_'lSBR EeDcknx Ee CDpċ,ggNǏ'lSirv'`( :Nؚp O͑Nf[uvRgRvg fnxǏ'lSv'`(Ǒ(uwƋyvelۏLRgT{sSS ^ N'Y0 144R 2008" ^N NRSf[S^vyP[e z_cknxv/f00 0A(Wz(l4l-NeQǏϑCO2NH3" H2O+CO2=NH4++HCO3c0B\ϑSO2eQCaClO 2nm-NSO2+H2O+Ca2++2ClOc=CaSO3!+2HClO0C(uzHNO3nmFeSVSOFeS+2H+=Fe2++H2S!0D"l'lSnmNI{ir(vϑvzkxxmTCa2++OHc+H++SO42c=CaSO4!+H2O pyP[e z_vfNQNyP[S^NRgA(l4lTǏϑvN'lSxS^ubxx"l BClOc g:_v'lS'` (W4lnm-NSO32c g:_v؏S'` ClOcSbSO32c'lS:NSO42c gkxxlmub CzHNO3 g'lS'` SbS2cNFe2+'lS D"l'lSnmNI{ir(vϑvzkxxmT yP[T"l'l9hyP[k:N12 "lyP[Tkxx9hyP[k:N12T{A(Wz(l4l-NeQǏϑCO2 SuS^:NNH3" H2O+CO2=NH4HCO3 xx"l/ffnN4lvv bbyP[ @bNyP[S^:NNH3" H2O+CO2=NH4++HCO3c EeAcknx BClOc g:_v'lS'` (W4lnm-NSO2 g:_v؏S'` NvGHQSu'lS؏SS^ ub/lyP[Tkxx9hyP[1uNkxx4l-Nn㉦^ N'Y kxx9hyP[NyP[SOb_bkxxlm S^vyP[e z_:NSO2 +ClOc+Ca2++H2O=CaSO4!+Clc+2H+ EeB CzHNO3 g'lS'` SbS2cNFe2+'lS ꁫ؏SbN'lS.l kx'lSbSbSO2bSO3I{ YFeS+4HNO3=FeNO3 3+S!+NO!+H2O EeC D"l'lSnmNI{ir(vϑvzkxxmT SuS^CaOH 2+H2SO4P%CaSO4!+2H2O yP[S^:NCa2++2OHc+2H++SO42cP%CaSO4!+2H2O EeD Ee Apċ,ggyP[S^e z_vfNQ fnxSuvSf[S^TϑvsQ|/fT{,gvsQ. layP[S^-N^OYuSf[_vir( DyP[k&{TSf[_/f勘vfp v^-NI{0 154R (Wg100mLmTx-N ]xxir(vϑSm^:N0.4mol/L kxxir(vϑSm^:N0.2mol/L TvQ-NReQ3.2gܔ| _p _vQEQRS^T nm-NܔyP[vir(vϑSm^~:N00 0A0.15mol/LB0.3mol/LC0.5mol/LDel{ pir(vϑSm^vvsQ{N{Rg9hncS^3Cu+2NO3c+8H+=3Cu2++2NO+4H2OHQ$ReǏϑ QۏL{T{T{(Wg100mLmx-N ]xxvir(vϑnHNO3 =0.1L0.4mol/L=0. 04mol kxxvir(vϑnH2SO4 =0.1L0.2moL/L=0.02moL @bN"lyP[vir(vϑnH+ =0.04moL+20.02moL=0.08mol ܔ|vir(vϑ==0.05mol Once z_ 3Cu+2NO3c+8H+=3Cu2++2NO+4H2O 3 2 8 0.05mol 0.04mol 0.08mol Sw"lyP[ N Ee9hncH+{ 1ue z_SwnCu2+ =0.08mol=0.03mol @bNCCu2+ ==0.3mol/L Ee Bpċ,ggN]xxvvsQ{ v^ N'Y ㉘elaOncyP[S^e z_{T{0 N0^ b 1616R A0B0C0DVyir(GW:N NRyP[~bvSn'`STir ~bُVyir(vyP[yP[ N͑ Y~T g 3yP[Na+0Al3+0Ba2+0NH4+4yP[Clc0OHc0CO32c0SO42cR+RSVyir(ۏL[ [~gY N `$A0DnmHTx'` BHTx'` CHT-N'` a$AnmNBnmS^ub}vrlm QRǏϑA lmϑQ\ FO NO[hQm1Y b$AnmNDnmmTv^Rp glSOub lSOOnmv~rwJՋmS݄ VT{ NR 1 AvSf[_/f0BaOH 20 (u5uP[_h:yCvb_bǏ z00 2 TAnm-NeQϑCO2 Oubvlmp`}Yn @b_nm-NTyP[ir(vϑSm^1u'Y0R\vz^/f0cHCO3c cBa2+ cOHc cH+ cCO32c 0 3 QQb$vyP[e z_0Ba2++CO32c+2NH4++2OHc2NH3!+2H2O+BaCO3!0 4 {DnmHTx'`vt1u0NH4+v4l z^\NCO32cv4l z^0 pyP[qQX[v{|4l㉄v^(uNyP[S^NRg9hncAnmNDnmmTv^Rp glSOub lSOOnmv~rwJՋmS݄ NA0DnmHTx'` BHTx'` CHT-N'` AnmNBnmS^ub}vrlm QRǏϑA lmϑQ\ FO NO[hQm1Y RA:NBaOH 2 B:NAl2SO4 2 C:NNaCl D:NNH4 2CO3 NdkegT{T{9hncAnmNDnmmTv^Rp glSOub lSOOnmv~rwJՋmS݄ lSO:N(ll Q1uA0DnmHTx'` BHTx'` CHT-N'` AnmNBnmS^ub}vrlm QRǏϑA lmϑQ\ FO NO[hQm1Y RA:NBaOH 2 B:N:_x1_xv RB:NAl2SO4 2 C:N:_x:_xv RC:NNaCl D:N1_x1_xv RD:NNH4 2CO3 1 A:NBaOH 2 C:NNaCl vQb_bǏ z:N EeT{Hh:NBaOH 2 2 TAnm-NeQϑCO2 Oubvlmp`}Yn nmvn(:NBaHCO3 2 1uSf[_S5uySw cHCO3c cBa2+ Q1uv4l>fx'`SwcOHc cH+ 5uyNug\vCO32c sSyP[ir(vϑSm^1u'Y0R\vz^:NcHCO3c cBa2+ cOHc cH+ cCO32c EeT{Hh:NcHCO3c cBa2+ cOHc cH+ cCO32c  3 b$:NBaOH 2NNH4 2CO3vS^ vQyP[S^:NBa2++CO32c+2NH4++2OHc2NH3!+2H2O+BaCO3! EeT{Hh:NBa2++CO32c+2NH4++2OHc2NH3!+2H2O+BaCO3! 4 NH4 2CO3nm>fx'` /fVNH4+v4l z^\NCO32cv4l z^ EeT{Hh:NNH4+v4l z^\NCO32cv4l z^pċ,ggir(vce0yP[vqQX[0yP[Sm^'Y\vk04l0yP[S^I{wƋ ~T'`:_ ^'Y f[u(Wcee~TQOo`v)R(u [f[uRBlؚ0 1716R g Tf[SN[ϑvAl0FemTir N2.0LgzvHNO3EQRS^ GPHNO3v؏SNirhQ:Nv(WS^Tvnm-N nReQ4mol" Lc1vNaOHnm @bRNaOHnmvSOyNNuvlmvir(vϑvsQ|YV@b:yRgVaVT{ 1 DEkSuS^vyP[e z_:N0NH4++OHc=NH3" H2O0 2 QQNaN*NAl0FeNgzHNO3S^vSf[e z_08Al+30HNO3=8AlNO3 3+3NH4NO3+9H2O0 3 Bp[^vlmvir(vϑ:N00.0320mol Cp[^v"l'lSnmvSOy:N070mL 4 S]xxnmvir(vϑSm^:N00.0740mol/L  pA0ݔv͑STirSf[e z_v gsQ{NV:yRgݔ|T|vmTirNN[ϑ_zHNO3EQRS^ 'lS:NAl3+0Fe3+ GPHNO3v؏SNirhQ:Nv1uVS_]xxǏϑ ReQ"l'lSnm^HQN]xxS^ Qublm S_lm[hQT 1uVw~~ReQ"l'lSnm lmϑ NS S_NNH4+SuNS^ R@wNaOHvnR SuvS^O!k g `$H++OHc=H2O a$Fe3++3OHc=FeOH 3! 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