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EMBED PBrush  p C + q D K= EMBED Equation.3  2aIN K'Y S^ۏLv z^'Y lSs'Y0 KSN)n^ gsQ0N,ckS^:N>epe )n^ؚ K\ckS^:N8Tpe )n^ؚ K'Y0 Sf[s^a8^pevi_TaIN ~`NQ Yef[vv Yef[p Yef[Ǐ z Y`N _eQ Ǐ!n [ Ǐ!n q_TSf[s^avagN ,{Ne 1Of[utSm^0S:_I{agN[Sf[s^avq_T0 NSm^0S:_I{agN9eSTv tVav\Ol0 tSm^0S:_I{agN[Sf[s^avq_T Sf[s^avi_TSf[s^a8^pevq_TV }0 Sf[s^aS/f(WN[agN NMbOc S_N*NSS^0Rs^ar`T 9eSSm^0S:_0)n^I{agN s^a\4xOW v(WeagN N^zevs^a0 ,gP42MR$Nk tNHNSSf[s^avyR Sm^0S:_0)n^I{agNYUOq_TSf[s^avyR 02 30 10mL 0.01mol/L FeCl3 R(W N +8n1mol/L FeCl3 N,{ N 10mL 0.01mol/L KSCN /eՋ{-N +8n1mol/L KSCN /e[k 9hncsa;`~ĉ_(WvQ[agN NSv v v ck `Q N X'YS^irvSm^ Sf[s^a v ck=v  TckS^eTyR0v^9hncSm^[S^ vck v  svq_T ;uQv tVaV1 0 (usvwƋcS_vQ[agN NS X v 'YNir0Q\NirTQ\S^irSm^ cS^ir X'Y t Sf[s^ayRveT v^;uQv tVa0 V1 v v  v  v ck=v  vck v ck v ck=v  vck v ck v  v v   cubir X'Y t cubir Q\ t 6qT,gP42 N0kXh Sm^[Sf[s^avq_TkXh [N glSOSRvS^ S:_[Sf[s^ayR gUOq_TT|S:_[Sf[S^svq_TNSSf[s^a8^pevwƋۏLRg \OQv tVa cQ~ 6qT,gP43 N0Rg]v~/f&Tcknx0  bq_ ;`~ ]V \ON YeT 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@@@@@@@@ @"@$@&@(@*@,@.@0@2@4@:@<@P@Z@@ $$Ifa$ $ & F$Ifa$$If $If`@@@@ AAAABpBBClCC$D\DDDTEXEEEFbFfFF $IfWDd`  $IfWDx` $If & F $IfCCCCCXD\D^D`DDDDDDDTEVEXEjElErEtEvExE|E~EEEEEEEEEEEEEEEEEEEEEEEEEEEFF FFPFRFTFVF`FbFdFhFvFFFF GGGGGh+CJPJo( h+CJH*h+CJH*o( h+CJo(h+CJH*o(jh+CJUmHnHu h+CJ h+CJo(HF G(G*GGGGGGGGGG|ppppp $IfWD`rkd$$Ifl<108X 8 064 lal & F$If$If GGGTHrH|H~HHHHHHHHHHHHIIIII IIII÷槛vcQDDh+CJOJPJQJo(#jh+CJEHOJPJQJU$jX? h+CJKHUVaJo(jlh+CJOJPJQJU(j? h+CJOJPJQJUVo(h+CJOJPJQJjh+CJOJPJQJUjih+CJEHU$j5X? h+CJKHUVaJo( h+CJjh+CJU h+CJo(h+CJPJo(h+ h+o(GGGGGHHHHH H HHHHHHHH H"H$H&H(H*H,H.H0H$If $IfWD`0H2H4H6HKDKFKHKJKNKPKRKTK\KfKlKKKKKKKKKKKKKK:LJLTLLLLLL8M:MMNMPM`MbMrMtMMMMMMMMMMMMMMNh+B*CJo(phh+B*o(ph h+o(h+CJOJo(h+CJOJPJo( h+CJo( h+CJH*jh+CJUmHnHu h+CJh+CJH*o(h+CJH*o( h+CJo(:LLLLLLLMM(MXRRRR$Ifkd#$IfK$L$l4FDC 06    4 laf4 $$Ifa$K$$IfK$ $IfWD`K$ (M:MLM^MpMMMMMMM[kdI$$IfK$L$l\DC 064 la$If$IfK$ MMMMMN&N6N$IfUDVD]^K$$IfUDVD]^$If$IfK$N N N$N0N4NNNRN^NbNrNxN~NNOXP4QLQhQjQQQQQQQQQQQQQϼo\$jX? h+CJKHUVaJo(j*h+CJOJPJQJU(j? h+CJOJPJQJUVo(h+CJOJPJQJjh+CJOJPJQJUj(h+CJEHU$j5X? h+CJKHUVaJo( h+CJjh+CJUh+CJPJo( h+o( h+CJo(h+B*CJo(ph6N8NepS^0 TGSؚ(rSm(s^aT8TpeTyR TMNO(rSEm(s^aT>epeTyR 9hncsa \OQv-tVa0 v v  v v v ck=v  v ck vck v ck=v  vck vck v v ck v ck=v   v v  v TX'Y t TQ\ t (uPSBRt PSBRYUOq_TSf[s^abT ,gP44 N0;`~QRYyrRSt0\OQO(uPSBRvv-tVa0 V0PSBR Nq_TSf[s^avyR FOSN)ws^a@bve0 Sm^0S:_0)n^I{agN[Sf[s^avq_TsSRYyrRSt0 1,gP45 2,gP47 `N ~`NQ Yef[vv Yef[͑p ec Rg ċN \~,{ Ne 1ccSf[s^ar`h_v$ReT gsQ{0 2cؚf[uRgT㉳QvR0 ~TЏ(uwƋ W{QctR0 O1(WR`)n N [핹[hV-NvSS^2SO3g  INCLUDEPICTURE "http://res2.pudong-edu.sh.cn/Resource/GZ/GZHX/JAJC/ZFX/tbjx0175zw_0012_2.gif" \* MERGEFORMATINET 2SO2g +O2g S(uegnx[S^]~0Rs^ar`v/f0000000 [00C0 ] AS^[hVQ S:_ Ne9eS BUSMOem1molSO3 Teub1molSO2 CUSMOem1molSO3 Tem1molSO2 D[hVQmTlSOv;`(ϑ NSuSS O2(WN[)n^ Nv[[[hV-N S_ NRirtϑ NQSuSSe NhfSS^As +2Bg  INCLUDEPICTURE "http://res2.pudong-edu.sh.cn/Resource/GZ/GZHX/JAJC/ZFX/tbjx0175zw_0012_3.gif" \* MERGEFORMATINET Cg +Dg %H<0]0Rs^ar`v/f00[0A0 ] AmTlSOvS:_ BmTlSOv[^ CBvir(vϑSm^ DS^>eQvpϑ NSf[s^ai_v,g(S[vY^ST$Re FOla-NSS^vyr_0ir(vr`sS N we z_N wr` N w|pe N wpHe^0 VT{O3*gcf[핹[hVvSOyV[ [NSOySS[hV s^aN&T [hVQS:_GW NO9eS A Ncknx0B yScNckS^s Ccknx0 VT{O4-N[hVvSOy}6qV[ FOSS^(WS^MRTlSOvSOyvI{ mTlSOv;`SOy NS s^aN&T [hVQS:_GW NO9eS A y Ncknx01u(ϑ[R`[_egRg S^irA:NVSO s^aMRTlSO(ϑ NvI{ B ycknx0 VT{[핹[hVvSOyV[ }6qmTlSOv;`ir(vϑ NS FOS^Ǐ z-NbRlSOvir(vϑ(W9eS Sm^(W9eS @bNC ycknxckS^:N>epS^ D y_Ncknx0 O1-NvA0B0D N*N yGW Ncknx S gCcknx0 O2-NS gA y NhfSS^0Rs^ar`0 Sf[s^ar`h_v$Reel )R(uvck=v$Re09hnca SYBlQ TNir(vRsI{Nu bs R0Rs^a0 N0)R(u8^Sf[ϑYSm^0S:_0[^0v[s^GWRP[(ϑ0SOyRpe0lSsI{ $Re0[gNwQSOS^ S_gNSf[ϑ Ns^ayR SS yvQ:N[ϑ [ϑ N\O:Ns^avh_S_gNSf[ϑs^ayR SuSS yvQ:NSϑ Sϑ NSe RS^0Rs^a0ibNS݋:N[ϑ N e Sϑ NQSRS e  e c$Re 0 O3(WTb(lS^-N \1mol N2T3 mol H2(WN[agN NS^ 0Rs^ae Onc NRagN BlQS^irN2lSvir(vϑ0 1 N2vlSs:N20% 2 s^amTir;`ir(vϑ:N36 mol ]V \ON YeT3 s^amTl-NNH3vSOyRpe:N20% 4 s^amTlvs^GWv[RP[(ϑ:N1063 5 S^_YeS:_Ns^aevS:_KNk:N10:9 6 )n^0S:_ NSe s^amTlSOv[^/fSegv4/3 ㉐gN2mvir(vϑ:Nx mol N N2 + 3 H2  EMBED PBrush  2NH3 ek wYϑmol 1 3 0 R lSϑmol x 3x 2x g s^aϑmol 1-x 3-3x 2x+0 l s^aemTlSOv;`ir(vϑ:N1-x +3-3x +2x+0 =4-2x x/1 =20% @bNx=02 2 4-2x=36 @bN x=02 3 V:N T)n TS lSOvSOyk=ir(vϑKNk @bN2x/4-2x =20% sSx=1/3 4  EMBED Equation.3 =28+6 /4-2X =1063 sSx=04 5 I{)nI{[ N lSOvS:_kI{NlSOvir(vϑKNk 4/4-2x =10/9 sSx=02 6 I{)nI{Se lSOv[^k=lSOv[RP[(ϑKNk 4-2x /4 =3/4 sSx=02 O4MCE99 X0Y0Z NylSO ba mol XTb mol YEQeQN[핹[hV-N SuS^X+2Y  EMBED PBrush  2Z 0Rs^ae傃[Nvir(vϑnnX +nY =nZ RYvlSs:N  A EMBED Equation.3 100% B EMBED Equation.3 100% C EMBED Equation.3 100% D EMBED Equation.3 100% ㉐gS^s^aemx mol Y X + 2 Y  EMBED PBrush  2Z wYϑmol a b 0 lSϑmol x/2 x x s^aϑmol a-x/2 b-x x OaS_a-x/2 +b-x =x sSx=2a+b /5 @bNYvlSs:N2a+b /5b B cknx0 ~`NQ ~`NQ Yef[vv Yef[͑p Yef[Ǐ z _eQ Ǐ!n bq_ ;`~ ]V \ON YeT Tb(lagNv b 1Of[ut㉂YUO^(uSf[S^sTSf[s^aSt bTb(lv[agN0 2Of[uN㉔^(uSf[St bS]uNagNv`Tel0 ^(uSf[S^sTSf[s^aSt bTb(lv[agN0 MRbQbNf[`NN gsQSf[S^sTSf[s^avwƋ ُbN\^(uُNwƋNwTb(lv[agN0 QQTb(lve z_ cQُ*NS^vyrp0 N2 + 3H2  EMBED PBrush  2NH3 + Q  = 1 \* GB3 `$SS^  = 2 \* GB3 a$ckS^:N>epS^  = 3 \* GB3 b$ckS^:NSOy)\vS^ (W]NuN-N EQRQ~NmHev NOS^ۏLv_ NONTvNϑfؚ 1\QSf[S^sTSf[s^a0 Tf[N9hncTb(lS^vyrp NSf[S^sTSf[s^a$N*N҉^Rg Tb(l^ǑSNHNS^agN ^uqQ T bq_~g0 N2 + 3H2  EMBED PBrush  2NH3 + Q S^agN OubNH3_ NS^sRg ONH3+Tϑؚ NSf[s^aStRg S:_ ؚS ؚS )n^ ؚ)n NO)n PSBR O(u Nq_T ,gP48^51 ;`~Tb(lv[agN0 Tb(lS^vyrp N2 + 3H2  EMBED PBrush  2NH3 + Q  = 1 \* GB3 `$/fSS^  = 2 \* GB3 a$ckS^:N>epS^  = 3 \* GB3 b$ckS^:NSOy)\vS^ N0Tb(lv[agN  = 1 \* GB3 `$S:_20 ^50MPa  = 2 \* GB3 a$ )n^5000CdkePSBR;m'`g'Y  = 3 \* GB3 b$PSBR扒Z  = 4 \* GB3 c$X'YN20H2vSm^ Se\ubvNH3Ry l = 1 \* GB3 `$SRR0Pge0YvP6R S:_ N*Y'Y0  = 2 \* GB3 a$N2TH2_{_sO(u0 ,gP54 N0Tb(lagNv b ,gP52 `N ~`NQ Sf[s^a ,{N Sf[S^s Sf[S^s 1[IN 2h:yel(uUSMOeQS^irSm^vQ\bubirSm^vXRegh:y0 3lQ_ EMBED Equation.3 = EMBED Equation.3  4USMOmol/Ls 0mol/Lmin la 1 ُ̑@bcvS^s/fs^GWS^s 2 TNS^vS^s SN(u N Tir(h:y vQpeeeQ4 mol SO2T2 mol O2 2 s+g Km_[hVQ g16 mol SO2 Bl2s QSO20O20SO3vS^s0 4.g)n^e V-Nf~X0Y0Z Nyir(v ir(vϑevSSf~01uV-Npenc Rg S^vSf[e z_:N S^_Y2 min Zvs^GWS^s :N 0 5b NRVyXvnmR+RReQV*Nv g10mL 2mol/L vxvpog-N GWR4lzʑ0R50mL dkeXTvxۏLS^ vQ-NS^sg_v/f( ) A20mL 3 mol/L B20mL 2 mol/L C 10mL 4 mol/L D10 mL2 mol/L 6 NRS^-N S_vQ[agN NSe X'YS:_ Sf[S^sR_v/f( )  = 1 \* GB3 `$N2+O2=2NO  = 2 \* GB3 a$Fe +CuSO4=FeSO4+Cu  = 3 \* GB3 b$N2+3H2=2NH3  = 4 \* GB3 c$2SO2+O2=2SO3 AS g = 4 \* GB3 c$ B = 1 \* GB3 `$ = 2 \* GB3 a$ = 3 \* GB3 b$ C = 1 \* GB3 `$ = 2 \* GB3 a$ = 4 \* GB3 c$ D = 1 \* GB3 `$ = 3 \* GB3 b$ = 4 \* GB3 c$ 7[NS^H2+I2=2HI (W[핹[hV-NۏL NRagN-NYR_S^sv/fGP[)n^ NS  A)\SOy OS:_X'Y BSOy NSEQeQH2OS:_X'Y CSOy NSEQeQNeOS:_X'Y DS:_ NSEQeQNe 8X'YS^irSm^0X'YS:_ glSOSRS^ 0GSؚ)n^TO(uPSBRSNX'YSf[S^s0vQ-NX'YS^irRP[-N;mSRP[~vRpev/f t1u/f 0  v 9S'lSv GrbeQ0Rv gzvxv Ջ{-N SsH2NuvsSS`QYV@b :y vQ-N0^t1sSSv;NSV/f t1^t2sSSv  ;NSV 0 0 t1 t2 t ,{N Sf[s^a N0Sf[s^av^z 1i_ 2yr_ 1   Sf[s^axvzv[a/fSS^ SS^ NۏL0R^ sSs^aeTS^irTubirvϑGW NI{N0  NI{NSR 2  R vck=v`" 0 sSSf[s^a/fR`s^a0 3  [ s^ae T~RvϑSm^0SOy0(ϑRpeI{ Oc NS 4  S S_agN9eSe s^aS4xOW \(WeagN N^zes^a0 3Sf[s^av^zNS^_esQSagNv T v^ ce z_vSf[ϑpevv^ϑMe O[hV-N;`(ϑOcvI{ R NNckS^0S^ bckS^ Te_Y g~0R TNs^ar`0 N0Sf[s^a8^peK  1i_ [NN,SSS^mA+nB!pC+qD K= EMBED Equation.3  2aIN 1 K'Y S^ۏLv z^'Y lSs'Y0 2 KSN)n^ gsQ0N,ckS^:N>epe )n^ؚ K\ckS^:N8Tpe )n^ؚ K'Y0 ~`N 1(WN[)n^ N S^A2g +B2g !2ABg 0Rs^avh_/f( ) USMOeQub n mol A2 Teubn mol AB B[hVQv;`S:_ NevSS SS CUSMOeQub 2n mol AB Teubn mol B2 DUSMOeQub n mol A2 Teubn mol B2 2(WNV[[yv[핹[hVQ 2mol AT1mol B(WN[agN NSuS^2Ag +Bg  EMBED PBrush 3Cg +Dg s^ae C =w mol/L 0(W TN[hV Oc N)n^ c NRMkۏLS^ NSOs^aeC =w mol/Lv/f( ) A4molA+2mol B B 3mol C + 1mol D C1mol+1/2molB+3/2molC+1/2molD D 1molA+1/2 molB 3g)n^ (WN*N2L[핹[hV-N A0 B0C Nir(vϑevSSf~YV RS^ir/f ubir/f 0 e;Rhf 0S ^vSf[e z_:N(uA0B0CNhir (  0 q_TSf[s^avagN q_TSf[s^avagNSs^ayRvSt agNvSS s^ayRveTs^ayRv~g Sm^cS^ir X'Y cS^ir Q\ cubir X'Y cubir Q\T S^eTyR T S^eTyR T S^eTyR T S^eTyROcS^ir OcS^ir Ocubir Ocubir S:_X'Y Q\T eTyR T eTyROlSOS:_ OlSOS:_ )n ^GSؚ MNOT eTyR T eTyRO)n^ O)n^  R Y yr R St Y lI{SOyS^TelSOSRS^ S:_9eS FOs^a NyR0 2O(uPSBR N9eSs^ayR FOSN)ws^a@bve0 O1(WR`)n N [핹[hV-NvSS^2SO3g  INCLUDEPICTURE "http://res2.pudong-edu.sh.cn/Resource/GZ/GZHX/JAJC/ZFX/tbjx0175zw_0012_2.gif" \* MERGEFORMATINET 2SO2g +O2g S(uegnx[S^]~0Rs^ar`v/f0000000 [00 ] AS^[hVQ S:_ Ne9eS BUSMOem1molSO3 Teub1molSO2 CUSMOem1molSO3 Tem1molSO2 D[hVQmTlSOv;`(ϑ NSuSS O2(WN[)n^ Nv[[[hV-N S_ NRirtϑ NQSuSSe NhfSS^As +2Bg  INCLUDEPICTURE "http://res2.pudong-edu.sh.cn/Resource/GZ/GZHX/JAJC/ZFX/tbjx0175zw_0012_3.gif" \* MERGEFORMATINET Cg +Dg %H<0]0Rs^ar`v/f00[00 ] AmTlSOvS:_ BmTlSOv[^ CBvir(vϑSm^ DS^>eQvpϑ ;`~Sf[s^ar`h_v$Reel )R(uvck=v$Re09hnca SYBlQ TNir(vRsI{Nu bs R0Rs^a0 N0)R(u8^Sf[ϑYSm^0S:_0[^0v[s^GWRP[(ϑ0SOyRpe0lSsI{ $Re0[gNwQSOS^ S_gNSf[ϑ Ns^ayR SS yvQ:N[ϑ [ϑ N\O:Ns^avh_S_gNSf[ϑs^ayR SuSS yvQ:NSϑ Sϑ NSe RS^0Rs^a0ibNS݋:N[ϑ N e Sϑ NQSRS e  e c$Re 0 O3(WTb(lS^-N \1mol N2T3 mol H2(WN[agN NS^ 0Rs^ae Onc NRagN BlQS^irN2lSvir(vϑ0 1 N2vlSs:N20% 2 s^amTir;`ir(vϑ:N36 mol 3 s^amTl-NNH3vSOyRpe:N20% 4 s^amTlvs^GWv[RP[(ϑ:N1063 5 S^_YeS:_Ns^aevS:_KNk:N10:9 6 )n^0S:_ NSe s^amTlSOv[^/fSegv4/3 O4MCE99 X0Y0Z NylSO ba mol XTb mol YEQeQN[ [hV-N SuS^X+2Y  EMBED PBrush  2Z 0Rs^ae傃[Nvir(vϑn nX +nY =nZ RYvlSs:N  A EMBED Equation.3 100% B EMBED Equation.3 100% C EMBED Equation.3 100% D EMBED Equation.3 100% Tb(lagNv b N2 + 3H2  EMBED PBrush  2NH3 + QS^agNOubNH3_ NS^sRg ONH3+Tϑؚ NSf[s^aStRg S:_)n^PSBR     PAGE   EMBED PBrush   EMBED PBrush  (*,.468>@BDHJLNPZ`"<h+5CJH*\o(h+5CJ\o(h+5CJ\aJ h+aJo( h+aJh+CJPJo( h+o( h+CJo(jh+CJUmHnHu h+CJ h+CJH*h+CJH*o(h+CJH*o( h+CJo(3<>@BLNX^`bdfhjl|||||||| $If`$Ifrkd1.$$Ifl108X 8 064 lallnprxz|~$If[$\$^ $If[$\$ $$Ifa$$If $If`<BDFHJLN468:@BDFHLNPRx*,.02TVX䜥䜕h+5CJ\aJ h+CJH*h+CJH*o(h+CJOJQJaJo(h+CJH*OJQJ h+CJj.h+CJUjh+CJUo(h+CJOJQJo(h+CJH*aJo( h+CJo(h+CJOJQJ30V&fpHFd d $If & Fd $If$If $If[$\$$IfWDd[$\$`XZ\$&(*,:RTf pv߱߱ؤؤ؞؂h+5CJ\aJh+CJaJh+ h+o( h+aJh+CJOJQJaJo( h+CJj0h+CJUjh+CJUo(h+CJOJQJo( 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