ࡱ> hjabcdefg R&bjbj"L 8LK#ȥj#((((333$2Ԫ6Ť1<!3"C3|1<1<Ť((F OOO1<f<((O1<OO7|ӣ(1toLTǞF0ȥ  M ӣ ӣ3,4O5m6333ŤŤN333ȥ1<1<1<1< 333333333 : z+g;`~  INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/Ye^YDn.tif" \* MERGEFORMAT  NN0]ϑl(W㉘-Nv^(u (WNNSf[S^-N ~8^OQsN N$Ny`QN/f(Wv Tr`(V0m0l) NvS^irۏLS^e 1uN glmb glSOub bS^MRTmTirv(ϑbSOy NN7h X[(W(ϑ]bSOy]N/f(WS^irr` N TvS^-N 1uNgyS^irRSRS^ [S^MRTir(X[(W(ϑ]bSOy]0OncS^MRTv(ϑ]bSOy]ۏLv{ {y]ϑl{0]ϑl{(WSvQSTirv{-N g@w^lv^(u0 0O100I{ir(vϑvN20O20CO2mTlSOǏNa2O2T SOyS:NSSOyveq \f(8,9)( T)n TS) ُemTlSO-NN20O20CO2ir(vϑKNk:N(00) A.36"46"1 B36"36"2 C66"76"3 D66"96"0 T{Hh0A ㉐g0SmTlv;`SOy:NV RV(N2)V(O2)V(CO2)eq \f(V,3) ǏNa2O2T SOyS:Neq \f(8V,9) Na2O2 2CO2===2Na2CO3 O2000V 211 eq \f(2V,9)eq \f(V,9)V eq \f(8V,9) ُeV(N2)2 V(N2)eq \f(V,3)00V(O2)2 V(O2) eq \f(V,9)eq \f(4V,9) V(CO2)2 V(CO2) eq \f(2V,9)eq \f(V,9) Onc?OR_W[_ T)n TSelSOvir(vϑKNkI{NvQSOyKNk0 n(N2)6"n(O2)6"n(CO2)V(N2)6"V(O2)6"V(CO2) eq \f(V,3)6"eq \f(4V,9)6"eq \f(V,9)36"46"1 0O200Rp4.54 g Na2CO3TNaHCO3vmTir(ϑ NQSS iRYOVSOv(ϑ:N3.30 g0{SmTir-NNa2CO3v(ϑRpe0 T{Hh026% ㉐g02NaHCO3eq \o(=====,\s\up7(%))Na2CO3 H2O! CO2! 1YSv(ϑ:N4lTN'lSx -N1Y͑:N4.54 g 3.30 g1.24 g Rm(NaHCO3)eq \f(1.24,62)284 g3.36 g Rm(Na2CO3)4.54 g 3.36 g1.18 g @bNNa2CO3v(ϑRpe:Neq \f(1.18 g,4.54g)100%26%0 NN0Na2CO3TNaHCO3v'`(S{ Na2CO3TNaHCO3\O:NxxvckvTx_v Ne g:S+RS gT|0RgY N 1N:_x(H )S^NuCO2 FOS^vgRp z^ N T 9hncS^vgRp z^SۏLt+R0 Tvx-NnReQNa2CO3nm(_YexǏϑ)2HCl Na2CO3===2NaCl CO2! H2OTNa2CO3nm-NnReQvx(_Yex N) HCl Na2CO3===NaCl NaHCO3(ell) HCl NaHCO3===NaCl CO2! H2O0 1uN NRgSw N TvnRz^Nu N Tvsa ُ1\/f N(uvQNՋBRt+RNa2CO3nmTvxvSt0 2Gwpp4le S^vyP[e z_} N T FOS^ubCaCO3lm Ee N(uwpp4lt+R[N0 3GNaOHnme Na2CO3 NS^0NaHCO3S^ FO1uNl gf>fsa Ee N(uNaOHnmt+R[N0 4NaHCO3 N3z[ SpRSubNa2CO3 ُfNa2CO3kNaHCO33z[0 Te_NS(uRpldSm(WNa2CO3-NvNaHCO30 5CO2eQNaOHnm CO2\ϑeubNa2CO3 CO2Ǐϑe Su COeq \o\al(2 ,3) CO2 H2O===2HCOeq \o\al( ,3) vS^ g~ubNaHCO30Ee(uCO2velSdSm(WNaHCO3nm-NvNa2CO30Na2CO3vn'`:_NNaHCO3vn'` (WN[)n^ NqTvNa2CO3nm-NeQCO2 OgQNaHCO3vfSO Na2CO3 CO2 H2O===2NaHCO2!0 0O300s g25 mL 2 molL 1Na2CO3nmT75 mL 1 molL 1vzvx0`$\Na2CO3nmban0Rzvx-Na$\zvxbanR0RNa2CO3nm-N (WhQrQ NNuvlSOvSOy(00) A.GW:N0.84 L B.GW:N0.56 L C`$>a$ Da$>`$ T{Hh0C  EeHCl Nn(CO2)0.025 mol 0O400gSf[Y;mR\~2k6RS~Na2CO3nmv^[Ǐ z-NvvsQ0SO bvՋBR gA 'YtwBvxC"l'lSnmDonwpp4l0 N T Tf[v6RY[eHhvS^Am zR+RY N 2uNaOHnmeq \o(  !,\s\up7(CO2))Na2CO3nm YNNaOHnmeq \o(  !,\s\up7(CO2),\s\do5(`$))NaHCO3eq \o(  !,\s\up7(Rpr^|pp),\s\do5(a$))Na2CO3VSOeq \o(  !,\s\up7(H2O))Na2CO3nm NNaOHnmeq \o(  !,\s\up7(CO2),\s\do5(b$))NaHCO3nmeq \o(  !,\s\up7(NaOH),\s\do5(c$))Na2CO3nm [b NR (1)cQ2u0YN$NeHhv;N:p 2ueHh_______________________________________________________0 YNeHh_________________________________________________________0 (2)Ǒ(uNeHh6RS~Na2CO3nm vQ[vsQ. g________________________________________________________________________ ________________________________________________________________________0 (3)GPS^b$@b_vNaHCO3nm-N+T gNa2CO30s)R(uA ^DVyՋBRfNa2CO3vX[(W `O@b bvՋBR g______(kXՋBRNS)0 A.CuCl2nm0000 BMgSO4nm Conwpp4l Dzvx (4)GPS^a$@b_vNa2CO3VSO-Nm g*gR㉄vNaHCO30YN Tf[ bonwpp4lKm[vQ-NvNaHCO3v(ϑRpe YN Tf[&T0R[vv________(kX  b N ) f{@bvpenc N {ft1u0 ________________________________________________________________________0 T{Hh0(1)CO2veQϑ Nfc6R0Ǐ zA~t d\O YBg (2)S^b$^EQRۏLS^b$Nc$@b(uNaOHnmvSOy^vI{ (3)AbB (4)0VSO7hT(ϑTlm;`(ϑ VSO!VSO!nmI{Ǐ z ǏNA~t0NeHh]Y)R(u$NI{NNaOHnm TvQ-NNN-NeQǏϑCO2 OvQlS:NNaHCO3 Q\$NNmT VSuNaOH NaHCO3===Na2CO3 H2O ub~QvNa2CO3nm0(3)(4)^)R(uNa2CO3TNaHCO3v N TegBl0 N Nё^\SvQSTirvce 1z4xp (1)yrkr `$0qrS^Na (Ğr)0K (+}r) a$ grnm +T gvyP[,Fe2 ,Fe3 ,Cu2 ,MnOeq \o\al( ,4) r,Em~r,Ğr,݄r,+}r b$ grVSO ~rCu0Fe2O3(~hr) ~rFe(OH)3 ~rCu2(OH)2CO30FeSO47H2O ݄rCu(OH)20CuSO45H2O ўrCuO0FeO0MnO20pў EmĞrNa2O20AgBr }vrFe(OH)20CaCO30BaSO40AgCl0Al(OH)30Mg(OH)2 (2)yrk'`( `$(WN[agN No}v grir(vmĞrVSOS gNa2O20 a$GSCN >f~rvS gFe3 0 b$8^vSnNNaOHnmv}vrlm gAl(OH)3 Sn0 c$ NnN4lTzHNO3(bHCl)vSTirBaSO4(}vr)0AgCl(}vr) (3)yr_S^ `$N:_xS^NulSOvir(;mlё^\ YNa0Al0ZnI{ N3z[v1_xv Yxxv0xx"lvI{0 a$NxS^NulSOvir(YAlI{US(vI{0 b$eN:_x0SN:_xS^vir( ё^\US( YAl$N'`STir YAl2O30Al(OH)3I{1_xv YNH4HCO30(NH4)2CO3I{1_xvx_v YNaHCO30NaHSI{0 c$NH2ONulSOvir( ;mlё^\US( YNa0K0Mg(Rp)0Fe(ؚ)n)I{ё^\Ǐ'lSir YNa2O2I{0 (4)yrkvlbcsQ| `$ޏ~lS Naeq \o(  !,\s\up7(O2))Na2Oeq \o(  !,\s\up7(O2))Na2O2 !Na2CO3(bNaOH)  INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/T22a.TIF" \* MERGEFORMAT   INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/T13.TIF" \* MERGEFORMAT  a$ N҉lS  INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/T14.TIF" \* MERGEFORMAT   INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/T15.TIF" \* MERGEFORMAT  2el cN NekRgv __ŏtn`ؚHe㉘ [{ Oo`![{ Oo`!T|wƋ![~bz4xS!ct$Re!_Q~! 0O500]w g NV@b:yir(vNlbcsQ|  INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/T16.TIF" \* MERGEFORMAT  ՋVT{ (1)QQBvSf[_0000 DvSf[_00000 (2)QQ1uElSbFvSf[e z______________________________________0 (3)QQ(uKSCNt+RGnmvyP[e z__________________________________________________________ TGnmReQAvyP[e z_________________________________________________________________________0 T{Hh0(1)FeCl20KCl (2)4Fe(OH)2+O2+2H2O===4Fe(OH)3 (3)Fe3++SCN-===[Fe(SCN)]2+ 2Fe3++Fe===3Fe2+ ㉐g01u0qrS^K+(+}r)T NnNz]xxv}vrlm(AgCl)NNyr_sabS^ SwG/fSTirKCl1u}vrlm(Wzzl-N'lSlS:N~rvlm wSF:NFe(OH)3 cQ}vrlmE:NFe(OH)2 HNG1\:NFeCl3ANFeCl3S^_0RB ANvxS^_0RBTlSO HNBN[/fNvnmFeCl2 A/fFe lSO/f"llNBS^vgnm1\/fKOH0  NVSn'`ݔvN:_xS^v gsQ{ 1BlNirAl(OH)3vϑS_n(Al3 )6"n(OH )e"16"3e n[Al(OH)3]eq \f(1,3)n(OH ) S_16"4n(Al3 )6"n(OH )16"3e n[Al(OH)3]4n(Al3 ) n(OH ) S_n(Al3 )6"n(OH )d"16"4e n[Al(OH)3]00 2BlS^irxvϑ S_n[Al(OH)3]n(Al3 )e n(OH )3n(Al3 ) S_n[Al(OH)3]n(Al3 )e 傱x N n(OH )3n[Al(OH3)] 傱xǏϑ n(OH )4n(Al3 ) n[Al(OH)3]0 0O600T20 mL 1molL 1vA l2(SO4)3nm-NReQ30 mL KOHnm EQRS^_0R0.78 glm RKOHnmvir(vϑSm^S/f(00) A.1 molL 1 B.3 molL 1 C5 molL 1 D7 molL 1 T{Hh0AC ㉐g0V:Nn(Al3 )0.04 mol n[Al(OH)3]0.01 mol @bNQKOH NTKOHǏϑ$Ny`Q 9hnc N Tv҉^ SN g N Tv㉘el0 (1)S_KOH Ne Al3 3OH ===Al(OH)3! n(KOH)3n[Al(OH)3]0.03 molc(KOH)eq \f(0.03 mol,0.03 L)1 molL 1 (2)S_KOHǏϑe lN cS^vǏ zz^ `$Al3 3OH ===Al(OH)3!ubn[Al(OH)3]0.04 molmn(KOH)0.12 mol a$Al(OH)3 OH ===AlOeq \o\al( ,2) 2H2Onn[Al(OH)3]0.04 mol 0.01 mol0.03 mol n0.03 mol Al(OH)3Smn(KOH)0.03 mol Eec(KOH)eq \f(0.03 mol 0.12 mol,0.03 L)5 molL 10   INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/ĉ_;`~.tif" \* MERGEFORMAT  ,g(W㉘Ǐ z-N bo SV/f_euAl(OH)3RnevNy`Q0Yg㉘Ǐ z-N \OQlmKOHnmReQϑvSSVa NVa NSv‰0W‰[0RReQNaOHnmev$Ny`Q ُ7hsSS2bko0 ]wn(Al3 )Tn[Al(OH)3]Bln(OH )e S_n[Al(OH)3]n(Al3 )e n(OH )3n(Al3 )b3n[Al(OH)3]  S_n[Al(OH)3]n(Al3+)e g$Ny`Q傱x N n(OH-)= 3n[Al(OH)3]傱xǏϑ n(OH-)=4n(Al3+)-n[Al(OH)3] NmQFe2 0Fe3 v'`(Sh 1Fe2 e g'lS'` S g؏S'` Fe3 wQ g:_v'lS'`0 Fe2 eq \o(%))&,\s\up7(O20H2O20Cl20Br20I20HNO30MnO\o\al( ,4)(H )),\s\do5(S2 0H2S0SO20SO2 30I 0Cu0Zn))Fe3 Y2Fe2 Cl2===2Fe3 2Cl 2Fe2 H2O2 2H ===2Fe3 2H2O 2Fe3 Cu===Cu2 2Fe2 Fe 2Fe3 ===3Fe2 (1)M6RFeSO4nmeR| 2bkFe2 'lS [[6RYFe(OH)2e2bkFe2 'lS(ueMFeSO4nm M6RNaOHnmv4lnql0 (2)Fe2 NMnOeq \o\al( ,4)(H )0NOeq \o\al( ,3)(H )I{(W4lnm-N N'YϑqQX[ Fe3 NI S2 SOeq \o\al(2 ,3)(W4lnm-N N'YϑqQX[ GW/fV:NSu'lS؏SS^0 (3)dBg dSFeCl2(FeCl3)RH2O2b/l4l dSFeCl3(FeCl2)RFe|0 2Fe3 NFe2 vhel (1)‰[l Fe3 vnmHThĞr Fe2 vnmHTEm~r0 (2)SCN l neQKSCNbvQNSn'`vkx0lSirnm HT@~r/fFe3 nm NS~FOnR\ϑ/l4lTS~r:NFe2 nm0 (3)xml R+RReQxm(YNaOHnm) ub~rlm:NFe3 nmHQub}vrn}rlm SŏlS:Npp~r gTS:N~r:NFe2 nm0 (4)KMnO4(bn4l)l R+RReQ\ϑx'`KMnO4nm(bn4l) OKN*r:NFe2 nm NOKN*r:NFe3 nm0 (5)ܔGrl R+RReQܔGr ܔGrnNnmnS:N݄~r:NFe3 nm ܔGr Nn nmr NS:NFe2 nm0 0O700Ğܔw(CuFeS2)/f6RSܔSvQSTirv;NSeKNN ؏S6RYkxSvSTir0 (1)QpܔvS^:N 8CuFeS2 21O2eq \o(=====,\s\up7(ؚ)n))8Cu 4FeO 2Fe2O3 16SO2 CuFeS2-NFevSTN:N 2 S^-N؏SvCQ }/f____________________(kXCQ }&{S)0 (2)ǏNkxx(K2S2O8)wQ g:_'lS'` S\I 'lS:NI2 S2Oeq \o\al(2 ,8) 2I ===2SOeq \o\al(2 ,4) I2 Ǐ9eSS^_ Fe3 0Fe2 GWSPS NS^0Ջ(uyP[e z_h:yFe3 [ NS^PSvǏ z______________________________________________________________ ________________________________________________________________________0 ________________________________________________________________________( N_Ms^)0 (3))R(uĞܔwQpܔNuvp#n(+TFe2O30FeO0SiO20A l2O3)S6RYFe2O30el:N `$(uzvxxmSp#n Ǐn0 a$nmHQ'lS QReQǏϑNaOHnm Ǐn \lmmm0r^q0Eqp_Fe2O30 ncN NOo`VT{ NR adSAl3 vyP[e z_/f___________________________________________0 b (ucOvՋBR [p#n-N+T gFeO0 cOvՋBRzvx0zkxx0KSCNnm0KMnO4nm0NaOHnm0x4l @b ՋBR:N________________________0 fp#n-N+T gFeOv[sa:N____________________________________ ____________________________________________________________0 T{Hh0(1)Cu0O0(2)2Fe3 2I ===2Fe2 I2 S2Oeq \o\al(2 ,8) 2Fe2 ===2SOeq \o\al(2 ,4) 2Fe3 (yP[e z_ NMs^ NcbR) (3)a.Al3 4OH ===AlOeq \o\al( ,2) 2H2O bzkxx0KMnO4nm zkxxxmSp#n@b_nmOKMnO4nm*r ㉐g0(1)9hnc'lS؏SS^-NSTNSS`Q$ReQ'lST؏SvCQ } 8Cu 2Fe 2S2 2 21O20eq \o(=====,\s\up7(ؚ)n))8Cu0 4Fe 2O 2 2Fe2 3O3 2 16S 4O2 CuTOvSTNMNON ؏S0 (2)V:NFe3 g'lS'` NI Su'lS؏SS^2Fe3 2I ===I2 2Fe2 ubvFe2 wQ gN[v؏S'` SSNS2Oeq \o\al(2 ,8)SuS^S2Oeq \o\al(2 ,8) 2Fe2 ===2SOeq \o\al(2 ,4) 2Fe3 0 (3)V:NA l(OH)3wQ g$N'` SNn(WNaOHnm-N S^_:NAl3 4OH ===AlOeq \o\al( ,2) 2H2O0 V:NFe2 g؏S'` SOx'`ؚ0xnm*r VdkSN(uzkxxn㉉p#nTQ(W@b _nm-NReQx'`ؚ0xnm ‰[sasSSnx[vQ-N+T gFeO0g INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/YePg`NT{.tif" \* MERGEFORMAT  1B0[ NNyP[GKSCNnm>f~r0] 2C0[GrbeQzkxx-N g"ll>eQGrbeQkxxܔnmT]xxnm-N R+R gVSOܔTgQ nm(ϑQ{0] 3D[epNvݔbݔXTyP[S^ub 'lSubўrv'lSir0] 4D[ yA -N^ gxxlmub yBTC5uw N[R`0] 5A 0[~rlm^:N"l'lS "l'lSSpRub~hrv'lS0] 6C0[]S^vFe3 vir(vϑ:Nx 9hnce z_Fe 2Fe3 ===3Fe2 SwubvNyP[vir(vϑ:N1.5x VdkS_]S^vFe3 vir(vϑ6"*gS^vFe3 vir(vϑx6"1.5x26"30] 7`$2Cu O2eq \o(=====,\s\up7(%))2CuO0a$CuO H2SO4===CuSO4 H2O b$CuSO4 2NaOH===Cu(OH)2! Na2SO4 c$Cu(OH)2eq \o(=====,\s\up7(%))CuO H2O d$Fe CuSO4===FeSO4 Cu 8,{NekNaOHnm8T6eCO2O_fbPQS:_Q\ \NYLu'YlS[fbPS*v c@wё^\ݔTNaOHnmS^ubH2 O_fbPQlSOS:_SX'Y VdkSwegN0 CO2 2OH ===COeq \o\al(2 ,3) H2O,2A l 2OH 2H2O===2A lOeq \o\al( ,2) 3H2! 9CaCO3eq \o(=====,\s\up7(ؚ)n))CaO CO2! 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2H2O===4NaOH O2!2Na2O2 2CO2===2Na2CO3 O2EeCycknx BnNzzl-N g~S:Nxx}vr|+g EeAycknxDy>f6q_Ncknx0 4gernm-N>eeQݔGrT g"llNu R NRyP[(W勶nm-N[SN'YϑX[(Wv/f(00) A.Na B.Mg2 C.S2 DHCOeq \o\al( ,3) T{Hh0A ㉐g0Acknx Na (Wx0x'`nm-N V NSuS^vSN'YϑX[(WB Ncknx Mg2 (Wx'`nm-N ubMg(OH)2lmC Ncknx S (Wx'`nm-N NH S^ NuH2SD Ncknx HCOeq \o\al( ,3)(Wx'`bx'`nm-N NH bOH SNS^0 5 gsQnm-N@b+TyP[vh NR$Recknxv/f(00) A .ReQ]xxxS QnRKSCNnmT g~rir(ub RSnm-NN[ gFe3 X[(W BReQvx gOonwpp4lSQmJmvlSOub RSnm-NN[ g'YϑvCOeq \o\al(2 ,3)X[(W C(ugnmZP0qrS^[ekp0q:NĞr R勶nm-NN[ gCQ } S gCQ } DR+R+T gMg2 0Cu2 0Fe2 TNa vVyvnm S(uNaOHnm/f NN!kt+R_v T{Hh0C ㉐g0A y_NS+TFe2 ByS+T gHCOeq \o\al( ,3)DyMg(OH)2:N}vrlm Cu(OH)2:N݄rlm Fe(OH)2HQ/f}vrlm NŏS:Npp~r gTS:N~r Na NOH esa EeSN!kt+R0 6 NRT~ir(vNmTۏLS^ e glSOubg~S glmubv/f(00) `$ё^\beQFeCl2nm-Na$ǏϑvNaOHnmTfwnmS^b$\ϑCaObeQ0RǏϑNaHCO3nm-Nc$Na2O2beQ0RFeCl2nm-N A.`$b$ B.b$c$ C.a$b$ D`$c$ T{Hh0D ㉐g0`$-NNaNFeCl2nmS^ubFe(OH)2lmTH2 b$-NCaONNaHCO3nmS^ubCaCO3lm c$-NNa2O2NFeCl2nmS^ubFe(OH)3lm[Fe(OH)2'lS b]TO2 a$-NǏϑvNaOHnmTKAl(SO4)2nmS^ NebOAl3 S:NAlOeq \o\al( ,2) sSelmNu SNeb_NelSOub0 7 NRT~ir(vN\O(u ubir NS^agNbS^irv(uϑSS SSv/f(00) A.NaTO2 B.NaOHTCO2 CNaHCO3TNaOH DNa2CO3THCl T{Hh0C ㉐g0NaTO2(W8^)n NS^ubNa2O RpeubNa2O2NaOHNCO2S^e CO2ǏϑubNaHCO3 NeubNa2CO3Na2CO3NvxS^e HClǏϑ RubCO2 NeubNaHCO30 8Sm^GW:N0.1 molL 1v NynmI{SOymT EQRS^Tl glmvN~nm/f(00) A.BaCl20NaOH0NaHCO3 BNa2CO30MgCl20H2SO4 CAlCl30NH3H2O0NaOH DBa(OH)20CaCl20Na2SO4 T{Hh0B ㉐g0(WagN N A-NSuvS^:NNaOH NaHCO3===Na2CO3 H2O Na2CO3 BaCl2===2NaCl BaCO3! EeA-N glmB-NSuvS^:NNa2CO3 H2SO4===Na2SO4 CO2! H2O Ee NSNulmC-NSuvS^:NAl3 4OH ===AlOeq \o\al( ,2) 2H2O iRYOvAl3 SuS^Al3 3NH3H2O===Al(OH)3! 3NHeq \o\al( ,4)D-NSuvS^:NBa(OH)2 Na2SO4===BaSO4! 2NaOH gBaSO4lmEe B0 9\4.6 gё^\beQ0Rϑ4l-N _0Ra gnm\4.8 gё^\AbeQ0Rϑvx-N _0Rb gnm GP4lv(ϑNvxv(ϑvI{ RS^T$Nnmv(ϑsQ|:N(00) A.ab B.ab C.ab Del$Re T{Hh0A ㉐g0nmv(ϑI{Nё^\T4l(bx)v(ϑQS>eQH2v(ϑ0 2Na 2H2O===2NaOH H2!0%m 4600000000000200044 46 g0000000000000 44 g Mg 2HCl===MgCl2 H2!00%m 2400000000002000 22 48 g000000000000 44 g @bNS^MRTnm(ϑvSS/fvI{v0 10\$NN(ϑGW:Nm gvݔTAvmTir R+RbeQ0RϑvNaOHnmTvx-N ubH2(W T)n TS NvSOyk:N16"2 RSmTir-NݔNAvir(vϑKNk:N(00) A.16"2 B.16"3 C.36"1 D26"3 T{Hh0D ㉐g0ubH2vir(vϑR+R:N1 mol02 mol0(WNaOHnm-N2A l^3H2 Aleq \f(2,3)mol(Wvx-Neq \f(2,3)mol Alub1 mol H2 Mgub(2 mol 1 mol)1 mol 1uMg^H2 Mg 1 mol Een(Al)6"n(Mg)26"30 YDn0(W+T gFe3 TCu2 vnm̑ RǏϑ| S^[hQ nQё^\k#n vQ(ϑp`}YNReQ|v(ϑvI{ RSmTnm̑vFe3 NCu2 vir(vϑKNk:N(00) A.26"3 B.16"7 C.36"5 D26"7 T{Hh0D ㉐g0Fe3 NCu2 vir(vϑR+R:Nx0y R g 2Fe3 Fe===3Fe2 0Cu2 Fe===Fe2 Cu00%m 00000000 6400560000000008 x000eq \f(x,2)000000y 000000000008y 9hnca NFe3 S^vFev(ϑI{NFeNCu2 S^Q\v(ϑ sSeq \f(x,2)568y ㉗_x6"y26"70 11 NRyP[e z_cknxv/f(00) A.T"l'lSnm-NeQ\ϑCO2 OH CO2===HCOeq \o\al( ,3) BߍzkxxS^02Fe 6H ===2Fe3 3H2! C]xxݔnm-NReQǏϑ(l4l Al3 4NH3H2O===AlOeq \o\al( ,2) 4NHeq \o\al( ,4) 2H2O Dkx0lSnm-NReQ N/lSnm Fe3 3SCN ===Fe(SCN)3 T{Hh0D ㉐g0 yA-NVCO2ϑ\ Nir^/fCOeq \o\al(2 ,3) yBNNN1_'lSBRS^ SubFe2  yC-N ]xxݔnm-NReQǏϑv(l4lAl3 3NH3H2O===Al(OH)3! 3NHeq \o\al( ,4) Al(OH)3Sn(W:_x:_x-N v^ NN1_xS^ NubAlOeq \o\al( ,2)Fe(SCN)3vS_N5uyir( @bNDcknx0 12(Wkxxnm-N ReQa gܔ [hQnT SReQb g EQRS^T_0Rc gkYOVSO Nac R NRlcknxv/f(00) A.kYOVSOhQ/fܔ BkYOVSOS:NTܔmTir CkYOVSO/f nm-NN[ N+TCu2 DgT_0RvnmS+T gFe3 T{Hh0A ㉐g0ac @bNCu2 *ghQ萫؏S cw N S^Tnm-NX[(WCu2 VSOk#nS/fܔ nm_NN[ NS gFe3 0 1316 g CH4[hQqp \ubirhQǏǏϑvNa2O2 Na2O2\X͑(00) A.16 gB.32 gC.4 gDel$Re T{Hh0B ㉐g016 g CH4[hQqpubCO2TH2O FOS_mTirǏNa2O2e CCQ } cCO8T6e HCQ }[hQ8T6eubNaOH016 g CH4qpTNa2O28T6ev(ϑ^:N1 mol COv(ϑR N4 mol Hv(ϑ qQ32 g0 14T'lSvmTirqQa mol RvxTVSOhQ萶n qQ6eƖ0Rb mol H2 Nnm-NReQKSCNnm N>f~r RSmTir-Nvir(vϑ:N(00) A.b mol B.(a b) mol C.eq \f(1,2)(a b) mol Deq \f(1,2)(a b) mol T{Hh0D ㉐g0Fe2O3nNvxubFeCl3 FenNvxubFeCl2TH20 ReQKSCN N>f~rfeFe3 VdkFe؏NFeCl3S^0 0Fe2O3 6HCl===2FeCl3 3H2O n(Fe2O3)00002n(Fe2O3) 0Fe0 02FeCl3===3FeCl2 n(Fe2O3)02n(Fe2O3) Feb mol 2HCl===FeCl2 H2!b mol Rn(Fe2O3) n(Fe2O3) b mola mol n(Fe2O3)eq \f(a b,2) mol n(Fe)n(Fe2O3) b moleq \f(a b,2) mol 15\a g Fe2O30A l2O37hTn(WǏϑv200 mLSm^:N0.1 molL 1vvxnm-N 6qTTvQ-NReQNaOHnm OFe3 0A l3 R}Y[hQlm (uSNaOHnm100 mL RNaOHnmvSm^:N(00) A.0.1 molL 1 B.0.2 molL 1 C0.4 molL 1 D0.8 molL 1 T{Hh0B YDn0s(WAlCl3TMgSO4vmTnm TvQ-N NeReQNaOHnm_0RvlmvϑNReQNaOHnmvSOyvsQ|Y NV@b:y RSnm-NCl 0SOeq \o\al(2 ,4)vir(vϑKNk:N(00)  INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/T18.TIF" \* MERGEFORMAT  A.16"1 B.26"3 C.36"2 D66"1 T{Hh0D N0^ b(,gSb5*N\ qQ40R) 16(8R)gY;mR\~f[u!jb|T8TbwQ-NvSt(Ǐ'lSNnonN'lSxS^) (u NRNhVeg6RS'llv^Kmϑ'llvSOy0  INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/T19.tif" \* MERGEFORMAT  V-NϑlňnE/f1u2u0YN$N9hst{~bv [N(uajv{ޏ v^ňeQϑ4l 2u{ g;R^(0 mL^50 mL) Oϑl(uYN{S N NyR NmbؚNO0 [[SO (uvoT؏ gzkxx0vx0Ǐ'lS0xx0'Ytw04l0ՋVT{ (1) Nňnvޏcz^/f(kXTcSvS vQ-Nޏc{S9YcňnGWweu)________________________________________________________________________0 (2)ňnC-N>eeQvS^ir/f00000T00000 (3)ňnA v\O(u/f_________________________________________________________0 ňnBv\O(u/f____________________________________________________________0 (4):NNQnx0WKmϑ'llvSOy dN_{hgte*Nňnvl['`KNY (WSS^MRT2u{-Nmbvpe BlvQ]fsa eQCl2TnmHT@~r RX[(WFe2 18(6R) NV-NA0RF/fSTir G/fUS(  T{Hh0NaHCO30Na2CO30Na2O20NaOH ㉐g0STirA SpRSub NySTir (W-Nf[8^vSTirVQ VSOA S/f N3z[vx_vbx_xxܔ SV:NA R㉧Nuv$NySTirNSTirES^NuUS(G GS:NO2 E:NNa2O2 ncdkS$ReC0D^:NH2O0CO20Q9hncA0B(Wnm-NSǏNF0CS^vNlS ~TRgSnx[C:NCO2 D:NH2O RA:NNaHCO3 B:NNa2CO3019(9R) gNfnm S+T g'YϑvMg2 0Fe3 0Al3 0Cu2 0Na 0H 0SOeq \o\al(2 ,4)0COeq \o\al(2 ,3)-NvNybQy SdknmZP NR[ `$S\ϑnmReQ(uvxxSvBaCl2nm g}vrlmub a$S\ϑnmReQǏ'lS|+g nm-N g}vrlmNuv^8QeresTvlSO ReQNa2O2vir(vϑNgQlmvir(vϑYV@b:y0Ջce  INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/T20.TIF" \* MERGEFORMAT  (1)nm-NN[+T gvyP[/f______________0 (2)nm-N[ N+T gvyP[/f________________0 (3)S+T gvyP[/f____________0 T{Hh0(1)Mg2 0Al3 0SOeq \o\al(2 ,4)0(2)COeq \o\al(2 ,3)0H 0Cu2 0Fe3 (3)Na ㉐g01u[`$Sw NyP[-NN(uvxxSvBaCl2nmS^Nu}vrlmvS gSO2 4 CO2 3[ NX[(W$-N Na2O2|+gR0Rnm-Ne Na2O2ONvQ-Nv4lSuS^ubNaOHTO2 VS^T_0RN}vrlmTeresTvlSO @bNnm-N[l gFe3 0Cu2 NVPvSSR-N bNSN$Renm-N[ gMg2 TAl3 Vnm-NReQNa2O2|+ge zsSNuNlm Vdknm-N NSX[(W'YϑvH 0 N[-Nelnx[/f&T+T gNa 0 20(9R)s gSm^T:N1 molL 1 vFeCl30FeCl20CuCl2mTnm100 mL ReQN[ϑv| c NR`QkXzz(]w'lS'`Fe3 Cu2 Fe2 ) (1)S^[k | giRYO0S^Tvnm-NN[+T______3yP[0 (2)S^[k gܔub |eiRYO0S^Tvnm-NN[+T________3yP[ 3yP[(Wnm-Nir(vϑvV/f________S^Tvnm-NS+T________3yP[0 (3)S^[kT eVSOlyirX[(W S^Tvnm-NN[+T________3yP[0 T{Hh0(1)Fe2 0(2)Fe2 00.25 mol<n(Fe2 )d"0.35 molCu2 0(3)Fe2 0Cu2 ㉐g0S_\|ReQmTnm-Ne 1u'lS'`Fe3 Cu2 Fe2 SwSSuvS^ gFe 2Fe3 ===3Fe2 Fe Cu2 ===Cu Fe2 S_| giRYOe fFe3 NCu2 ]hQS^ EeN[ gFe2 S_ gܔub |eiRYOe Rf,{N*NS^[hQ ,{N*NS^_NSu Sp`}YS^ _NS| N EeS^Tvnm-NN[+T gFe2 S+T gCu2 ]wFeCl30FeCl20CuCl20mTnm-N Nvir(vϑGW:N0.1 mol S_p`}YS^e Fe2 vir(vϑg'Y:N0.15 mol 0.1 mol 0.1 mol0.35 mol S_NSu,{N*NS^e Fe2 vir(vϑ:N0.15 mol 0.1 mol0.25 mol EevQV/f0.25 moln(Fe2 )d"0.35 mol0 YDn0\0.1 molvA0ݔmTirnN100 mL 2 molL 1vH2SO4nm-N 6qTQnR1 molL 1vNaOHnm0VT{  INCLUDEPICTURE "../../AppData/Local/Temp/Rar$DIa0.316/T21.TIF" \* MERGEFORMAT  (1)(WnRNaOHnmvǏ z-N lm(ϑmReQNaOHnmvSOyVSSvsQ|Y NV@b:y S_V1160 mLe Rё^\|+g-Nn(Mg) mol V2 mL0 (2)(WnRNaOHnmǏ z-N 2kOMg2 0A l3 R}Ylm[hQ RneQNaOHnmvSOyV(NaOH)mL0 (3)mTirN:N0.1 mol vQ-NMg|vir(vϑRpe:Na (u100 mL 2 molL 1vH2SO4ndkmTirT QReQ450 mL 1 mol/L NaOHnm @b_lm-NeA l(OH)30ndkagNvavSBTVprvxz|忯忯hPhD LOJPJQJ^JhD LOJPJQJ^Jh`WhD LH*OJPJQJ^Jh`WhD LOJPJQJ^JhD LOJQJ^Jh`WhD LOJQJ^JhD LOJPJQJ^Jh`WhD LOJPJQJ^J: "*,:<>@`b񝐆xkhD LH*OJQJ^Jo(h`WhD LH*OJQJ^JhD LOJQJ^Jh`WhD LOJQJ^JhPhD LOJPJQJ^JhD LOJPJQJ^Jo(h`WhD LQJ^JhD LOJPJQJ^J h`WhD L@OJPJQJ^Jh`WhD LH*OJPJQJ^Jh`WhD LOJPJQJ^J* 8:@BTVXZ\^`djnr|~(׿ͱͿ͢͢wwgwwgZhD LOJPJQJ^Jo(h`WhD LH*OJPJQJ^Jh`WhD LH*OJPJQJ^Jh`WhD LOJPJQJ^JhD LOJPJQJ^Jh`WhD LOJPJQJ^Jh`WhD LH*OJQJ^JjhD LOJQJU^JhD LOJQJ^Jh`WhD LOJQJ^JhD 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