ࡱ>  R>~bjbj eeb !!!!!!!!8!$ #!4#Q$Q$Q$Q$///$ZQ!8-/88!!Q$Q$ >&R&R&R8!lQ$!Q$&R8&R&RBs q!,3Q$ A1]!O0fT0N(Q3!3/,0&R152///QX///8888///////// : NSNؚ2013J\ؚ N,{N!kgSf[ՋyHr QNRQi_ [Nsv 2012-9-8 S(u0Rvv[SP[(ϑ H 1 O 16 C 12 S 32 K 39 Fe 56 Na 23 N 14 Mg 24 Cl35.5 BaSO4 233 CuSO4 160 CuSO45H2O 250 N0 bkS gN*Ncknx y,k\3R qQ48R 1. 1803t^cQSP[f[ :NяNSf[SU\`Y[NZW[W@xvSf[[/f AVvS\ BlVvbt! COVvwcR+Y DVvdlYu 2. NA:N?[OR_W8^pe NRS-Ncknxv AhQrQ N 22.4LCO2TO2mTlSO-N+T gv'lSP[pe:NNA B0.1mol Fe(W0.1mol C12-NEQRqp lyv5uP[pe:N0.3NA C2mol SO2T1mol O2(W[핹[hV-NRpV2O5PS EQRS^T [hVQRP[;`pe:N2NA D\0.1mol Cl2NϑNaOHnm(W8^)n NEQRS^ lyv5uP[pe:N0.1NA 3. R{|el(WSf[f[yvSU\-Nw0RN^8^͑v\O(u0 NRR{|hQTtv/f `$9hncxRP[-N+T gv"lSP[*Npe\xR:NNCQx0NCQxI{ a$9hncS^-N/f&T g5uP[vly\Sf[S^R:N'lS؏SS^T^'lS؏SS^ b$9hncRce|/f&TwQ gN\sa\Rce|R:Nnm0SOTJmm c$9hncS^-NvpHe^\Sf[Sf[S^R:N>epS^T8TpS^ A`$a$ Bb$c$ C`$b$ Da$c$ 4[2012hQVwS] cknxh:y NRS^vyP[e z_v/f(00) Akxxݔnm-NReQǏϑ(l4lAl3 3OH ===Al(OH)3! 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R4le NNaǏN;R^? 0 V{ 200 0.6molL-1Fe2(SO4)3T1.2molL-1CuSO4vmTnm200mL ReQN[ϑ|EQRS^T Km_nm-NFe2+NCu2+ir(vϑKNk:N21 RReQ|vir(vϑ/fY\id\ NDR 21nfsN N $NZPS,{N~R \sSZP,{N ZP,{NeR N0A0B0C0D0ENySn'`STir R+R1u3yP[Fe3+0Ba2+0Al3+0Na+0Ag+T4yP[NO3 0OH 0SO42 0Cl 0CO32 -NvTNy~byP[ N͑ Y 0sZPY N[`$ATEvnm>fx'` 0.1molL 1AnmvpH\N13 a$(WBvnm-NnReQ(l4l g}vrlmub ~~R(l4lǏϑ lmm1Y b$(WCvnm-NReQ| nmv(ϑXR c$(WDvnm-NReQǏϑvBa(OH)2nm l glm0 VT{ NR1 9hncN NN[ceA EvSf[_ A B C D E 0 2 (uyP[e z_h:yAnm>fx'`vSV 0 3 QQb$0c$vyP[e z_b$  c$ 0 N0 gA0B0C0D0ENy8^STir /f1u Nh-NvyP[b_bv 3yP[K+ Na+ Cu2+ Al3+4yP[SO42 HCO3 NO3 OH :NNt+R NSTir R+R[bN N[ vQ~g/f `$\[NnN4lT D:N݄rnm vQNGW:Nernm a$\EnmneQ0RCnm-NQs}vrlm ~~nR lmn b$ۏL0qrS^ N gB0C:N+}rǏ݄rst  c$(WTnm-NReQ]xxnm QRǏϑz]xx S gA-N>eQerlSO S gC0D-NNu}vrlm d$\B0D$NnmmT *glmblSOub0 9hnc N[kXzz 1 QQB0DvSf[_B D 0 2 \+Tlmol AvnmN+Tl mol EvnmS^Tr^ N_0RNySTir STirSf[_:N 0 3 C8^(u\OQ4lBR (uyP[e z_h:yvQQ4lSt 0 4 (WAnm-NReQ\ϑonwpp4l vQyP[e z_:N 0 5 T20mL 2mol/L Cnm-NReQ30mL Enm EQRS^T_0R0.78glm REnmvir(vϑSm^S/f moI/L0 NSNؚؚ N,{N!kgՋT{aS ^S bk3R qQ48R S12345678T{HhS910111213141516T{Hh N0kXzzqQ47R 170(1) 2 sa yP[e z_ 3 T vv 4 1801 A B C 2 A D  D E (3) 4 190(1) 2 3 a b c 4 N0{ 200 21 N01 A B C D E (2) (3) b$ c$ N01 B D (2) (3) (4) (5) NSNؚ2013J\ؚ N,{N!kgSf[ՋST{Hh bk3R qQ48R S12345678T{HhADDCCDDAS910111213141516T{HhBACDCBCC N0kXzzqQ47R 170(1) 4Na+O2==2Na2O mĞr  2Na+O2 pq Na2O2 2Na2O2+2H2O=4Na+ +OH +O2! 2 Fe3+ +3H20 = Fe(OH)3(SO)+3H+ sa HQ g~rlmub QReQkxxlmn yP[e z_Fe(OH)3+3H+=Fe3++3H2O 3 zvxTQ\ vvzvx2bkNyP[4l Q\2bkNyP['lS 4 8Fe3++NO3 +10H+==NH4++8Fe3++5H2O 8:1 1801 A NaI BNaClO CAgI  A!D2I +ClO +H2O =I2 +Cl +2OH D!EI2+5ClO +2OH ===2IO3 +5Cl +H2O 3 yP[e z_ 2Fe3+ + SO2+2H2O =2Fe2+ + SO4 2- +4H+ 4 Sf[e z_ Cl2+2NaOH====NaCl+NaClO+H2O 190(1) 2.1 250 ϑR{0pog0sth04Yn{ 2 BCAFED 3 aNOb NO cؚ 4 ͑eM6R N0{ 200 0.16 V0DR 21 N0A- Na2CO3 B-AgNO3 C-FeSO4 D-AlCl3 E-Ba(OH)2 (2) CO32 +H2O HCO3 +OH b$ 2Fe3+ + Fe = 3Fe2+ c$ Al3++4OH ===[Al(OH)4] N0(1)KNO3 CuSO4 (2)Na2CO3 (3)  EMBED Equation.3   (4) EMBED Equation.3   EMBED Equation.3  5 1b5     20090323 s~ Y T :W s~ Y T :W >`@`D`\`n`p`t`~``````````aaa aaaa$a&a(a*a0a測zczP$hP:h0vB*aJmHo(phsH,hP:h0vB*OJQJaJmHo(phsH!hP:h0vB*aJmHphsHh0vB*aJmHo(phsH h0vaJo(hP:h0vaJo(hMQh0v5aJo(h`h0vOJQJaJo(h0vOJQJaJo()h`h0v0J!5>*@KHOJQJhh`h0vOJQJaJh`h0vOJQJaJ0a2a4a8aaBaDaFaHaJaLaNaPaTaXaZa\a`afahajata~aٰٝىzcMٝz+hP:h0vB*H*QJaJmHo(phsH,hP:h0vB*OJQJaJmHo(phsHhP:h0vB*QJaJph'hP:h0vB*H*aJmHo(phsH$hP:h0vB*aJmHo(phsH+hP:h0vB*H*QJaJmHo(phsH$hP:h0vB*H*aJmHphsH!hP:h0vB*aJmHphsH)hP:h0vB*OJQJaJmHphsH~aaaaaaaaaaaaaaaaaaaaabNbPbRbTbVbXbZb\b^b`b~bbb̹ݦ̹ݘuulalalalalalWhP:h0vH*aJhP:h0vQJaJhP:h0vaJ hP:h0vB*QJaJo(ph#hMQh0v5B*QJaJo(phh0vB*QJaJo(ph$hP:h0vB*aJmHo(phsH$hP:h0vB*H*aJmHphsH!hP:h0vB*aJmHphsHhP:h0vB*QJaJph%hP:h0vB*QJaJmHphsH"aaaFbRcccd*aJhP:h0vH*aJhP:h0vaJo(hP:h0vQJaJo(hP:h0vaJhP:h0vQJaJ@eeeeeeeffff"f&f(f*f,f2f8f:fhhhhwjwZwjwhMQh0v>*OJQJ^Jo(h0v>*OJQJ^Jo(hMQh0vOJQJ^Jo(hP:h0vo(hP:h0vH*QJaJo(hP:h0vH*QJaJo(hP:h0vQJaJo(hP:h0vQJaJhP:h0vH*QJaJhP:h0vH*aJhP:h0vaJhP:h0vH*aJo(hP:h0vH*aJhP:h0vaJo(#eff"f`fkUU  @d$Ifgd0vxkd$$Ifl0064 layt0v  @id$IfWD2`igd0v`fbfffg@ggo]]]? 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