ࡱ> y  !"#$%&'()*+,-./023456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXaZ[\]^_`zbcdefghijklmnopqrstuvwx{|}~Root Entry Fp!AZ@ SummaryInformation(XDocumentSummaryInformation8 ObjectPool.-Rt!AZp!AZ  !"#$%&(+,-023456789:;<=>?@ABCEHIJMOPQRSTUVWXYZ[\]^_`abcehijknsvy~Oh+'0(4@T`l    >s~ؚN s Y T f[S 0 b~ _o(u7b Normal.dotAdministrator2@n @V1!AZ^ Microsoft Office Word՜.+,D՜.+,x4    $,www.xunchi.com (\dlKSOProductBuildVer2052-9.1.0.4984L$N1  .1  &`/ &_1234567890FRt!AZ'v!AZ_1234567891 FRt!AZv!AZ_1234567892FRt!AZ'v!AZ_1234567893 Fzt!AZ'v!AZ_1234567894&Ft!AZ'v!AZ_1234567895 "Ft!AZ'v!AZ_1234567896*F t!AZ'v!AZOle PIC  LMETA CompObj 'fObjInfo) MathTypep8Symbol-2 (8Symbol-2 n)Times New Roman- 2 6Al^2 DNaAlO^ 2 Al^ 2 |OHTimes New Roman- 2 NaOHq 2 Z H 2 xSO Times New Roman- 2 ) 2p 2 &3p`Times New Roman- 2 1%2P 2 14PSymbol!- 2 P 2 J 2 ;P 2 P 2  P 2 :J 2  P 2 P 2 P & "Systems-;P 2 P FMicrosoft Equation 2.0 DS Equation Equation.29qZGFF Al  eNaOH CNaAlO 2   eH  2 eSO  4 CAlOH() 3l-2  (LEquation Native *Ole .PIC /LMETA 1N1 I .1   &/ & MathTypep*Symbol-2  (*Symbol-2 _ )8Symbol-2 }(8Symbol-2 )Times New Roman- 2 6Al^ 2 sAl^ 2  SO 2 /Al^ 2 OHTimes New Roman- 2 H 2 1SO 2 NaOHq`Times New Roman- 2 12P 2 14P Times New Roman- 2 2p 2  4p 2 - 3p 2 &i3pSymbol!- 2 P 2 J 2 ;P 2 P 2 P 2  P 2 J 2 0P 2 P & "Systems-P 2  FMicrosoft Equation 2.0 DS Equation Equation.29qZGHFF Al  eH  2CompObjDfObjInfoFEquation Native GOle K eSO  4 CAl 2 SO 4 () 3   eNaOH CAlOH() 3L N1  .1  & &PIC LLMETA NhCompObjdfObjInfof MathType*Symbol-2  (*Symbol-2 _ )8Symbol-2 O(8Symbol-2 )Times New Roman- 2 6Al^ 2 sAl^ 2  SO 2 H6Al^2 HDNaAlO^ 2 Al^ 2 OHTimes New Roman- 2 H 2 1SO 2 NaOHq`Times New Roman- 2 W2P 2 W4P Times New Roman- 2 2p 2  4p 2 S 3p 2 ) 2p 2 f;3pSymbol!- 2 P 2 J 2 ;P 2 P 2 P 2 HP 2 HJ 2 H;P 2 HP 2   2   2   2   2 B  2 iJ & "Systems-P 2 HP 2 H FMicrosoft Equation 2.0 DS Equation Equation.29qZG\FF Al  eH Equation Native gOle lCompObjmiObjInfo o 2 eSO  4 CAl 2 SO 4 () 3 Al  eNaOH CNaAlO 2 }AlOH() 3) FMicrosoft ʽ 3.0 İ DS Equation Equation.39qEquation Native p>Ole qCompObj!#riObjInfo$t"\ a+b4 FMicrosoft ʽ 3.0 İ DS Equation Equation.39qF(II 3a+c4Equation Native uDOle wCompObj%'xiObjInfo(z FMicrosoft ʽ 3.0 İ DS Equation Equation.39qF$oI{I a+c4 FMicrosoft ʽ 3.0 İ DS Equation Equation.39qEquation Native {@Ole |CompObj)+}iObjInfo,Equation Native 8WordDocument1.0Table/Y;Data  C'FdII b3Dd}  VA  0S&{SPicture 103"rjB Xi۱zjB Xi۱($ X??0Dd#  VA  0S&{SPicture 113"rjB Xi۱zjB Xi۱($ X??0Dd  TA  0S&{SPicture 93"rjB Xi۱zjB Xi۱($ X??0Dd&)t  s 6A 0 VGr 203"2;_sqԁ `!_sqԁ  ݟ]xKaϽ5/2u!UT઻XЈɺ5@ F\ WR.wWZ;vN4100={B,0H@zfy)Bl۶"S4Hɩ'Gq "gn_ 7ja 4 UK7QґT ˒'wԑC*&K\\'GNCf9|JzzH}~T$;ɕRa0;(zMXϮՑ9$Y6u;ݺK3Z HQ ǿTPV>ťn4%xI^ߋNN7ƲG{$D'=oeEK&JcO=2k.$~y&nX.8uD}jΔzGy+|"$lVdD ]QiUOV,B|AtB͔VY`51v*8fczӰqAQTOk z~a--Ɠ٭z>S@ PN7?b æxT.*N{պCᲝ(T*tM)owaVCWSKlR0%$1ԡd:s__/Ȣay5I?^Csuro2z+q %W LN1S'>ȏK:B^2ay}ޘLjK O1_tiI]]rͣ蝜OT;PDd 8L)t  s 6A 0 VGr 223"2֊펙&d`!\֊펙&`= *xkA{;1͏@XBS"-Mb!$MhKC%Q($=x4xA:ofv5҅~̰ gWL '!oBT)EN"FЗ&5si M'_ZnS̷4\*-ݜ/\t%F'oT8[Wo,T`뎡NHJ%'|ῖf%hg:i+E~r0]SP-݂ ؝$U.^J FfԖhNa⼏ӥ/&k'7mﵤNAy`LB ca ?Bw@~6#T׀ے7L=+w|?03:J{}:}1")"}TtD9g2jyy]|,}3jp1"Y6ygOɞر=a'{⡕s3LC&?"r4BvD [Ӥ>]JP.K>vx^[*Wfﭣt'!oDdDl  JA 0?Picture 1C"`2Bj"WI琎i`!aBj"WI琎&Iv/xcdd``f 2 ĜL0##0KQ* Wy A?df@ UXRY T,@1[Ar#X=@Hfnj_jBP~nbÍ 3vq0fRn#I1nnc;ȄJ?Oİ {+ss&:|n=Lp{.ծ䂆(8K6F&&\ @ ]` 1 dGDdDl  DA 0Picture 23"2qԱ[jeĎsN^M`!EԱ[jeĎsN^Ivxcdd``$D@9@, fbd02,(1dbfazYRcgb vq3 憪aM,,HD(me.f Y fjQ;f&br<) @ڈ9؄F&0nRc8(?4 \s<&~˴Cנf 0y{@Ĥ\Y\ІFf:E'NDdl  DA 0Picture 33"2xg] c|Q7T`!Lg] c|Q7@:vxcdd``$D@9@, fbd02,(1dbfaz"d3H1ibY;F`ꁪaM,,HD(me.f YAv#L ! ~ Ay MS8WFb(?я7f@7L`}h ғ sHͭ@?0W&00\1 _ \)ثP3=XhcdbR ,.IehCw#3XE*Ddl  DA 0Picture 43"2TaN&0`!(aN&ޒ Txcdd``>$D@9@, fbd02,(1dbfaz(d3H1ibY;i3PT obIFHeA*P - :@@ l.#t&&0KRb7S? `731d++&10,z@M`$`=&1MJb gS$R#RpeqIj.CU31,:I DdR    ^A  0G2HX23Picture 53"bY !}+Qg(s5 n- !}+Qg(sPNG  IHDR2gAMA|Q pHYs\F\FCAIDATxOo6p>x7arnvuE/=SEU⺨0P  sn*R|||Iu]%m'Q|$8l}D Q'N-<7ROL~;fodUlLRKca\Y5[\C-Oyu#k!CRjȜ޸ZG\.1su U%%4jz2~YsAHV?csͶCJ}zْ&Qd#\7َjSByIIIIITvKnLU wySj%y |}Ux?}>Ca Za}Tx՝F7Oԭ3TYRKI]BE澠.us'ߐ^f(H jC EzZ%SA]DvZ*A-3^W) F?H*RKtvDnZH] .+ \X k!uiBD4*z4Ĕ &. P[WϢύp U; T!a}O%΄QP ]HjUQ8PmV(2%Tnj]WPqBBuIRPnxNF+#HOX%i{BTj[$PuFqjQ`>aZ*TMpjsUOX+V5 OXU^nýI9|fywQ~(PׂڶR&W7iucHOX\Yrj, &WɕS:VلjLSA]0*^=ն/Nlzu!mFm{DVYWJSڦ+'2i;Tt-Pv6لM\եnױ&ld5r ۫ojwJu80N&PK?AuN:Ӈm;`BD|-\:u&FJQT3:5TwϨkA r kվ31RPݴ&'ܬگ'@]يD`&aگhն *VʼSAuՖ$U'3@Ū"3 V ̫}eBHJe+վզkN!BĪZF$OɕKץT&aB ZMkK3k'xԪt¶5S^폘Tm JT]QNضMRK=&TR#ULʏgWR  (OIwXuFrӪt6J-P}UzVkU:a1V}~U!U2asC<AjJP]贜J&lSHN@)եk 'ٌ^SڧSa U2aNTk?;Α%t=䷑ **]#ހKS8U7SaO$U1jrʏN݀k2p7Q&H]djz*jrp{u*nh*,'+>Za¥ih:B>V}4Vm=S~Vf4ԏP}Bj-XΈ+P@A4Zm=W&Pu[5|V!&N KSBmXթwFka5\[ܩ Z*;D+ |as40jxe6Kw jcaKW:uVTt$z <&nUu=l*Zkh>: T7t*O F4*LWBu=T*:P_hZ>JUtV@lZ.Y*; լ^E]].k\w@5ZПGqUSYڪ+6 ן6U?i_y1znDP*QUZ}N*JPejUi; q&uR'uR'cQ]Sͅ=;}";j[7^j$u!Ԕ!\VU7F,PS~ޚ*^[Sg+G>ע*PKQQ{ jGBaԆ,ws+Rt6~ߍƸoIITy9+Q IENDB`$$If:V 44l44l Pr(KSKS.?Kd Kd fz8<l=;;";$nh'W9!9+:^Cl s~ؚN s Y T f[S 0 b~ ؚNSf[Yef[HhNSOS ,{ NUSCQ NݔWw0RݔTё ݔv"l'lSir 0f[`Nvh0 10wS"l'lSݔv'`( NݔSvQSTir(WuNu;m-Nv͑^(u 20N$N'`"l'lSirvi_ wS"l'lSݔ/f$N'`"l'lSir 0;Nr^wƋ0 "l'lSݔv6RY Al3+ + 3NH3H2O = Al(OH)3!+ 3NH4+ "l'lSݔvSpfR:  $N'`"l'lSirsSSNN:_xS^ubvT4l SSNN:_xS^ubvT4l Al(OH)3 + 3H+  Al3+ + 3H2O 00Al(OH)3 + OH  AlO2 + 2H2O 0ug0 Al(OH)3lmϑv{ T+T gamolAlCl3vnm-NReQ+TbmolKOHvnm Blublmvir(vϑ Rg n(OH-) n(Al3+) AlCQ }vX[(Wb__ Al(OH)3lmϑ ba ______e Al3++Al(OH)3 ba ______e Al(OH)3 ____ba ____e Al(OH)3+AlO2 ba ______e AlO2 O10T100 mL 0.2 molL-1vAl2(SO4)3nm-NReQ100 mL 0.9 molL-1vNaOHnm BlubAl(OH)3lmv(ϑ/fY\? O200.1mol/LAl2(SO4)3vnm100mL-NReQ0.5mol/LNaOHnm_0R1.17glm BlReQNaOHnmvvSOy0 ݔ N҉ ݔCQ }X[(Wv Ny8^͑ST`Al3+0AlO2 0Al(OH)3,[NKN`7h$N$NvNlbc? 10Al3+ Al(OH)3 Al3+ ________________________________________ ________________________________________ 20AlO2 Al(OH)3 ____________________________________________________________ ________________________________________ 30Al3+AlO2 0 Al(OH)3 AlO2 ____________________________________________________________ ________________________________________ 0hcؚ0 S12345678910111213T{Hh10eNNaOHnmS^ SNH2SO4nmS^vir(/f ANaHCO3 BAl(OH)3 CNaHSO4 DNa2CO3 20(WOnm-NvAlO2-[hQlSbAl(OH)3 ^ bvg}YՋBR/f AH2SO4 BHCl CCO2 DNH3H2O 30 NRS^gT glmubv/f AAlCl3nmRǏϑNaOHnm BNaAlO2nmRǏϑvx CNaAlO2nmeQǏϑCO2 Dwpp4leQǏϑCO2 40 NRyP[e z_fNQv/f A0ݔ|beQ0RNaOHnm-N2Al+2OH-=2AlO2-+H2! B0Al(OH)3nNNaOHnm-NAl(OH)3+OH-=AlO2-+2H2O C0NaAlO2nm-NeQϑvCO22AlO2-+ CO2+3H2O= 2Al(OH)3!+CO32- D0Al2O3|+gnNNaOHnm-NAl2O3+2OH-=2AlO2-+H2O 50NWWAݔTёnNzvxT ReQǏϑ"l'lSnm dkenm-NX[(W AMgCl2 BAlCl3 CNaAlO2TNaCl DMg(OH)2TAl(OH)3 60 NRsQNAl(OH)3v'`(vSv/f A0Al(OH)3 /fnN4lv}vrlm B0Al(OH)3 8TD4l-Nv`nmir C0Al(OH)3 nN(l4l D0Al(OH)3^\N$N'`"l'lSir 70bBa(OH)2nmneQfwnm-N OSO42 hQlS:NBaSO4lm dkeݔCQ }v;NX[(Wb__/f A0Al3+ B0Al(OH)3 C0AlO2 D0Al3+TAl(OH)3 80 NR[d\ON[sa Nv&{v/f A\0.1mol / L AlCl3nmnReQ0.1mol / LvI{SOyvNaOHnm-N/ca, sa:Nlm(n(lm(lmXY B\0.1mol /L AlCl3nmnReQ0.4mol / LI{SOyvNaOHnm-N/ca, sa:Nlm(lmXY C\0.4mol / L AlCl3nmnReQ0.1mol / LI{SOyvNaOHnm-N/ca, sa:Nlm(n(lm(lmXY D\0.4mol / L NaOHnmnReQ0.1mol / LI{SOyvAlCl3nm-N/ca, sa:Nlm(lmXY(lmQ\(lmm1Y 90(uzH2SO40NaOHTAl:NSe6RSAl(OH)3, g NR Ny N Tv_ 2u:  EMBED Equation.2  YN:  EMBED Equation.2  N:  EMBED Equation.2  6RSI{ϑvAl(OH)3R A2u0YNmvSe T7hY BYNmvSeg\ CNmvSeg\ D NmvSe T7hY 100(WNaAlO2nm-N eQamolHCllSO ubbmollmT SeQcmolHCllSOe lmp`}Yn RSNaAlO2nm-N+TNaAlO2vir(vϑ/f A.  EMBED Equation.3  mol B.  EMBED Equation.3 mol C.  EMBED Equation.3 mol D.cmolb EMBED Equation.3 mol 110\AlCl3nmTNaOHnmI{SOymT _0Rvlmir-NTnm-N@b+TvݔCQ }(ϑvI{ RSAlCl3nmTNaOHnmvid\Sm^KNkS/f A013 B023 C014 D027 120 gNWWAl FeTё, nNϑvvx-N, Q(uǏϑvNaOHnmYt, \NuvlmǏn0mm0r^q0|pp, [hQSb~r|+gNSTё(ϑp`}YvI{, RTё-Nݔv(ϑ Rpe:N A070% B047.6% C052.4% D030% 130(WH2SO4xSǏvAl2(SO4)3nm-NnRNaOHnm ublmW(g)N@bRNaOHnmSOyVvsQ|YV vQ-Ncknxv/f  140QQ NRS^vyP[e z_ `$ё^\ݔnNvx-N __________________________________________________ a$ݔGrN"l'lSnmS^ __________________________________________________ b$"l'lSݔNϑvxS^ __________________________________________________ c$/lSݔnm-NReQǏϑ(l4l_________________________________________________ 150 NRN*NV-N *jPWhh:yReQvir(vϑ ~PWhh:yublmvϑN E-N bTBlv^SkXeQh-N  A B C D E nmReQvir(T{Hh^SqTwpp4lCO2ǏϑAlCl3nmǏϑvNH3+T\ϑNaOHvNaAlO2nmǏϑvCO2NaAlO2nmnRzHClǏϑMgCl2 AlCl3vmTmnRNaOHǏϑ160s gAlCl3TMgSO4mTnm TvQ-N NeReQNaOHnm _0RlmvϑNReQNaOHnmvSOy:NV@b:y BlSnm-NCl 0SO42-vir(vϑKNk:NY\  170\1.02g Al2O3TFe2O3vmTirn(WǏϑv100mL0.05mol/LvzH2SO4-N 6qTTvQ-NReQNaOHnm OFe3 0Al3 R}Y[hQlS:Nlm qQ(uSNaOHnm100mL RNaOHnmir(vϑSm^:NY\ PAGE  PAGE 1 2Al(OH)3 = Al2O3 + 3H2O % l m ϑ 0 0.1 0.4 0.5 v(NaOH)  2:Fjz|  F H J R T V d f ü}yuqmhd_ZU 5o(\ 5o(\ 5o(\5\ 5o(\5\o(\o(\o(\o(\ 5o(\5\ 5o(\5\ CJPJo( CJPJo(CJPJo(5\CJPJo(5\ CJPJo(CJPJ CJo(5\PJo(5>*\ PJ5>*\ PJ5\ PJ5>*\ PJ5\ PJ5>*\ PJ5\ PJ5\ PJ5\f l p t  ymgb]YIC>:o(\ 5o(\ o(mHsHCJOJQJmHsHnHtHUo(\ 5o(\ 5o(\ o(mHsHOJQJ5H*mHsHCJOJQJ5H*mHsHOJQJmHsHOJQJo(mHsHOJQJH*mHsHOJQJmHsHOJQJH*mHsHOJQJmHsHCJOJQJo(mHsHnHtHOJQJH*mHsHOJQJmHsHOJQJH*mHsHOJQJmHsH5o(mHsH\  $ & ( * , 0 2 4 6 8 < @ B D F J L N R V b d f h ĺ|tmeb[SIB mHsHaJH*o(aJmHsHH*mHsHaJ mHsHaJaJo(aJmHsH mHsHaJH*mHsHaJ mHsHaJo(aJmHsH mHsHaJH*o(aJmHsHH*mHsHaJ mHsHaJo(aJmHsH mHsHaJH*o(aJmHsHH*mHsHaJ mHsHaJo(aJmHsH mHsHaJH*o(aJmHsHH*mHsHaJ mHsHaJo(\h j n p r t z | ~   " $ ( 0 ȹ}vqljgeb^\YVo(H*o(QJo(o(o(H*o( 5o(\ 5o(\ 5H*o(\ 5o(\ 5o(\ 5o(\QJo(mHsH mHsHaJH*mHsHaJ mHsHaJo(aJmHsH mHsHaJB*`JphaJH*mHsHH*mHsHaJ mHsHaJo(aJmHsH mHsHaJ5H*mHsHaJ mHsHaJo(aJmHsH!0 4 6 P R r ~    ( T ` b |  " $ , 8 d j l n >*o(o(H*o(H*o( 5o(\o(>*o(>*o(o(H*o(H*H*o( 5o(\o(>*o(>*o(o(H*o( 5o(\o(>*o(>*o(o(H*o(H*o(H*o( 5o(\o(QJo( QJo(H*QJo(o(o(H*0 8:LNPRTnpvxz| .ý|vrlfbQJo( QJo(H* QJo(H*QJo( QJo(H*QJo( 5o(\ 5o(\ 5o(\ 5o(\ 5o(\o(o(H*o(o(H*o(o(H*o(o(o(o(o(o(aJo(aJ H*o(aJo(aJ H*o(aJo(aJ H*o(aJo(aJ H*o(aJo(aJ H*o(aJo(aJ H*o(aJo(aJo(>*o(&.0LNVZ\^jl Z\fhjlxz|HJRVĶztfb^ZT QJo(H*QJo(QJo(QJo(CJQJmHsHnHtHU QJo(H* QJo(H* QJo(H* QJo(H*QJo( jUo( QJo(H* QJo(H*QJo(QJo(QJo(QJo(QJCJQJmHsHnHtHUQJo( QJo(H*QJo( QJo(H*QJo( jUo(QJo( QJo(H*QJo(QJo(QJo( QJo(H*VX^`bDF¼zm`SFB*`JphOJQJ^JB*`JphOJQJ^JB*`JphOJQJ^JB*`JphOJQJ^JB*`JphOJQJ^JB*`JphOJQJ^JB*`JphOJQJ^JB*`JphCJOJQJ^J5\5\\o( QJo(H* QJo(H* QJo(H* QJo(H* QJo(H*QJo( QJo(H*QJo( QJo(H* QJo(H*QJo( jZUo(˾}pcVI@TVZfhtſ{wuqkga_[UQQJo( QJo(H*QJo(o( OJQJo(QJo( QJo(H*QJo(o(QJo(QJo( QJo(H*QJo(o( OJQJo(QJo(B*`JphQJo(H*B*`JphQJo(B*`JphOJQJo( PJo(H* PJo(H*PJo( PJo(H*PJo(B*`JphPJo(B*`JphPJo(H*B*`JphPJo(PJo( PJo(H*tvz &(:<>LP^`bfzvpja_][YWo(o(o(o(o(B*`Jpho( H*o(aJ H*o(aJo(aJ H*o(aJo(aJ H*o(aJ H*o(aJo(aJ H*o(aJo(aJ H*o(aJo(aJo(aJo(aJ H*o(aJo(aJ H*o(aJ H*o(aJo(aJB*`Jpho(aJH*B*`Jpho(aJQJOJQJ^JaJH*OJQJ^JaJ OJQJo(! 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