ࡱ>  Robjbjee%  ]]8Vi"###UUUUUUU$=Y[\Uu&"#&&U]]fiVT>T>T>&]RUT>&UT>T>M"N_]9$dNUV0VxN;\;;\(NN;\T#L#6T>+$,W$###UU<###V&&&&;\#########  #: wmWSwm?ef[!h2013J\ؚ NSf[,{N!kgՋ(Ջe2012-9-7090R 100R) S(u0Rvv[SP[(ϑH 1 C 12 N-14 O 16 Na 23 S-32 Cl 35.5 Mg 24 K-39 Mn-55 Fe 56 Cu 64 Zn-65 Se-79 I-127 }TN"IQn ,{`!wS N0 b,g'YqQ6\ k\2R nR12R0(Wk\~QvV*N y-N S gNy/f&{TvBlv0 1R{|/fSf[f[`NTxvzv8^(uKbk0 NRR{|OncT~cknxv/f 0 AHClO0HNO30SmH2SO4wQ:_'lS'` /f'lS'`x BH2O0HCOOH0Cu2OH 2CO3GW+T g'lCQ } /f'lSir CHF0CH3COOH0CH3CH2OHfnN4l /f5u( DHCOOH0H2CO30H2SO4RP[-NGW+T g$N*N"lSP[ /fNCQx 2. NR[ňnbd\ON|P[v'Y\evcsQ|v/f (00)  3.SV/fgqdqS5uSYt^lvňn:yaV0ňnQSuv;NS^-N N+T ASTS^ BRS^ CnbcS^ D'lS؏SS^ 4.  /fNyؚqe gsQSf[S^vϑSSYV@b:y ]weˆ1molSf[.@bvϑkJ  N=N:N9420O=O:N5000N-N:N154 Reˆ1molN-H.@bvϑKJ /f A.194 B.391 C.516. D.658 5. 25!T101kPae YNp0YNpTNp~bvmTp32mL NǏϑ'llmTv^[hQqp dS4ll b` Y0RSegv)n^TS:_ lSO;`SOy)\N72mL SmTp-NYNpvSOyRpe:N(00) A12.5% B25% C50% D75% 6. (W100mL+TI{ir(vϑvHBrTH2SO3vnm̑eQ0.01molCl2, gNJSBr-S:NBr2(]wBr2'lSH2SO3 )0Snm-NHBrTH2SO3vSm^I{N 0A.0.0075 molL-1 0B. 0.008molL-1 0C.0.075molL-1 0 D.0.08molL-1 b,g'YqQ6\ k\4R nR24R0(Wk\~QvV*N y-N gNyb$Ny/f&{TvBlv0 bY N_R, [FO NhQ_2 R 7. NA:N?OR_W8^pevpe

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"("￲|tl^L#h4AhOJQJ^JmHo(sHh4AhOJQJ^Jo(h4Aho(h4AhRo( hPFo(h4Ah|>*o(h4Ah|H* h4Ah|h4Ah|o(h4AhRKHOJQJ^Jo(h|KHOJQJ^Jo(h4Ah|KHOJQJ^J"h4Ah|>*KHOJQJ^Jo(h4A>*KHOJQJ^Jo(h4Ah|>*KHOJQJ^Jv!x! "" #"#$#$$$$j&&PQSVrVtVVZWWtXX $1$4$a$gd  $1$4$a$gd"z4$gd"zgdJ1$gdJ iWD2`igdqLgdgdK*("*","0"4"6":"<">"B"L"P"T"V"Z"\"b"n"r"v"x"|"~"""""""""""###### #"#ڶژ}rh OJQJ^Jo(hOJQJ^Jo(h4AhH*OJQJ^Jo(h4AhOJQJ^Jo(h4AhqLQJ^JmHo(sH"h4AhH*QJ^JmHo(sH#h4AhqLOJQJ^JmHo(sH#h4AhOJQJ^JmHo(sH&h4AhH*OJQJ^JmHo(sH("#$#x#|#########$$$$6$:$B$D$H$L$R$V$\$^$d$l$p$t$z$~$$$$$$$$$$$$$Өӵ㕍ooh4AhJH*OJQJ^Jo(h4AhJOJQJ^Jo(h4AhJo(h4Ah|o(h4AOJQJ^Jo(h4AH*OJQJ^Jo(h4AhqLOJQJ^Jo(h4AhH*OJQJ^Jo(h4AhH*OJQJ^Jo(h4AhOJQJ^Jo(h4Ah OJQJ^Jo(+$"%B%V%^%b%h%%%b&d&f&h&&&'''<'>'@'(PP P"P$PtPvPPPPPPPQQQQQQZRbRdRhRRRRRRRSSǴǥLjjh4AhJU^Jh4AhJH*OJQJ^Jo(jh4AhJU^JUjoh4AhJU^J hT^Jjh4AhJU^Jh4A>*OJQJ^Jo(h4AhJ>*OJQJ^Jo(h4AhJOJQJ^Jo(4\* MERGEFORMAT  2 (W\pog-NReQ20mL4l Rpl~T Tl4l-NneQ1mL FeCl3nm ~~nqlvnmHT r sSS6R_Fe(OH)3SOSYN 0 INCLUDEPICTURE "../../AppData/DOCUME~1/ADMINI~1/LOCALS~1/Temp/ksohtml/wps_clip_image-3579.png" \* MERGEFORMAT  3 SSN\pog_NReQ20mL4lT Tpog-NReQ1mLFeCl3nm /caGWST \dkpogS2u NSYNvpogNw>enfYR+R(uoIQ{gq\pog-NvmSO SN w0R pog-NvmSOONuN\He^0ُ*N[SN(ueg:S+R 0 INCLUDEPICTURE "../../AppData/DOCUME~1/ADMINI~1/LOCALS~1/Temp/ksohtml/wps_clip_image-3713.png" \* MERGEFORMAT  4 SYNpog-N\ϑFe(OH)3SOnNՋ{-N TՋ{-NnRN[ϑzvx n/ca SN w0RnmHQQs~rQmJm c@w~rQmJmnSEm g~S_0RĞrvFeCl3nm HQQs~rQmJmvSV S_0RĞrvFeCl3nmvSf[e z_:N 0 INCLUDEPICTURE "../../AppData/DOCUME~1/ADMINI~1/LOCALS~1/Temp/ksohtml/wps_clip_image-3893.png" \* MERGEFORMAT  5 ]wAl(OH)3SOYQ4l RFe(OH)3SO kX  b N Q4l0 1713R gyx\~(uMnO2TSmvx6RYCl2e )R(uR8T6eǏ\ϑSO2vNaOHnm[vQ>\lۏL8T6eYt0 1 [bSO2NǏϑNaOHnmS^vSf[e z_SO2+2NaOH = ________________0 2 S^Cl2+Na2SO3+2NaOH2NaCl+Na2SO4+H2O-Nv؏SBR:N________________0 3 8T6e>\lNkeT 8T6em:_x'` -N[X[(WCl-0OH-TSO42-0[ cvz8T6em-NSX[(WvvQN4yP[ NQzzlvCO2vq_T 0 `$cQTtGP0GP1SX[(WSO32-GP2e NX[(WSO32-_N NX[(WClO-GP3_____________0 a$[eHh ۏL[0(WT{aS NQQ[ekNSgsaT~0P [ՋBR3moLL-1H2SO401moLL-1NaOH00.01molL-1KMnO40m|-KInm0+}rwJՋm0 [ekgsaT~ek1S\ϑ8T6emNՋ{-N nR3 moLL-1 H2SO4nmHTx'` 6qT\@b_nmRnNA0BՋ{-Nek2ek318.11R [[S1uo0w(;NbR:NMnO2)6RYKMnO4elY N:o0wNǏϑVSOKOHTKClO3(Wؚ)n NS^ ub0x(K2MnO4)TKCl(u4lnnSk#n,nmxST K2MnO4lS:NMnO2TKMnO4; nSMnO2lm,Sm)nm ~vf_0Rm+}rvrKMnO4.VT{: (1)o0w6RYK2MnO4vSf[e z_/f:________________________________________________ (2) K2MnO46RYKMnO4vyP[e z_/f:_________________________________________________ (3)(u2.5 go0w(+TMnO280%)ۏL N[,{KMnO4vt;`Nϑ. (4) KMnO4Npv~kxxxSvNa2C2O4S^ubMn2+TCO2,S^vSf[e z_/f:_______________ (5) N6R_vKMnO4NT0.165 g,p`}YN0.355 g~Na2C2O4S^[hQ,{KMnO4v~^. S123456T{HhACCBCDS789101112T{HhBB DAB CA CB13.1 Nx-NS+T gvyP[Rg SO32-wQ g:_v؏S'` Vdkx'`agN NSO32-NNO3-/f NqQX[v0NSm)T@b_v4NՋmۏLv[RgSw,{NNxSTnRϑvm|KInm HT݄r f gNO3 bNO2- 6I- + 2NO3- + 8H+ = 3I2 + 2NO!+ 4H2Ob2NO2-+ 2I + 4H = I2 + 2NO!+ 2H2O ,{NNnR(uvxxSvBaCl2nm g}vrlmgQ f gSO42 ,{ NNnRNaOHnm Rp NuvlSOOnmv~rwJՋ~S݄ f gNH4 ,{VNReQϑ]xxxSvAgNO3nm glmNu fS gCl bSO42 (ubAgCl!bAg2SO4! GW NnNz]xx) Yn (W NB\nm-NnRx'`KMnO4nm N*r fl gNO2- &TRNO2-yP[NwQ:_'lS'`vx'`KMnO4nmS^ OKMnO4nm*r5NO2- + 2MnO4 +6H = 5NO3 + 2Mn2 + 3H2O 0@bN x-N[X[(WvyP[ gSO42-0NO3-0NH4+[ NX[(WvyP[ gSO32-0NO2-02 Ջm-NnRm|KInm@bSuS^vyP[e z_/f6I- + 2NO3- + 8H+ = 3I2 + 2NO!+ 4H2O03 1uNՋm-NX[(W@wSO42 @bN hՋm-N/f&TX[(WCl- eQcdSO42 vr^pb0hvel:NS\ϑՋm nRϑvBa(NO3)2nm YnS NB\nm nR]xxxSvAgNO3nm g}vrlmNu RX[(WCl-04 ncvJTw /fcvzNOSNkxxWx薄vb_b 9hnckxxWx薄vb_bv:gtSwqevqp0+Tkxё^\wwvQpTkxxvuNI{Ǐ z-NNuvSO2 ʑ>e0Rzzl-N (WIQgq0p\-Nvё^\'lSirI{vPS\O(u N SO2 N'llS^ubSO3 SO3 nN4lTb_bH2SO40VdkS_(Wpt-NEQeQ+T g\ϑNOvSO2lSO babaeQO2e ubSO3 _{ gPSBRSN @bNNO^/fwNPSBRv\O(u Ǐ z-NSuvSf[S^/f2NO+O2= 2NO2 NO2+SO2 = SO3 + NO0 14CH4 g + 2O2g !CO2g + 2H2Ol %H=-890.3KJ/mol1 V:N2COg + O2g ! 2CO2g %H=-571.6KJ/mol)R(uϑ[R`_ @bN 2CO2g !2COg + O2g %H=571.6KJ/mol2 V:N2H2 g + O2g ! 2H2Ol %H=-566KJ/mol Tt @bN2H2Ol !2H2 g + O2g %H=566KJ/mol 3 1 +2 +3 _ CH4 g + CO2g !2COg + 2H2 g %H=274.3KJ/mol ㉾ub1m3hQ CO@bpϑ:NX 1m3=1000L CH4 g + CO2g !2COg + 2H2 g %H=274.3KJ/mol 44.8L 274.3KJ 1000L X X=5520KJ=5.52103KJ 15. ㉐g(1) CuSO45H2Ov(ϑ:Nx H2Ov(ϑ:Ny CuSO45H2Ovv[RP[(ϑ:N250 CuSO4vv[RP[(ϑ:N160  EMBED Equation.3  16x=5 (x+y) x:y=5:11 Ee@bCuSO45H2ONH2Ov(ϑKNk:N5110 (2) 7hT-NCuClv(ϑ:Nx 1uSf[S^e z_SwCuCl Fe2+ Ce4+  EMBED Equation.3  x=0.100 0 molL-124.6010-3L99.5 gmol-1 x=0.244 8 g  EMBED Equation.3 100%=97.92% 97.92%>96.50% Ee7hT-NCuClv(ϑRpe&{ThQ0 16.eu 17. 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